A Facile Route to Group 13 Difluorodiorganometalates:
A facile synthesis utilizing tetra-n-butylammonium hydrogen difluoride and Group 13 alkyl compounds leads to the soluble salts 1 - 4. Compound 1 is the smallest difluoro-diorganoaluminate so far characterized. The corresponding gallium and indium derivatives 3 and 4 are not sensitive to moisture.
Roesky
HW
Institut für Anorganische Chemie der Universität Tammannstrasse 4, 37077 Göttingen (Germany).
Stasch
A
Hatop
H
Rennekamp
C
H Hamilton D
Noltemeyer
M
Schmidt
HG