The Macromolecular Route to Chiral Amplification.
Cooperative phenomena, described by one-dimensional statistical physical methods, are observed between the enantiomeric characteristics of monomeric materials and the polymers they produce. The effect of minute energies associated with this amplified chirality, although currently not interpretable, can be easily measured. Nonlinear relationships between enantiomeric excess or enantiomeric content and polymer properties may offer the possibility of developing chiral catalysts and chiral chromatographic materials in which the burden of large enantiomeric excess or content may be considerably alleviated. New approaches to information and sensor technology may become possible.
Green
MM
Herman F. Mark Polymer Research Institute, Polytechnic University Six Metrotech Center, Brooklyn, New York 11201 (USA).
Park
JW
Sato
T
Teramoto
A
Lifson
S
Selinger
RL
Selinger
JV