title: Immobilization of TADDOL with a High Degree of Loading on Porous Silica Gel and First Applications in Enantioselective Catalysis.
abstract: The versatile TADDOL moiety has been immobilized for the first time on an inorganic support (highly porous silica gel). This gives access to Ti - Lewis acids (see picture), which turn out to be very efficient in two standard enantioselective reactions. X=OiPr, OTos.
authors.affiliation: Laboratorium für Organische Chemie der Eidgenössischen Technischen Hochschule Zürich ETH-Zentrum, Universitätstrasse 16, CH-8092 Zürich (Switzerland).
authors.initials: A
authors.lastname: Heckel
authors.initials: D
authors.lastname: Seebach