Identification of character impact odorants of different soybean lecithins.
The potent odorants of standardized, enzymatically hydrolyzed, and deoiled soybean lecithins were characterized systematically by combined gas chromatography/mass spectrometry and olfactometry. Sixty-one odorants were identified; 53 of these odor-active compounds have not previously been reported as odorants of soybean lecithin flavor. By aroma extract dilution analysis and modified combined hedonic and response measurement the following odorants showed the highest flavor dilution factors and CHARM values: (E,E)-2, 4-decadienal (deep-fried), (E)-beta-damascenone (apple-like), 2, 3-diethyl-5-methylpyrazine (roasty, earthy), (E)-2-nonenal (cardboard-like), trans-4,5-epoxy-(E)-2-decenal (metallic), 1-nonen-3-one (mushroom-like), 2-ethyl-3,5-dimethylpyrazine (roasty, earthy), and 1-octen-3-one (mushroom-like). Enzymatic hydrolysis intensified especially the roasty sensation of 2, 3-diethyl-5-methylpyrazine, whereas deoiling effected a general significant decrease in olfactory perception on the nitrogen-containing compounds. In addition, sensory profiles of nasal and retronasal lecithin odor were performed.
Stephan
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Institute of Biochemistry and Food Chemistry, University of Hamburg, Grindelallee 117, D-20146 Hamburg, Germany. fc6a080@chemie.chemie.uni-hamburg.de
Steinhart
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H
D002849:Chromatography, Gas; D009812:Odorants; D010713:Phosphatidylcholines / Q000737:chemistry* / Q000145:classification; D013025:Glycine max / Q000737:chemistry*
D010713:Phosphatidylcholines