A microwave-induced plasma based on microstrip technology and its use for the atomic emission spectrometric determination of mercury with the aid of the cold-vapor technique.
A new low-power, small-scale 2.45 GHz microwave plasma source at atmospheric pressure for atomic emission spectrometry based on microstrip technology is described. The MicroStrip Plasma (MSP) source was produced in microstrip technology on a fused-silica wafer and designed as an element-selective detector for miniaturized analytical applications. The electrodeless microwave-induced plasma (MIP) operates at microwave input power of 10-40 W and gas flows of 50-1000 mL.min-1 of Ar. Rotational (OH) and excitation (Fe) temperatures were found to be 650 and 8000 K, respectively. Spatially resolved measurements of the Hg I 253.7-nm atomic emission line with an electronic slitless spectrograph (ESS) showed that a cylindrically symmetric plasma with a diameter of about 1 mm is obtained. With the MSP, Hg could be determined by applying the flow injection cold vapor (FI-CV) technique with a detection limit of 50 pg.ml-1. In terms of the relative standard deviation, a time stability of < 1.4% for 45 replicates within 80 min can be realized at a concentration level of 10 ng.ml-1 of Hg. Hg could be determined in the leachate of a certified standard reference soil (STSD-4) obtained by treatment with aqua regia at the 930 +/- 76 ng.g-1 level. Results obtained by calibration with aqueous solutions of Hg and with standard addition were found to be in good agreement with those of cold-vapor atomic absorption spectrometry.
Engel
U
U
Fachbereich Chemie, Universität Dortmund, Germany.
Bilgiç
A M
AM
Haase
O
O
Voges
E
E
Broekaert
J A
JA
D004566:Electrodes; D008628:Mercury / Q000032:analysis*; D008872:Microwaves; D013054:Spectrophotometry, Atomic / Q000295:instrumentation* / Q000379:methods
D008628:Mercury