A spirostanol saponin from the underground parts of Ruscus aculeatus.
A new spirostanol saponin was isolated from the underground parts of Ruscus aculeatus and the structure was assigned as (23S,25R)-spirost-5-ene-3 beta,23-diol 23-O-[O-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside] on the basis of spectroscopic analysis, including two-dimensional NMR spectroscopic techniques and the result of acid hydrolysis. The saponin is unique in structure having a diglycoside unit at C-23 of the spirostanol skeleton.
Mimaki
Y
Y
School of Pharmacy, Tokyo University of Pharmacy and Life Science, Japan. mimakiy@ps.toyaku.ac.jp
Kuroda
M
M
Yokosuka
A
A
Sashida
Y
Y
D005060:Europe; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D018517:Plant Roots / Q000737:chemistry; D010946:Plants, Medicinal / Q000737:chemistry*; D012503:Saponins / Q000737:chemistry* / Q000302:isolation & purification; D016339:Spectrometry, Mass, Fast Atom Bombardment; D013141:Spiro Compounds / Q000737:chemistry* / Q000302:isolation & purification; D013150:Spirostans
D012503:Saponins; D013141:Spiro Compounds; D013150:Spirostans; C120409:spirost-5-ene-3,23-diol-23-O-(O-glucopyranosyl-(1-6)-glucopyranoside)