title: A method for detecting breakthrough of organic solvent vapors in a charcoal tube using semiconductor gas sensors.
abstract: This study developed a method for detecting organic vapors that break through charcoal tubes, using semiconductor gas sensors as a breakthrough detector of vapors. A glass column equipped with two sensors was inserted in Teflon tubing, and air containing organic vapor was introduced at a constant flow rate. After the output signal of the sensors became stable, a charcoal tube was inserted into the tubing at the upstream of the sensors. The resistance of the sensors was collected temporally in an integrated circuit (IC) card. The vapor concentration of the air near the sensors was measured with a gas chromatograph (GC) equipped with a flame ionization detector (FID) at intervals of 5 minutes to obtain the breakthrough curve. When the relative humidity was zero, the output signals of the sensors began to change before the breakthrough point (1% breakthrough time). This tendency was almost the same for methyl acetate, ethyl acetate, isopropyl alcohol (IPA), toluene, and chloroform. For dichloromethane and 1,1,1-trichloroethane, the time when the sensor output signals began to rise was almost the same as the breakthrough point. When the relative humidity was 80 percent, the sensors could also detect many vapors before the breakthrough point, but they could not perceive dichloromethane and chloroform vapors. A personal sampling system with a breakthrough detector was developed and its availability is discussed.
authors.affiliation: School of Health Sciences, University of Occupational and Environmental Health, Japan.
authors.forename: H
authors.initials: H
authors.lastname: Hori
authors.forename: Y
authors.initials: Y
authors.lastname: Noritake
authors.forename: H
authors.initials: H
authors.lastname: Murobushi
authors.forename: T
authors.initials: T
authors.lastname: Higashi
authors.forename: I
authors.initials: I
authors.lastname: Tanaka
mesh_terms: D016902:Air Pollution, Indoor / Q000032:analysis*; D002606:Charcoal; D004784:Environmental Monitoring / Q000295:instrumentation; D006801:Humans; D009930:Organic Chemicals / Q000032:analysis*; D012666:Semiconductors; D012997:Solvents / Q000032:analysis*
chemical_list: D009930:Organic Chemicals; D012997:Solvents; D002606:Charcoal