title: A Metamagnetic Two-Dimensional Molecular Material with Nickel(II) and Azide.
abstract: Bridging azido ligands transmit both ferro- and antiferromagnetic interactions. The sheetlike structured complex [Ni(µ-N(3))(2)(N,N-Et(2)-N'-Me-en)](n) (see picture) exhibits a range of magnetic behaviors at low temperature. Short-range ferromagnetic and three-dimensional antiferromagnetic ordering compete, giving metamagnetic behaviors. N,N-Et(2)-N'-Me-en=N,N-diethyl-N'-methylethylenediamine.
authors.affiliation: Departament de Química Inorgànica Universitat de Barcelona, Diagonal 647, 08028 Barcelona (Spain).
authors.initials: M
authors.lastname: Monfort
authors.initials: I
authors.lastname: Resino
authors.initials: J
authors.lastname: Ribas
authors.initials: H
authors.lastname: Stoeckli-Evans