Synthesis and Structures of 1,3,5,7-Tetraazaheptatrienylsodium and -thallium(I).
Highly stable multinuclear metal complexes with planar [{Me(3)SiNC(H)N}(2)CH](-) ligands are obtained from MN(SiMe(3))(2) (M=Na, Tl) and 1,3,5-triazine (structure for Tl shown in the picture). These complexes display unusual structural features such as a pseudo-C(3) symmetry (Na complex).
Boesveld
WM
The Chemistry Laboratory School of Chemistry, Physics and Environmental Science University of Sussex Brighton BN1 9QJ (UK).
Hitchcock
PB
Lappert
MF
Nöth
H