title: Mass spectrometric study of tricarbonyl (eta(6)-phenyl methanols) of chromium(0).
abstract: A mass spectrometric study of several tricarbonyl (eta(6)-phenyl methanols) of chromium(0) was performed. Electron ionization (EI), chemical ionization (CI) and fast atom bombardment (FAB) mass spectra were acquired for each molecule, and compared in order to establish a general fragmentation pattern. The suggested pathways were investigated and confirmed by means of constant b/e linked scans and high resolution data. In addition a Hammett-McLafferty correlation for some peaks derived from the molecular ions was accomplished.
authors.affiliation: Facultad de Estudios Superiores Cuautitlán-Universidad Nacional Autónoma de México, Campo 1, Cuautitlán Izcalil, Estado de México, C.P. 054740, USA.
authors.forename: G A
authors.initials: GA
authors.lastname: Arroyo
authors.forename: R
authors.initials: R
authors.lastname: Miranda
authors.forename: J G
authors.initials: JG
authors.lastname: García
authors.forename: F
authors.initials: F
authors.lastname: Delgado
authors.forename: L
authors.initials: L
authors.lastname: Cessa
authors.forename: F J
authors.initials: FJ
authors.lastname: Pérez
authors.forename: L
authors.initials: L
authors.lastname: Velasco
mesh_terms: D002857:Chromium / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D009942:Organometallic Compounds / Q000737:chemistry*; D016339:Spectrometry, Mass, Fast Atom Bombardment
chemical_list: D009942:Organometallic Compounds; D002857:Chromium