title: Binding mechanism of heavy metals biosorption by Pycnoporus sanguineus.
abstract: Non-living biomass of Pycnoporus sanguineus has an ability to take up lead,copper and cadmium ions from an aqueous solution. The role played by various functional groups in the cell wall and the mechanism uptake of lead, copper and cadmium by Pycnoporus sanguineus were investigated. Modification of the functional groups such as lipids, carboxylic and amino was done through chemical pretreatment in order to study their role in biosorption of metal ions. Results showed that the chemical modification of these functional groups has modified the ability of biomass to remove lead, copper and cadmium ions from the solution. Scanning electron microscopy was also used to study the morphological structure of the biomass before and after adsorption. The electron micrograph indicated that the structure of biomass changed due to the adsorption of the metals onto the cell walls. Furthermore, the X-ray energy dispersion analysis (EDAX) showed that the calcium ion present in the cell wall of biomass was released and replaced by lead ions. This implied that an ion exchange is one of the principal mechanisms for metal biosorption.
authors.affiliation: School of Chemical Engineering, Universiti Sains Malaysia, Seri Iskandar, Perak Darul Ridzuan.
authors.lastname: Mashitah
authors.forename: Z
authors.initials: Z
authors.lastname: Zulfadhly
authors.forename: S
authors.initials: S
authors.lastname: Bhatia
mesh_terms: D000327:Adsorption; D000588:Amines; D018533:Biomass; D002104:Cadmium; D002264:Carboxylic Acids; D002625:Chemistry, Organic; D003300:Copper; D005658:Fungi / Q000378:metabolism*; D007474:Ion Exchange; D008055:Lipids; D019216:Metals, Heavy / Q000493:pharmacokinetics*; D055601:Organic Chemistry Phenomena; D017550:Spectroscopy, Fourier Transform Infrared; D018508:Water Purification / Q000379:methods*; D014961:X-Ray Diffraction
chemical_list: D000588:Amines; D002264:Carboxylic Acids; D008055:Lipids; D019216:Metals, Heavy; D002104:Cadmium; D003300:Copper