Controlled Arrangement of Supramolecular Metal Coordination Arrays on Surfaces.
Metallo-supramolecular systems have been adsorbed in a controlled way onto graphite surfaces and visualized with molecular resolution for the first time. A parallel or orthogonal arrangement of the metal coordination arrays is evident depending on the specific ligands (see picture). Furthermore, simple nanomanipulations were performed by extracting single grids from the layer.
Semenov
A
Organische Chemie III/Makromolekulare Chemie der Universität, D-89081 Ulm (Germany).
Spatz
JP
Möller
M
Lehn
JM
Sell
B
Schubert
D
Weidl
CH
Schubert
US