Accurate intensities of broad NMR lines from composite pulse experiments.
Accurate determination of integral intensities of broad lines is difficult when spin relaxation during the applied pulses cannot be neglected and/or when ringing of the tank circuit interferes with the signal. Here we present an extension of the analytical solution of the generalized Bloch equations (G. A. Morris and P. B. Chilvers, J. Magn. Reson. A 107, 236 (1994)), which is then used to evaluate the signal intensity obtained in a composite pulse experiment designed to cancel ringing effects. Comparing intensities of broad and narrow (81)Br spectral lines tests and proves the accuracy of this approach.
Hedin
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N
Department of Chemistry, Royal Institute of Technology, Stockholm, SE-100 44, Sweden.
Furó
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I
D001966:Bromine; D007554:Isotopes; D009682:Magnetic Resonance Spectroscopy
D007554:Isotopes; D001966:Bromine