Take the Right Catalyst: Palladium-Catalyzed C-C, C-N, and C-O Bond Formation on Chloroarenes.
Unreactive chloroarenes have been outwitted: The key to successful C-C, C-N, and C-O bond formation on chloroarenes is the development and optimization of suitable catalysts. Electron-rich alkylphosphanes are mandatory as ligands in these palladium-catalyzed reactions.
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BASF AG, Hauptlaboratorium, ZHF/D, A30, 67056 Ludwigshafen (Germany).