title: Two oleanene glycosides from the aerial parts of Caltha polypetala.
abstract: Two new oleanene glycosides (1-2) possessing hederagenin as the aglycone were isolated from the methanolic extract of the aerial parts of Caltha polypetala together with four known glycosides. The saccharide portion linked to C-3 of the aglycone is made up of alpha-L-arabinopyranose, alpha-L-rhamnopyranose and galactopyranose in the new compounds; while compound 1 possesses linked to C-28 a trisaccharide moiety made up of two beta-D-glucopyranose and one alpha-L-rhamnopyranose unit, in compound 2 the 28-COOH group is free. The structures were elucidated by 1D and 2D NMR experiments including 1H-1H (DQF-COSY, 1D-TOCSY, 2D-ROESY) and 1H-13C (HSQC, HMBC) spectroscopy.
authors.affiliation: Department of Pharmacognosy, Faculty of Pharmacy, Gazi University, Ankara, Turkey.
authors.forename: T
authors.initials: T
authors.lastname: Baykal
authors.forename: E
authors.initials: E
authors.lastname: Bedir
authors.forename: I
authors.initials: I
authors.lastname: Calis
authors.forename: R
authors.initials: R
authors.lastname: Aquino
authors.forename: S
authors.initials: S
authors.lastname: Piacente
authors.forename: C
authors.initials: C
authors.lastname: Pizza
mesh_terms: D006027:Glycosides / Q000737:chemistry* / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy; D010944:Plants / Q000737:chemistry*; D016339:Spectrometry, Mass, Fast Atom Bombardment
chemical_list: D006027:Glycosides