Structural analysis of three sulfated oligosaccharides isolated from human milk.
The structures of two sulfated octasaccharides and one sulfated nonasaccharide isolated from human milk have been investigated. Using 13C and 1H NMR spectroscopy and ESMS, the following structures 1-3 were established: [formula: see text].
Guérardel
Y
Y
Laboratoire de Chimie Biologique, Université des Sciences et Technologies de Lille, Villeneuve d'Ascq, France.
Morelle
W
W
Plancke
Y
Y
Lemoine
J
J
Strecker
G
G
D000818:Animals; D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D005260:Female; D005643:Fucose / Q000737:chemistry; D006801:Humans; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D008895:Milk, Human / Q000737:chemistry*; D008969:Molecular Sequence Data; D009844:Oligosaccharides / Q000737:chemistry* / Q000302:isolation & purification; D013463:Sulfuric Acid Esters / Q000737:chemistry* / Q000302:isolation & purification
D009844:Oligosaccharides; D013463:Sulfuric Acid Esters; D005643:Fucose