(Z)-3-hexenyl and trans-linalool 3,7-oxide beta-primeverosides isolated as aroma precursors from leaves of a green tea cultivar.
6-O-beta-D-Xylopyranosyl-beta-D-glucopyranosides (beta-primeverosides) of (Z)-3-hexenol and trans-linalool 3,7-oxide were newly isolated from fresh leaves of a tea cultivar (Camellia sinensis var. sinensis cv. Yabukita). In addition, the already identified beta-primeverosides of benzyl alcohol, methyl salicylate, and trans-linalool 3,6-oxide from an oolong tea cultivar were isolated from the Yabukita cultivar. It was confirmed that all aglycones of the linalool oxide glycosides isolated here were of the optically active S-form by chiral GC after enzymatic hydrolysis with glycosidase.
Nishikitani
M
M
Department of Nutrition and Food Science, Ochanomizu University, Tokyo, Japan.
Wang
D
D
Kubota
K
K
Kobayashi
A
A
Sugawara
F
F
D000080462:Acyclic Monoterpenes; D001592:Benzyl Alcohols / Q000302:isolation & purification; D006027:Glycosides / Q000737:chemistry / Q000302:isolation & purification*; D009682:Magnetic Resonance Spectroscopy; D039821:Monoterpenes; D009812:Odorants; D016339:Spectrometry, Mass, Fast Atom Bombardment; D013662:Tea / Q000737:chemistry*; D013729:Terpenes / Q000302:isolation & purification
D000080462:Acyclic Monoterpenes; D001592:Benzyl Alcohols; D006027:Glycosides; D039821:Monoterpenes; D013662:Tea; D013729:Terpenes; C069904:benzyl alcohol xylopyranosyl-(1-6)-glucopyranoside; C090216:linalool 3,6-oxide 6-O-xylopyranosylglucopyranoside