Study of the Interaction Products of Some N- and O-Containing Compounds with Highly Dispersed Copper(II) Hydroxide.
Composition and structure of the surface compounds formed after interaction between Cu(OH)2 supported on aerosil and bpy, py, PhOH, and H2O2 are studied. The EXAFS and electron spectroscopy methods show the main part of copper ions to remain in a hydroxide surrounding, whose structure does not change practically and does not depend on the nature of the extra ligands used. The colloidal Cu(OH)2 stabilized by starch is found to reveal the same properties as the supported one, but differs by greater sizes of hydroxide particles. Copyright 1999 Academic Press.
Elizarova
GL
Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
Kochubey
DI
Kriventsov
VV
Odegova
GV
Matvienko
HL
Kolomiychuk
VN
Parmon
VN