Mass spectrometric study of tricarbonyl (eta(6)-phenyl methanols) of chromium(0).
A mass spectrometric study of several tricarbonyl (eta(6)-phenyl methanols) of chromium(0) was performed. Electron ionization (EI), chemical ionization (CI) and fast atom bombardment (FAB) mass spectra were acquired for each molecule, and compared in order to establish a general fragmentation pattern. The suggested pathways were investigated and confirmed by means of constant b/e linked scans and high resolution data. In addition a Hammett-McLafferty correlation for some peaks derived from the molecular ions was accomplished.
Arroyo
G A
GA
Facultad de Estudios Superiores Cuautitlán-Universidad Nacional Autónoma de México, Campo 1, Cuautitlán Izcalil, Estado de México, C.P. 054740, USA.
Miranda
R
R
García
J G
JG
Delgado
F
F
Cessa
L
L
Pérez
F J
FJ
Velasco
L
L
D002857:Chromium / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D009942:Organometallic Compounds / Q000737:chemistry*; D016339:Spectrometry, Mass, Fast Atom Bombardment
D009942:Organometallic Compounds; D002857:Chromium