Determination of interfacial tension from crystallization and dissolution data: a comparison with other methods.
Methods for the determination of interfacial tension between a solid and a liquid are reviewed including solubility/particle size, crystallization and dissolution kinetics. The use of solubility as a function of particle size, originally put forward by Ostwald and later corrected by Freundlich, may be unjustified for determining interfacial tension at solid-liquid interfaces. The interfacial tension values between solutions and sparingly soluble minerals such as hydroxyapatite, fluorapatite, brushite, octacalcium phosphate, calcium oxalate monohydrate, barium sulfate, calcium sulfate, calcite, and divalent metal fluorides are discussed. A comparison of these results is made with contact angle or wetting measurements. The interfacial tension values obtained from constant composition reaction kinetics are of the same order of magnitude as those determined using a contact angle method involving thin layer wicking techniques.
Wu
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Department of Chemistry, State University of New York at Buffalo 14260, USA.
Nancollas
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GH
D002623:Chemistry Techniques, Analytical / Q000379:methods*; D003460:Crystallization; D008956:Models, Chemical; D012995:Solubility; D013500:Surface Tension; D013816:Thermodynamics