title: Influence of soil moisture on sorption and degradation of hexazinone and simazine in soil.
abstract: Sorption and degradation rates of hexazinone and simazine on soil were determined in a sandy loam soil incubated, during 44 days, at 25 degrees C with moisture contents ranging from 4% to 18%. Herbicide levels in soil solution were also measured, after extraction of this solution by a centrifugation method. All experiments were conducted with treated soil in plastic columns, and the results showed that this method is suitable for the simultaneous study of pesticide sorption and degradation in soil at different environmental conditions. In general, sorption of both herbicides was higher for aged herbicide residues compared to recently applied herbicides, and soil subjected to drying and rewetting cycles had the highest sorption values. K(f) values ranged from 0.5 to 1.2 for simazine and from 0.2 to 0.4 for hexazinone. Degradation rates increased with soil moisture content for both herbicides, and drying-rewetting of soil yielded degradation rates slower than that obtained at 10% soil moisture content. Hexazinone concentration in soil solution decreased with incubation time faster than simazine.
authors.affiliation: Departamento Uso Sostenible del Medio Natural, INIA, Apdo 8111, 28080 Madrid, Spain.
authors.forename: A I
authors.initials: AI
authors.lastname: García-Valcárcel
authors.forename: J L
authors.initials: JL
authors.lastname: Tadeo
mesh_terms: D006540:Herbicides / Q000737:chemistry*; D007700:Kinetics; D012839:Simazine / Q000737:chemistry*; D012987:Soil; D014227:Triazines / Q000737:chemistry*; D014867:Water
chemical_list: D006540:Herbicides; D012987:Soil; D014227:Triazines; D014867:Water; D012839:Simazine; C025641:hexazinone