title: First and Highly Diastereoselective Synthesis of Palladepanes.
abstract: Unexpected stability is observed for the palladacycloheptane rac-2, which is obtained as major product and single diastereomer from the cyclization of 1 and Pd(0). Up to a temperature of 50 degrees C 2 shows neither reductive elimination nor intramolecular insertion of another olefin.
authors.affiliation: Institut für Organische Chemie der Universität, Marie-Curie-Strasse 11, D-60439 Frankfurt (Germany).
authors.initials: AS
authors.lastname: Hashmi
authors.lastname: Rivas Nass A
authors.initials: JW
authors.lastname: Bats
authors.initials: M
authors.lastname: Bolte