title: Quantification of Spatial Correlation in Porous Media and Its Effect on Mercury Porosimetry.
abstract: In many porous media the grains are packed in a disordered manner, rather than in regular lattices. Theoretical treatments of the properties of these media often assume that because there is no regular lattice, the pore space between grains is completely spatially disordered. Here we present an analysis of a real granular medium (a close packing of equal spheres) which shows that, contrary to the popular assumption, the pore space is spatially correlated. The origin of this pore space correlation is the strong spatial correlation of grain locations, which is a feature of all dense granular media. Our analysis relies on physically representative network models of the pore space constructed from knowledge of the grain locations. Simulated drainage experiments on these networks agree with mercury porosimetry experiments in simple sandstones, whereas simulations in uncorrelated but otherwise identical networks do not. Thus the spatial correlation inherent in the pore space of simple porous media significantly affects mercury porosimetry. Deriving pore size distributions from mercury porosimetry without considering spatial correlation can give misleading results. The likelihood of error is compounded if such pore size distributions are used to estimate transport coefficients such as permeability, diffusivity, and electrical conductivity.
authors.affiliation: Colloid Science Group, Eniricerche, via F. Maritano, 26, San Donato Milanese, 20097, Italy
authors.initials: S
authors.lastname: Bryant
authors.initials: G
authors.lastname: Mason
authors.initials: D
authors.lastname: Mellor