The Rotational Spectrum of Ar-SiH(4) and Ar-SiD(4).
Microwave spectra of Ar-(28)SiH(4), Ar-(29)SiH(4), Ar-(30)SiH(4), and Ar-(28)SiD(4) were recorded using a pulsed molecular beam Fourier transform microwave spectrometer. The K = 0 and K = 1 components of the J = 3 <-- 2 through the J = 7 <-- 6 transitions were measured and assigned in the 9-24 GHz region. For the primary (28)Si isotopic species, Ar-(28)SiH(4) and Ar-(28)SiD(4), a K = 0, A symmetry, a K = 0, F symmetry, a doubly degenerate K = 1, E symmetry, and an l/K-doubled, K = 1, F symmetry rotational progression are observed at the approximately 1 K rotational temperature of the supersonic expansion. The rotational constants for the K = 0, A state for Ar-(28)SiH(4) and Ar-(28)SiD(4) are B = 1700.40624(9) MHz and 1630.687073(22) MHz and the centrifugal distortion constants are D(J) = 29.089(3) and 20.0198(8) kHz and H(J) = -1.91(3) and -0.851(8) Hz, respectively, where type A expanded uncertainties with a coverage factor, k = 3, are given here and elsewhere. The values of the rotational constants for the K = 0, A, and F states and for the K = 1, E state are in good agreement with the infrared-determined values for Ar-(28)SiH(4). The measured linear Stark effect of the E-state transitions was analyzed to give a dipole moment of 9.24(8) x 10(-32) C. m [0.0277(2) D]. Copyright 1999 Academic Press.
Kawashima
Y
Department of Applied Chemistry, Kanagawa Institute of Technology, 1030 Shimo-ogino, Atsugi, Kanagawa, 243-0292, Japan
Suenram
RD
Fraser
GT
Lovas
FJ
Hirota
E