Construction and evaluation of an aerosol generating apparatus for combustion products from polyurethane foam.
A system has been constructed and evaluated for generating aerosols from combustion or pyrolysis of various cross-linked polymers. The system consists of an aerosol generator and an aerosol chamber with a sampling compartment designed for various samplers and sampling probes. A geared electric motor assembly is used to lower a polymer strip into the controlled atmosphere of a quartz-lined furnace. The polymer used in this investigation was a polyurethane foam (PUF) based on toluene diisocyanate (TDI). Combustion of the PUF was conducted in filtered air at a temperature of 300 degrees C. The particle number concentration of the generated aerosol was measured by light scattering in the particle size range from 0.1 micron to greater than 5 microns. Air samples were collected periodically in impinger flasks using dibutylamine (DBA) in toluene as derivatization reagent. The TDI-DBA derivatives from the impinger samples were analyzed with high performance liquid chromatography. The aerosol generating system was found to generate a stable, reproducible, and predictable concentration of particles and TDI monomer. Three partial least squares models were created to evaluate the generator. The investigated responses were the TDI concentration, the particle number concentration, and the stability of the particle number concentration during the generating process. The factor with most impact on the concentrations of the generated aerosol was found to be the interaction between linear feeding rate of the polymer strip and the flow rate of combustion gas. For stability the linear feeding rate was the most important.
Melin
J
J
Department of Analytical Chemistry, Stockholm University, Sweden. jens.melin@anchem.su.se
Johansson
R
R
Bemgård
A
A
Colmsjö
A
A
D000336:Aerosols; D000395:Air Pollutants, Occupational / Q000032:analysis; D002617:Chemical Industry / Q000295:instrumentation*; D004867:Equipment Design; D005069:Evaluation Studies as Topic; D006358:Hot Temperature; D010316:Particle Size; D011140:Polyurethanes / Q000032:analysis; D015203:Reproducibility of Results; D014051:Toluene 2,4-Diisocyanate / Q000032:analysis
D000336:Aerosols; D000395:Air Pollutants, Occupational; D011140:Polyurethanes; D014051:Toluene 2,4-Diisocyanate