Chemoenzymatic synthesis of an unnatural tetramethyl cobalt corphinoid.
The chemoenzymatic synthesis and structural characterization by 13C NMR of a tetramethyl cobalt-corphinoid produced by methylation of cobalt-precorrin-3 using CbiF are described.
Department of Chemistry, Texas A&M University, College Station 77842-3012, USA.
P J
PJ
Santander
N J
NJ
Stolowich
A I
AI
Scott
D003035:Cobalt / Q000737:chemistry; D004926:Escherichia coli / Q000201:enzymology; D009682:Magnetic Resonance Spectroscopy; D008745:Methylation; D008780:Methyltransferases / Q000737:chemistry; D008956:Models, Chemical; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D014578:Uroporphyrins / Q000737:chemistry*
D009942:Organometallic Compounds; D014578:Uroporphyrins; C121490:tetramethyl cobalt corphinoid; C078447:precorrin 3; D003035:Cobalt; D008780:Methyltransferases; C078454:precorrin-3 11-methyltransferase