First synthesis of optically active benzocyclobutene and biphenylene-based unusual alpha-amino acid derivatives.
Various optically pure benzocyclobutene and biphenylene-based alpha-amino acid derivatives are prepared in a very high diastereoselective manner via a six step sequence using Schöllkopfchiral auxiliary.
Kotha
S
S
Department of Chemistry, Indian Institute of Technology, Mumbai.
Screenivasachary
N
N
Halder
S
S
D000596:Amino Acids / Q000138:chemical synthesis* / Q000737:chemistry; D001713:Biphenyl Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D011083:Polycyclic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D000596:Amino Acids; D001713:Biphenyl Compounds; D011083:Polycyclic Compounds; C079040:benzocyclobutene