[Me]
The long-postulated reactive intermediates of polar fluoride-inititated trifluoromethylations with Me(3)SiCF(3) (see scheme) were identified by NMR spectroscopy as [Me(3)Si(CF(3))F](-) and [Me(3)Si(CF(3))(2)](-)(.)
Maggiarosa
N
Institut für Anorganische Chemie der Universität, Greinstrasse 6, D-50939 Köln (Germany).
Tyrra
W
Naumann
D
Kirij
NV
Yagupolskii
YL