title: Sugar interaction with metal ions. FT-IR study on the structure of crystalline galactaric acid and its K+, NH4+, Ca2+, Ba2+, and La3+ complexes.
abstract: The FT-IR spectra of galactaric acid and its K+, NH4+, Ca2+, Ba2+, and La3+ salts have been recorded and interpreted. Spectroscopic evidence shows that the dimeric carboxylic groups of the free acid are dissociated upon formation of the salt, and the asymmetric and symmetric stretching vibrations of the anionic COO- group in these salts are observed at about 1600 and 1400 cm-1, respectively. The two carboxylic groups of the galactarate coordinate with Ca2+ ions in a monodentate form. One of the carboxylic groups in the Ba2+ salt coordinates in a monodentate state; another group interacts with three cations in a tetradentate form. In the K+, NH4+, and La3+ salts, the COO- groups coordinate in a polydentate manner with the cations. By comparison of the spectra of the salts with that of the free acid, it is concluded that the hydroxyl groups of the galactarate skeleton take part in metal-oxygen interaction, and the hydrogen-bonding network is rearranged upon sugar metalation. The degree of participation of the sugar OH groups in metal-galactarate interaction is varied from the K+ and NH4+ salts to the Ca2+, Ba2+, and La3+ salts.
authors.affiliation: Department of Chemistry, Peking University, Beijing, PR China.
authors.forename: W
authors.initials: W
authors.lastname: Tian
authors.forename: L M
authors.initials: LM
authors.lastname: Yang
authors.forename: Y Z
authors.initials: YZ
authors.lastname: Xu
authors.forename: S F
authors.initials: SF
authors.lastname: Weng
authors.forename: J G
authors.initials: JG
authors.lastname: Wu
mesh_terms: D001464:Barium / Q000737:chemistry; D002118:Calcium / Q000737:chemistry; D002412:Cations / Q000737:chemistry*; D002614:Chelating Agents / Q000737:chemistry; D007811:Lanthanum / Q000737:chemistry; D015394:Molecular Structure; D011188:Potassium / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013400:Sugar Acids / Q000737:chemistry*
chemical_list: D002412:Cations; D002614:Chelating Agents; D000644:Quaternary Ammonium Compounds; D013400:Sugar Acids; D001464:Barium; D007811:Lanthanum; C000090:galactaric acid; D011188:Potassium; D002118:Calcium