Sodium-23 MAS NMR study on nuclear quadrupole interaction in NA(1-x)Ag(x)NO2.
Ag-impurity effects on the first- and second-order quadrupole interaction (QI) at 23Na site in an isomorphic mixed system, Na(1-x)Ag(x)NO2 (x = 0, 0.0084, 0.026, 0.079, 0.094, 0.16), have been investigated by employing 23Na (I = 3/2) magic angle spinning nuclear magnetic resonance (MAS NMR) technique. The central transition (CT) and satellite transition (ST) are simultaneously observed with this system. From the spectral analysis, the quadrupole parameter and its distribution width are obtained as a function of Ag concentration. From the intensity loss of CT MAS centerband and of the envelope function of ST MAS sidebands due to impurities, the range of their influence on the second- and first-order QI is estimated. The estimated ranges contain the second and first neighbouring Na sites from the resonating 23Na nucleus for the first- and second-order QI, respectively.
Jung
J K
JK
Magnetic Resonance Group, Korea Basic Science Institute, Taejeon, South Korea.
Han
O H
OH
Choh
S H
SH
D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D012834:Silver; D012975:Sodium Isotopes
D012975:Sodium Isotopes; D012834:Silver