title: Isotropic mixing, sign discrimination, and sensitivity in solid-state wideline heteronuclear correlation experiments.
abstract: A variant of the solid-state wideline heteronuclear NMR correlation experiment is described which overcomes some of the drawbacks associated with the routine experiment. The modified experiment results in spectra which are sign-discriminated in the omega(1) dimension, but without the loss in sensitivity expected for a standard hypercomplex implementation. In favorable cases sensitivity enhancements over comparable routine experiments are obtained. As well as these advantages, the method retains the selectivity of modified WISE experiments proposed previously which give spectra containing correlations between directly bonded nuclei only.
authors.affiliation: School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, United Kingdom.
authors.forename: S L
authors.initials: SL
authors.lastname: Oliver
authors.forename: J J
authors.initials: JJ
authors.lastname: Titman
mesh_terms: D002247:Carbon Isotopes; D003460:Crystallization; D005583:Fourier Analysis; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008962:Models, Theoretical; D020959:Polyethylene / Q000737:chemistry; D012680:Sensitivity and Specificity
chemical_list: D002247:Carbon Isotopes; D020959:Polyethylene