title: A study on the adsorption structure of an adhesive monomer for precious metals by surface-enhanced Raman scattering spectroscopy.
abstract: In order to clarify the role of a primer on the adhesion between dental precious metals and resin, surface-enhanced Raman scattering (SERS) technique has been applied to the structural analysis of the adhesive monomer, 6-(N-(4-vinylbenzyl)propylamino)-1,3,5-triazine-2, 4-dithione (VBATDT) adsorbed on colloidal Au surfaces. VBATDT is one of the major components of commercial primers. A mixture of a methanol solution of VBATDT and aqueous Au colloid was illuminated by the 647.1 nm line from a Kr ion laser to obtain the SERS. The most intense peak at 458 cm-1 due to C = S stretching in the Raman spectrum of solid VBATDT disappears completely in the SERS, while all the other peaks due to vinylbenzyl group vibrations remain unchanged. It suggests that some structural change occurs in VBATDT upon adsorption on Au which involves the C = S bonds and that the molecule undergoes thione-thiol-type tautomerization in the adsorption process. The SERS spectrum of a commercial primer containing VBATDT exhibits a similar spectral pattern. The present results lead us to conclude that some specific interactions exist between the sulfur atoms of VBATDT and Au surface to form chemical bond likes, which are effective to improve the bond strength between dental precious metals and resin. The ambivalent properties of the primer, chemical stability in storage and chemical affinity to Au, are also explained by the thione-thiol-type tautomerization of VBATDT on the basis of the spectroscopic evidence.
authors.affiliation: Department of Molecular Science, College of Arts & Sciences, Showa University, Tokyo, Japan. suzukima@cas.showa-u.ac.jp
authors.forename: M
authors.initials: M
authors.lastname: Suzuki
authors.forename: A
authors.initials: A
authors.lastname: Fujishima
authors.forename: T
authors.initials: T
authors.lastname: Miyazaki
authors.forename: H
authors.initials: H
authors.lastname: Hisamitsu
authors.forename: K
authors.initials: K
authors.lastname: Kojima
authors.forename: Y
authors.initials: Y
authors.lastname: Kadoma
mesh_terms: D000269:Adhesives; D000327:Adsorption; D003102:Colloids; D001840:Dental Bonding; D003764:Dental Materials; D006046:Gold; D012542:Scattering, Radiation; D013059:Spectrum Analysis, Raman / Q000379:methods; D013501:Surface-Active Agents / Q000737:chemistry; D014227:Triazines / Q000737:chemistry*
chemical_list: D000269:Adhesives; D003102:Colloids; D003764:Dental Materials; D013501:Surface-Active Agents; D014227:Triazines; D006046:Gold; C076160:6-(4-vinylbenzyl-n-propyl)amino-1,3,5-triazine-2,4-dithiol