[Pt]
The intermediacy of CO/NO substitution in the condensation of [Pt(19)(CO)(22)](4-) into [Pt(38)(CO)(44)](2-) (structure shown) has been demonstrated. Two high-nuclearity carbonyl metal clusters, including one with an unprecedented nitrosyl ligand, have been synthesized and structurally characterized.
Ceriotti
A
Dipartimento di Chimica Inorganica, Metallorganica e Analitica e Centro CNR, Università di Milano, via G. Venezian 21, I-20133 Milano (Italy).
Masciocchi
N
Macchi
P
Longoni
G