title: Direct lithiation and alkylation of trifluoromethyl enol ethers having a beta-sulfur substituent.
abstract: The direct lithiation and alkylation of beta-sulfur-alpha-trifluoromethyl substituted enol ethers 1-3 proceeded to give the alkylated products 4a-f, 5, 6a-c in moderate to high yields.
authors.affiliation: Department of Chemistry, Faculty of Education, Gifu University, Japan.
authors.forename: M
authors.initials: M
authors.lastname: Yoshimatsu
authors.forename: S
authors.initials: S
authors.lastname: Kinoshita
mesh_terms: D000478:Alkylation; D005019:Ethyl Ethers / Q000737:chemistry*; D007202:Indicators and Reagents; D008094:Lithium / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D011437:Propylamines; D013455:Sulfur / Q000737:chemistry*; D014753:Vinyl Compounds / Q000737:chemistry*
chemical_list: D005019:Ethyl Ethers; D007202:Indicators and Reagents; D011437:Propylamines; D014753:Vinyl Compounds; D013455:Sulfur; D008094:Lithium; C007442:diisopropylamine