Carbocyclic Ring Closure of Unsaturated S-, Se-, and C-Aryl Glycosides.
Triisobutylaluminum-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons-such as C-aryl glycoside 1, or O-, S-, and Se-glycosides-provides direct access to highly functionalized cyclohexane derivatives such as 2.
Sollogoub
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Département de Chimie Associé au CNRS, Ecole Normale Supérieure 24 rue Lhomond, 75231 Paris cedex 05 (France).
Mallet
JM
Sinaÿ
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