beta-triketones from myrtaceae: isoleptospermone from leptospermum scoparium and papuanone from corymbia dallachiana
Naturally occurring beta-triketones, isoleptospermone [3, 5-hydroxy-4-(2-methyl-1-oxopentyl)-2,2,6, 6-tetramethyl-4-cyclohexene-1,3-dione) from Leptospermum scoparium] and papuanone [6, 5-hydroxy-4-(1-oxohexyl)-2,2,6, 6-tetramethyl-4-cyclohexene-1,3-dione from Corymbia dallachiana], have been synthesized. Full spectral data are reported for the first time. The 13C NMR spectra of 3, 6, and the other triketones flavesone (2), leptospermone (4), and grandiflorone (5) found in Myrtaceous plants are fully assigned.
van Klink JW
Plant Extracts Research Unit, New Zealand Institute for Crop and Food Research Limited, Department of Chemistry, University of Otago, Box 56, Dunedin, New Zealand, and School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia.
Brophy
JJ
Perry
NB
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RT