Activation of
Reversible C(6)F(5) transfer takes place between the boron centers in the anion formed by methide abstraction from [MeZr{N(SiMe(3))(2)}(3)] or [Cp(2)ZrMe(2)] (L(n)M-CH(3) in the reaction scheme) by the perfluorinated diborane 1. The solution chemistry of the metallocenium ion pairs formed from 1 and [Cp(2)ZrMe(2)] is correlated with the observed ethylene polymerization behavior of 1 in comparison to the monoborane B(C(6)F(5))(3), the related diborane 1,2-C(6)H(4)[B(C(6)F(5))(2)](2), and the 9,10-diboraanthracene compound 9,10-(C(6)F(5))(2)C(12)B(2)F(8).
Williams
VC
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, AB, T2N 1N4 (Canada).
Dai
C
Li
Z
Collins
S
Piers
WE
Clegg
W
Elsegood
MR
Marder
TB