title: Determination of the insecticide pyridafenthion in river water, soils and wine by adsorptive stripping voltammetry.
abstract: Solid-phase extraction or liquid-liquid extraction has been combined with adsorptive stripping voltammetry at a hanging mercury drop electrode to isolate, determine, quantify and recover trace concentrations of pyridafenthion in water, wine and soil. A systematic study of the experimental parameters affecting the stripping response was carried out by differential pulse voltammetry. By using an accumulation potential of 400 mV and an accumulation time of 540 s, the limit of detection was 0.17 microgram l-1 and the relative standard deviation (n = 10) was 1.9% at a concentration level of 8.5 micrograms l-1. Different methods are proposed which eliminate matrix interferences. These results have been applied to the systematic study of this compound in water, wine and soil. The lowest detectable concentration for pyridafenthion is 34 micrograms l-1 in water, 102 micrograms l-1 in wine and 80 micrograms kg-1 in soil. Recoveries of the pyridafenthion from supplied environmental samples were in all cases higher than 92% with a relative standard deviation lower than 3%.
authors.affiliation: Department of Analytical Chemistry, Faculty of Pharmacy, University of the Basque Country, Vitoria-Gasteiz, Spain.
authors.forename: M C
authors.initials: MC
authors.lastname: Sampedro
authors.forename: Z
authors.initials: Z
authors.lastname: Gomez de Balugera
authors.forename: A
authors.initials: A
authors.lastname: Goicolea
authors.forename: R J
authors.initials: RJ
authors.lastname: Barrio
mesh_terms: D004563:Electrochemistry; D006801:Humans; D007306:Insecticides / Q000032:analysis*; D009946:Organothiophosphorus Compounds / Q000032:analysis*; D012989:Soil Pollutants / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014920:Wine / Q000032:analysis*
chemical_list: D007306:Insecticides; D009946:Organothiophosphorus Compounds; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical; C010418:pyridafenthion