Organotitanium Fluorides as Matrices for Trapping Molecular ZnF(2) and MeZnF.
Trapped as molecular solids, the transition metal fluorides ZnF(2) and MeZnF-the latter isolated for the first time-exist as adducts in [(Cp*TiF(3))(8)(ZnF(2))(3)] (1) and [(Cp*TiF(3))(4)(MeZnF)(2)] (2), respectively. Compounds 1 and 2 were obtained in reactions of [Cp*TiF(3)] (Cp*=C(5)Me(5)) with ZnMe(2) and Me(3)SnF in various molar ratios. The single-crystal structure of 1 is shown here; the unlabeled circles are F atoms.
Yu
P
Institut für Anorganische Chemie der Universität, Tammannstrasse 4, D-37077 Göttingen (Germany).
Müller
P
Roesky
HW
Noltemeyer
M
Demsar
A
Usón
I