Synthesis and structural characterization of a Re(V) complex with a 2N1S donor and the radiochemical behavior of its Tc analog.
A rhenium(V) complex with 2-(2-pyridylmethylthio)-aniline has been synthesized and characterized by UV-VIS absorption, IR, MS and X-ray crystallography. The complex contains a ReO3+ moiety and the amine compound, acting as a monobasic tridentate(NSN) ligand. The chemical behavior of its technetium analog has been studied radioanalytically by solvent extraction, TLC, electrophoresis and HPLC using 99mTc tracer.
Chattopadhyay
P
P
Department of Nuclear Science, National Tsing Hua University, Hsinchu, Taiwan, ROC.
Chiu
Y H
YH
Lo
J M
JM
Chung
C S
CS
Lu
T H
TH
D018360:Crystallography, X-Ray; D013058:Mass Spectrometry; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011868:Radioisotopes; D012211:Rhenium; D013053:Spectrophotometry; D013667:Technetium
D009942:Organometallic Compounds; D011868:Radioisotopes; C405710:dichlorooxo(2-(2-pyridylmethylthio)aniline)rhenium(V); D012211:Rhenium; D013667:Technetium