title: Mechanistic aspects of the tyrosyl radical-manganese complex in photosynthetic water oxidation.
authors.affiliation: Department of Chemistry, Michigan State University, East Lansing 48824-1322, USA.
authors.forename: C W
authors.initials: CW
authors.lastname: Hoganson
authors.forename: G T
authors.initials: GT
authors.lastname: Babcock
mesh_terms: D020134:Catalytic Domain; D004578:Electron Spin Resonance Spectroscopy; D004579:Electron Transport; D005609:Free Radicals / Q000737:chemistry / Q000378:metabolism; D006863:Hydrogen-Ion Concentration; D008345:Manganese / Q000737:chemistry / Q000378:metabolism*; D013058:Mass Spectrometry; D008956:Models, Chemical; D010084:Oxidation-Reduction; D010788:Photosynthesis; D045322:Photosynthetic Reaction Center Complex Proteins / Q000737:chemistry / Q000378:metabolism*; D011522:Protons; D014443:Tyrosine / Q000031:analogs & derivatives* / Q000737:chemistry / Q000378:metabolism; D014867:Water / Q000737:chemistry / Q000378:metabolism*
chemical_list: D005609:Free Radicals; D045322:Photosynthetic Reaction Center Complex Proteins; D011522:Protons; C114979:tyrosyl radical YZ; D014867:Water; D014443:Tyrosine; D008345:Manganese