Glycoside primers of Psittacanthus cucullaris.
Bioassay-directed chromatographic separation of the ethyl acetate extract of the whole plant of Psittacanthus cucullaris afforded a new phenolic xyloside, ellagic acid-4-O-beta-xyloside-3,3', 4'-trimethyl ether (1) together with four known compounds, ellagic acid-4-O-beta-xyloside-3,3'-dimethyl ether (2), gallic acid, beta-sitosterol, and beta-sitosterol beta-D-glucoside. The structure of the new compound was determined by spectroscopic methods. Like other beta-D-xylosides, compounds 1 and 2 stimulated the formation of glycosaminoglycan chains when fed to the cultured Chinese hamster ovary cells.
Sinha
A
A
Division of Cellular and Molecular Medicine, Glycobiology Program, University of California, San Diego, 9500 Gilman Drive, La Jolla, California 92093-0687, USA.
Taylor
W H
WH
Khan
I H
IH
McDaniel
S T
ST
Esko
J D
JD
D000818:Animals; D016466:CHO Cells; D006224:Cricetinae; D006025:Glycosaminoglycans / Q000096:biosynthesis; D006027:Glycosides / Q000302:isolation & purification / Q000494:pharmacology*; D009682:Magnetic Resonance Spectroscopy; D010430:Pentosyltransferases / Q000172:deficiency / Q000235:genetics; D010568:Peru; D010944:Plants / Q000737:chemistry*; D013268:Stimulation, Chemical; D000097608:UDP Xylose-Protein Xylosyltransferase
D006025:Glycosaminoglycans; D006027:Glycosides; D010430:Pentosyltransferases; D000097608:UDP Xylose-Protein Xylosyltransferase