title: Sliding mechanics of coated composite wires and the development of an engineering model for binding.
abstract: A tribological (friction and wear) study, which was designed to simulate clinical sliding mechanics, was conducted as part of an effort to determine the suitability of poly(chloro-p-xylylene) coatings for composite orthodontic archwires. Prototype composite wires, having stiffnesses similar to those of current initial and intermediate alignment wires, were tested against stainless steel and ceramic brackets in the passive and active configurations (with and without angulation). Kinetic coefficient of friction values, which were determined to quantify sliding resistances as functions of the normal forces of ligation, had a mean that was 72% greater than uncoated wire couples at 0.43. To improve analysis of the active configuration, a mathematical model was developed that related bracket angulation, bracket width, interbracket distance, wire geometry, and wire elastic modulus to sliding resistance. From this model, kinetic coefficients of binding were determined to quantify sliding resistances as functions of the normal forces of binding. The mean binding coefficient was the same as that of uncoated wire couples at 0.42. Although penetrations through the coating were observed on many specimens, the glass-fiber reinforcement within the composite wires was undamaged for all conditions tested. This finding implies that the risk of glass fiber release during clinical use would be eliminated by the coating. In addition, the frictional and binding coefficients were still within the limits outlined by conventional orthodontic wire-bracket couples. Consequently, the coatings were regarded as an improvement to the clinical acceptability of composite orthodontic archwires.
authors.affiliation: Department of Biomedical Engineering, School of Medicine, University of North Carolina at Chapel Hill, USA.
authors.forename: S W
authors.initials: SW
authors.lastname: Zufall
authors.forename: R P
authors.initials: RP
authors.lastname: Kusy
mesh_terms: D000537:Aluminum Oxide / Q000737:chemistry; D000704:Analysis of Variance; D017438:Bisphenol A-Glycidyl Methacrylate / Q000737:chemistry; D002516:Ceramics / Q000737:chemistry; D016009:Chi-Square Distribution; D020099:Coated Materials, Biocompatible / Q000737:chemistry; D003188:Composite Resins / Q000737:chemistry; D003764:Dental Materials / Q000737:chemistry*; D004548:Elasticity; D004738:Engineering; D017276:Friction; D005898:Glass / Q000737:chemistry; D006801:Humans; D007700:Kinetics; D008026:Ligation / Q000295:instrumentation; D008422:Materials Testing; D019563:Mechanics; D008855:Microscopy, Electron, Scanning; D008962:Models, Theoretical; D016910:Orthodontic Brackets; D009969:Orthodontic Wires; D011092:Polyethylene Glycols / Q000737:chemistry; D011108:Polymers / Q000737:chemistry; D011109:Polymethacrylic Acids / Q000737:chemistry; D012044:Regression Analysis; D013193:Stainless Steel / Q000737:chemistry; D013499:Surface Properties; D014992:Xylenes / Q000737:chemistry
chemical_list: D020099:Coated Materials, Biocompatible; D003188:Composite Resins; D003764:Dental Materials; D011108:Polymers; D011109:Polymethacrylic Acids; D014992:Xylenes; C009753:fiberglass; D013193:Stainless Steel; C020946:triethylene glycol dimethacrylate; C011055:parylene; D011092:Polyethylene Glycols; D017438:Bisphenol A-Glycidyl Methacrylate; D000537:Aluminum Oxide