Biotransformation of (4E,8R)-caryophyll-4(5)-en-8-ol by Botrytis cinerea.
Biotransformation of (4E,8R)-caryophyll-4(5)-en-8-ol (1) with Botrytis cinerea afforded 14 products (3-16). Thirteen of these (4-16) are described here for the first time. The main reaction paths involved the isomerization of the double bond at C-4/C-5 and hydroxylation of methyl groups.
Durán-Patrón
R
R
Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Cádiz, Apdo. 40, 11510 Puerto Real, Cádiz, Spain.
Aleu
J
J
Hernández-Galán
R
R
Collado
I G
IG
D001711:Biotransformation; D020171:Botrytis / Q000378:metabolism*; D015394:Molecular Structure; D012717:Sesquiterpenes / Q000737:chemistry / Q000378:metabolism*; D013057:Spectrum Analysis
D012717:Sesquiterpenes