Synthesis and surface-active properties of glycosyl carbamates and thioureas.
Several amphiphilic glycosyl carbamates, glycosyl thiocarbamates and glycosylthioureas were prepared by addition of the anomeric hydroxyl group of acetylated glycosyl derivatives to alkyl isocyanates, or by reaction of glycosyl isothiocyanates with alcohols or amines. The solubility, critical micelle concentrations and detergent efficiency for the extraction of proteins of these compounds were evaluated and compared.
Prata
C
C
Laboratoire de Chimie Bioorganique et des Systèmes Moléculaires Vectoriels, Faculté des Sciences d'Avignon, France.
Mora
N
N
Lacombe
J M
JM
Maurizis
J C
JC
Pucci
B
B
D002219:Carbamates / Q000138:chemical synthesis*; D006001:Glycoconjugates / Q000138:chemical synthesis*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D012995:Solubility; D013499:Surface Properties; D013500:Surface Tension; D013501:Surface-Active Agents / Q000138:chemical synthesis*; D013859:Thiocarbamates / Q000138:chemical synthesis; D013890:Thiourea / Q000031:analogs & derivatives* / Q000138:chemical synthesis
D002219:Carbamates; D006001:Glycoconjugates; D013501:Surface-Active Agents; D013859:Thiocarbamates; D013890:Thiourea