title: Use of abiotic oxidative-reductive technologies for remediation of munition contaminated soil in a bioslurry reactor.
abstract: The possibility to clean-up TNT contaminated soil, 400 mg TNT kg-1, surrounding Nebraska Ordnance Plant's (US), below the USEPA goal of 17.2 mg TNT kg-1 using Fenton oxidation (Fe2+ + H2O2), Fe0 reduction, combined Fe0/H2O2 and CaO2 was explored at pilot scale. Treatments were performed in a 60 l airlift reactor, which was a prototype of larger commercial unit. All the treatments reduced TNT soil concentration below the required clean-up goal and in shorter time with respect to bench scale. Using 2% (w/w) Fe0, TNT soil concentration reduced below the required standard just within 4 h. No significant TNT destruction improvement was observed when 2% Fe0 (w/w soil) was combined with four sequential additions of 0.25% H2O2. Laboratory experiments with 14C-TNT indicated that most of the 14C, approximately 80%, was unextractable residue. A time greater than 24 h was required either with Fenton reagent, 8 x (80 mg Fe2+ L-1 + 0.125% H2O2) or 0.2% (w/w) CaO2. The optimal performance of Fenton reagent was obtained when the reagent was added in eight increments rather than in a single or double dose and less cumulative amount of H2O2 (0.75%) was required with respect to bench scale (1%).
authors.affiliation: Dipartimento di Scienze Chimico Agrarie, Università degli Studi di Napoli, Italy. arienzo@katamail.com
authors.forename: M
authors.initials: M
authors.lastname: Arienzo
mesh_terms: D007220:Industrial Waste; D009329:Nebraska; D010084:Oxidation-Reduction; D010865:Pilot Projects; D012989:Soil Pollutants; D014303:Trinitrotoluene; D018505:Waste Management / Q000379:methods*
chemical_list: D007220:Industrial Waste; D012989:Soil Pollutants; D014303:Trinitrotoluene