title: Synthesis and NMR study of a heptasaccharide, epitope of the stage-specific embryonic antigen-1 (SSEA-1).
abstract: This paper describes an efficient synthesis of the beta-2-trimethylsilylethyl glycoside of lacto-N-fucoheptaose based on a highly stereo- and regioselective glycosylation between a Lewis(x) trisaccharidic donor and a tetraol tetrasaccharidic acceptor. The title compound was characterized by high-resolution NMR spectroscopy.
authors.affiliation: Ecole Normale Supérieure, Département de Chimie, UMR 8642, Paris, France.
authors.forename: Y
authors.initials: Y
authors.lastname: Zhang
authors.forename: B
authors.initials: B
authors.lastname: Dausse
authors.forename: P
authors.initials: P
authors.lastname: Sinaÿ
authors.forename: M
authors.initials: M
authors.lastname: Afsahi
authors.forename: P
authors.initials: P
authors.lastname: Berthault
authors.forename: H
authors.initials: H
authors.lastname: Desvaux
mesh_terms: D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D000939:Epitopes / Q000737:chemistry*; D006031:Glycosylation; D016256:Lewis X Antigen / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008969:Molecular Sequence Data; D009844:Oligosaccharides / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000939:Epitopes; D016256:Lewis X Antigen; D009844:Oligosaccharides; C010478:lacto-N-fucoheptaose