New Building Blocks for the Design of Oligonuclear Copper Complexes Based on Amino Carbohydrates.
Remarkably high magnetic coupling and O(2)-activation ability analogous to that of catechol oxidase are characteristics of the first structurally defined, low-symmetry oligonuclear copper complexes of tridentate beta-oxoenamine ligands based on amino carbohydrates (the structure of a bis(acetylbutenonylaminoglucosidato)bis(µ-acetato)tricopper(II) complex is shown).
Wegner
R
Institut für Anorganische und Analytische Chemie der Universität August-Bebel-Strasse 2, 07743 Jena (Germany).
Gottschaldt
M
Görls
H
Jäger
EG
Klemm
D