title: Analysis of size-classified ice crystals by capillary electrophoresis.
abstract: In order to analyse the main inorganic cations (NH4+, K+, Na+, Ca2+, Mg2+) and anions (Cl-, NO3-, SO4(2-)) as well as carboxylic and dicarboxylic acids in ice crystals by capillary electrophoresis, electrolyte systems were developed and optimised with respect to limits of detection, resolution, reproducibility and analysis time. We applied indirect UV detection, which enables the simultaneous detection of multiple components. Salicylic acid and 4-methylaminophenolsulfate were used as UV-active co-ions for analysis of anions and cations, respectively. The special features of these systems were low limits of detection in the range 0.3-0.9 micromol L(-1), i.e. absolute limits of detection were in the fmol range, and short analyses times. Separations of cations as well as anions including carboxylic and dicarboxylic acids were completed within 4 min allowing a high sample throughput. Furthermore, the applicability of the newly developed electrolyte systems was demonstrated by comparative analyses with ion chromatography and by first field experimental studies.
authors.affiliation: Paul Scherrer Institut, Villigen, Switzerland.
authors.forename: B
authors.initials: B
authors.lastname: Tenberken-Pötzsch
authors.forename: M
authors.initials: M
authors.lastname: Schwikowski
authors.forename: H W
authors.initials: HW
authors.lastname: Gäggeler
mesh_terms: D002412:Cations; D003460:Crystallization; D019075:Electrophoresis, Capillary / Q000379:methods*; D006863:Hydrogen-Ion Concentration; D007053:Ice
chemical_list: D002412:Cations; D007053:Ice