Characterization of new acrylic bone cement based on methyl methacrylate/1-hydroxypropyl methacrylate monomer.
New formulations of acrylic bone cement based on methyl methacrylate/1-hydroxypropyl methacrylate (MMA/HPMA) monomers were developed with the purpose of obtaining more ductile materials with reduced polymerization shrinkage. In this way, the ductility of such materials increased, but the introduction of high percentages of the hydrophilic component produced an important decrease in Young's modulus and strength. To ascertain the reason for the deterioration of the tensile parameters, an analysis by scanning electron microscopy of these formulations was carried out; it revealed poor adhesion between the matrix and poly(MMA) beads. We also observed that the polymerization shrinkage increased as the amount of hydrophilic monomer in the formulation decreased, and the 50% (v/v) HPMA modified bone cement compensated for this volume reduction with its water uptake swelling. Measurements taken on the setting time and polymerization exotherm showed a decrease in the former and an increase in the latter, because of the introduction of a more reactive monomer in the bone cement formulation.
Departamento Ciencia y Tecnología de Polímeros, Facultad de Química, UPV/EHU, San Sebastián, Spain.
B
B
Pascual
I
I
Goñi
M
M
Gurruchaga
D001843:Bone Cements; D004548:Elasticity; D006801:Humans; D066298:In Vitro Techniques; D008422:Materials Testing; D008689:Methacrylates; D020366:Methylmethacrylate; D008855:Microscopy, Electron, Scanning; D013696:Temperature; D013718:Tensile Strength; D013997:Time Factors; D014783:Viscosity; D014867:Water
D001843:Bone Cements; D008689:Methacrylates; D014867:Water; D020366:Methylmethacrylate; C032802:hydroxypropyl methacrylate