Isolation and Structure of the OCNCO(+) Ion.
Strongly bent at the nitrogen atom (130.7 degrees ), the OCNCO(+) ion (see structure) is the closest relative to carbon suboxide OCCCO. According to calculations the linear OCNCO(+) ion is only a few kJ mol(-1) higher in energy.
Bernhardi
I
Institut für Anorganische und Analytische Chemie der Freien Universität, Fabeckstrasse 34-36, D-14195 Berlin (Germany).
Drews
T
Seppelt
K