title: Enantioselective Addition of Allylic Trimethoxysilanes to Aldehydes Catalyzed by p-Tol-BINAP small middle dotAgF.
abstract: Catalytic asymmetric allylation of aldehydes with allylic trimethoxysilanes was achieved with the p-Tol-BINAP small middle dotAgF complex as catalyst [Eq. (a); p-Tol-BINAP=2,2'-bis(di-p-tolylphosphanyl)-1,1'-binaphthyl)]. High anti and enantioselectivities were obtained in the reaction with crotyltrimethoxysilane, irrespective of the configuration at the double bond.
authors.affiliation: Graduate School of Engineering, Nagoya University, CREST, Japan Science and Technology Corporation (JST), Chikusa, Nagoya 464-8603 (Japan).
authors.initials: A
authors.lastname: Yanagisawa
authors.initials: H
authors.lastname: Kageyama
authors.initials: Y
authors.lastname: Nakatsuka
authors.initials: K
authors.lastname: Asakawa
authors.initials: Y
authors.lastname: Matsumoto
authors.initials: H
authors.lastname: Yamamoto