Thermal C-glycosylation of D-glucal with trimethylsilyl cyanide.
The treatment of 3,4,6-tri-O-acetyl-D-glucal and unprotected D-glucal with trimethylsilyl cyanide, under thermal conditions in the absence of catalyst, afforded the corresponding 2,3-unsaturated glycosyl cyanides in high yield.
Hayashi
M
M
Department of Chemistry, Faculty of Science, Yamaguchi University, Japan. hayashi@po.cc.yamaguchi-u.ac.jp
Kawabata
H
H
Inoue
K
K
D002125:Calcium Gluconate / Q000737:chemistry*; D003486:Cyanides / Q000138:chemical synthesis / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis*; D006031:Glycosylation; D009682:Magnetic Resonance Spectroscopy; D014297:Trimethylsilyl Compounds / Q000737:chemistry
D003486:Cyanides; D006027:Glycosides; D014297:Trimethylsilyl Compounds; C058010:trimethylsilyl cyanide; D002125:Calcium Gluconate