The red form of [Re(phen)(CO)3(H2O)]-CF3SO3.H2O.
The coordination geometry of the cations in the red form of aquatricarbonyl(1,10-phenanthroline-N,N')rhenium(I) trifluoromethanesulfonate hydrate, [Re(C12H8N2)(CO)3-(H2O)]CF3SO3.H2O, is approximately octahedral, with a facial arrangement of the linearly coordinated carbonyl ligands. The phenanthroline (phen) ligands interleave to form a columnar pi-stacked structure.
Connick
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WB
Beckman Institute, California Institute of Technology, Pasadena 91125, USA. bill.connick@uc.edu
Di Bilio
A J
AJ
Schaefer
W P
WP
Gray
H B
HB
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry*
D009942:Organometallic Compounds; D010618:Phenanthrolines; C120467:aquatricarbonyl(1,10-phenanthroline-N,N')rhenium(I)