title: New Types of Stable Aldehydes: Formylphosphane and Formylphosphane Oxide.
abstract: The reactivity of the formyl group in alpha-phosphorus-substituted aldehydes 1 can be tuned by adjusting the coordination number of the phosphorus atom. When X is a lone pair, the formylphosphanes obtained are stable compounds, whereas when X=O a relatively unstable formylphosphane oxide is produced. R=iPr(2)N, cHex(2)N.
authors.affiliation: Laboratoire d'Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier, 118, route de Narbonne, F-31062 Toulouse cedex 04 (France).
authors.initials: D
authors.lastname: Amsallem
authors.initials: H
authors.lastname: Gornitzka
authors.initials: A
authors.lastname: Baceiredo
authors.initials: G
authors.lastname: Bertrand