title: Ga(22)
abstract: A metal-rich intermediate was captured prior to metal formation by means of a substitution reaction during the disproportionation of a metastable Ga(I) bromide solution. In the thus obtained Ga(22) cluster (see structure), the central gallium atom displays the unusual coordination number of 13.
authors.affiliation: Institut für Anorganische Chemie der Universität (TH), Engesserstraße, Geb. 30.45, D-76128 Karlsruhe (Germany).
authors.initials: A
authors.lastname: Schnepf
authors.initials: E
authors.lastname: Weckert
authors.initials: G
authors.lastname: Linti
authors.initials: H
authors.lastname: Schnöckel