Molecular complexes of iron violurate with donor amines.
The acceptor character of iron violurate complex was studied by examining the electronic, vibrational and 1H-nmr spectra of the charge transfer molecular complexes formed between the iron violurate as pi-acceptor and some amines as n-donors. Elemental analysis and spectral results establishes 1:2 stoichiometry of the adducts. The study has been conducted at different temperatures. Values of delta G degree, delta H degree and delta S degree have been calculated from the self-consistent values of the formation constants (KCT). Ionization potentials of the donors have been calculated and the solvent effect on the KCT values is discussed. The antibacterial and antifungal effects of the molecular complexes were studied.
Belal
A A
AA
Department of Chemistry, Faculty of Science, Aswan, Egypt.
Abdel-Rahman
L H
LH
D000588:Amines / Q000737:chemistry* / Q000378:metabolism; D000890:Anti-Infective Agents / Q000737:chemistry* / Q000494:pharmacology; D000935:Antifungal Agents / Q000737:chemistry / Q000494:pharmacology; D001463:Barbiturates / Q000737:chemistry* / Q000378:metabolism / Q000494:pharmacology*; D004048:Diethylamines / Q000737:chemistry / Q000378:metabolism; D004353:Drug Evaluation, Preclinical; D005021:Ethylamines / Q000737:chemistry / Q000378:metabolism; D010880:Piperidines / Q000737:chemistry; D012997:Solvents; D013056:Spectrophotometry, Ultraviolet; D013329:Structure-Activity Relationship; D013816:Thermodynamics; D014732:Vibration
D000588:Amines; D000890:Anti-Infective Agents; D000935:Antifungal Agents; D001463:Barbiturates; D004048:Diethylamines; D005021:Ethylamines; D010880:Piperidines; D012997:Solvents; C094277:violuric acid; C032727:piperidine; C034281:diethylamine; C016162:triethylamine