Electronic structures of single-walled carbon nanotubes determined by NMR
Single-walled carbon nanotubes were studied by (13)C nuclear magnetic resonance (NMR). Two types of (13)C nuclear spins were identified with different spin-lattice relaxation rates. The fast-relaxing component, assigned to metallic tubes, followed the relaxation behavior expected in metals, and the density-of-states at the Fermi level increased with decreasing tube diameter. The slow-relaxing component has a significantly lower density-of-states at the Fermi level. Exposure to oxygen has a substantial effect on relaxation rates of both components.
Tang
X
Department of Physics and Astronomy and Curriculum in Applied and Materials Sciences, University of North Carolina, Chapel Hill, NC 27599-3255, USA.
Kleinhammes
A
Shimoda
H
Fleming
L
Bennoune
KY
Sinha
S
Bower
C
Zhou
O
Wu
Y