title: Comparison of the core size distribution in iron dextran complexes using Mössbauer spectroscopy and X-ray diffraction.
abstract: Mössbauer spectra of a series of iron dextran complexes in the intermediate temperature range where both sextet and doublet coexist may be used to obtain a qualitative description of the distribution of core sizes in these samples. Eight samples from five suppliers have been examined at 100 and 77 K. These differ markedly in the relative doublet contribution to the total spectral area and also in the hyperfine fields characterizing the sextets. The results indicate three distinct types of distribution. One sample from each type has also been examined at 4 K, where the doublet component has vanished and the hyperfine field distribution has become narrow and symmetric. These data are compared with estimates of average core diameters from X-ray line broadening.
authors.affiliation: Department of Chemistry, North Carolina State University, Raleigh 27695-8204, USA.
authors.forename: B
authors.initials: B
authors.lastname: Knight
authors.forename: L H
authors.initials: LH
authors.lastname: Bowen
authors.forename: R D
authors.initials: RD
authors.lastname: Bereman
authors.forename: S
authors.initials: S
authors.lastname: Huang
authors.forename: E
authors.initials: E
authors.lastname: De Grave
mesh_terms: D007505:Iron-Dextran Complex / Q000737:chemistry*; D008280:Magnetics; D015204:Spectroscopy, Mossbauer; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D007505:Iron-Dextran Complex