title: Thermal C-glycosylation of D-glucal with trimethylsilyl cyanide.
abstract: The treatment of 3,4,6-tri-O-acetyl-D-glucal and unprotected D-glucal with trimethylsilyl cyanide, under thermal conditions in the absence of catalyst, afforded the corresponding 2,3-unsaturated glycosyl cyanides in high yield.
authors.affiliation: Department of Chemistry, Faculty of Science, Yamaguchi University, Japan. hayashi@po.cc.yamaguchi-u.ac.jp
authors.forename: M
authors.initials: M
authors.lastname: Hayashi
authors.forename: H
authors.initials: H
authors.lastname: Kawabata
authors.forename: K
authors.initials: K
authors.lastname: Inoue
mesh_terms: D002125:Calcium Gluconate / Q000737:chemistry*; D003486:Cyanides / Q000138:chemical synthesis / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis*; D006031:Glycosylation; D009682:Magnetic Resonance Spectroscopy; D014297:Trimethylsilyl Compounds / Q000737:chemistry
chemical_list: D003486:Cyanides; D006027:Glycosides; D014297:Trimethylsilyl Compounds; C058010:trimethylsilyl cyanide; D002125:Calcium Gluconate