Determination of polycyclic aromatic hydrocarbons in marine sediments by high-performance liquid chromatography after microwave-assisted extraction with micellar media.
A simple and rapid method is developed for extraction and determination of polycyclic aromatic hydrocarbons (PAHs) in marine sediments. The procedure was based on the microwave-assisted extraction of PAHs in marine sediment samples using a micellar medium of Polyoxyethylene 10 lauryl ether as extractant. Two-level factorial designs have been used to optimize the microwave extraction process. The analysis of extracts has been carried out by HPLC with UV detection. Fortified sediments gave an average recovery between 85.70 and 100.73%, with a relative standard deviation of 1.77-7.0% for PAHs with a ring number higher than three.
Pino
V
V
Department of Analytical Chemistry, Nutrition and Food Science, University of La Laguna, Spain.
Ayala
J H
JH
Afonso
A M
AM
González
V
V
D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D008823:Micelles; D008872:Microwaves; D011083:Polycyclic Compounds / Q000032:analysis*; D012623:Seawater; D013056:Spectrophotometry, Ultraviolet; D014874:Water Pollutants, Chemical / Q000032:analysis*
D008823:Micelles; D011083:Polycyclic Compounds; D014874:Water Pollutants, Chemical