Synthesis of selected aminodeoxy analogues of galabiose and globotriose.
Six aminodeoxy 2-(trimethylsilyl)ethyl (Me3SiEt) glycoside analogues of galabiose (4'- and 6'-aminodeoxy) and globotriose (6"-, 4"-, 2"-, and 6'-aminodeoxy) were synthesized by glycosylation of protected Me3SiEt galactoside and lactoside acceptors with azido-substituted monosaccharide donors, followed by reduction of the azido groups and removal of the protecting groups.
Hansen
H C
HC
Center for Chemistry and Chemical Engineering, Lund University, Sweden.
Magnusson
G
G
D004187:Disaccharides / Q000737:chemistry*; D006031:Glycosylation; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D014312:Trisaccharides / Q000737:chemistry*
D004187:Disaccharides; D014312:Trisaccharides; C032103:4-O-alpha-D-galactopyranosyl-D-galactose; C113460:globotriose