title: 1,2-Hydride Shift in the Biosynthesis of Pinguisane-type Sesquiterpenes.
abstract: A (2)H-NMR analysis of 6α-hydroxy-3-oxo-pinguis-5(10)-ene-11,6-olide produced by axenic culture of liverwort Aneura pinguis in the presence of [4-(2)H2]-labeled mevalonate clarified the presence of a 1,2-hydride shift and retention of deuterium at the C-4 position in the biosynthesis of pinguisane-type sesquiterpenes from FPP.
authors.affiliation: a Department of Bioresource Science, Obihiro University of Agriculture and Veterinary Medicine.
authors.forename: H
authors.initials: H
authors.lastname: Tazaki
authors.affiliation: a Department of Bioresource Science, Obihiro University of Agriculture and Veterinary Medicine.
authors.forename: T
authors.initials: T
authors.lastname: Iwasaki
authors.affiliation: b Basic Research Div. 3, Takasago International Corporation.
authors.forename: Y
authors.initials: Y
authors.lastname: Kawakami
authors.affiliation: a Department of Bioresource Science, Obihiro University of Agriculture and Veterinary Medicine.
authors.forename: K
authors.initials: K
authors.lastname: Nabeta