Catalysis as a key technology for the environmentally benign synthesis of amines and amino acids.
The rhodium-catalyzed amination of aromatic olefins and the palladium-catalyzed amidocarbonylation of aldehydes are presented as new atom-efficient methods to yield biologically interesting amines and N-acyl amino acids.
Beller
M
M
Institut für Organische Katalyseforschung an der Universität Rostock e.V., Buchbinderstrasse 5-6, 18055 Rostock, Germany.
D000447:Aldehydes / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry; D000577:Amides / Q000737:chemistry; D000588:Amines / Q000138:chemical synthesis*; D000596:Amino Acids / Q000138:chemical synthesis*; D002248:Carbon Monoxide / Q000737:chemistry; D002384:Catalysis; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D006801:Humans; D006868:Hydrolysis; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry; D013678:Technology, Pharmaceutical
D000447:Aldehydes; D000475:Alkenes; D000577:Amides; D000588:Amines; D000596:Amino Acids; D010165:Palladium; D002248:Carbon Monoxide; D012238:Rhodium