title: The Electrophilic Behavior of Stable Phosphanylcarbenes Towards Phosphorus Lone Pairs.
abstract: As expected for a singlet carbene, the stable phosphanylsilylcarbene 1 possesses an accessible vacant orbital, as shown by reactions with Lewis bases such as phosphanes and a bimetallic complex containing a side-on-coordinated full blockC:full blockP identical withPfull blockC:full block moiety (see the reaction scheme). R=cHex(2)N.
authors.affiliation: Laboratoire d'Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier, 118, route de Narbonne, F-31062 Toulouse cedex O4 (France).
authors.initials: S
authors.lastname: Goumri-Magnet
authors.initials: O
authors.lastname: Polishchuk
authors.initials: H
authors.lastname: Gornitzka
authors.initials: CJ
authors.lastname: Marsden
authors.initials: A
authors.lastname: Baceiredo
authors.initials: G
authors.lastname: Bertrand