Chemical bonding of lead in glasses through isotropic vs anisotropic correlation: PASS shifted echo.
When observing spin I = (1/2) nuclei with important chemical shift anisotropy in disordered materials, the distribution of isotropic shift can become so large that no accessible spinning rate is able to provide a resolved spectrum. This is the case of 207Pb in glasses where static and high-speed MAS spectra are nearly identical. It is still possible in such a case to rebuild a spinning sideband free spectrum using a shifted echo modified PASS sequence. This makes it possible to discuss isotropic and anisotropic chemical shifts of lead in phosphate glasses, to characterize its structural role and its chemical bonding state.
Centre de Recherche sur les Matériaux à Haute Température-, CNRS, Orléans Cedex 2, 45 071, France.
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Fayon
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Bessada
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Douy
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Massiot
D016880:Anisotropy; D017352:Echo-Planar Imaging / Q000379:methods*; D005898:Glass / Q000737:chemistry*; D007554:Isotopes; D007854:Lead / Q000737:chemistry*; D011208:Powders / Q000737:chemistry; D013113:Spin Labels
D007554:Isotopes; D011208:Powders; D013113:Spin Labels; D007854:Lead; C036682:lead phosphate