Ion exchange-based preconcentration for the determination of anions by capillary electrophoresis.
In the present paper a capillary zone electrophoresis (CZE)-compatible preconcentration technique for anions, based on ion exchange, is described. The described preconcentration approach has found limited use until recently because of the inherent elution step that leads to contamination of the sample with eluent components. In this paper, we describe an improved anion exchange-based preconcentration technique in which contamination of the sample with the eluent constituents, which occurs during anion elution from the preconcentration column, is eliminated by on-line chemical suppression on a packed-bed suppressor column. In the present communication, the basic principles of the proposed anion enrichment system are presented. The system was optimized, resulting in a minimal additional dilution of the eluted sample plug. This was achieved by the use of a computer-controlled, sensing/switching system. The effectiveness of the developed method was later tested on the determination of some anions in a synthetic sample using CE apparatus.
Novic
M
M
National Institute of Chemistry, Ljubljana, Slovenia. milko.novic@ki.si
Gucek
M
M
D000837:Anion Exchange Resins; D000838:Anions / Q000032:analysis*; D019075:Electrophoresis, Capillary / Q000295:instrumentation / Q000379:methods*; D011137:Polystyrenes; D014867:Water / Q000737:chemistry
D000837:Anion Exchange Resins; D000838:Anions; D011137:Polystyrenes; D014867:Water; C003771:Amberlite XAD-2 resin