title: Synthesis, X-ray structure and high-resolution NMR spectroscopy of methyl 3-azido-2,3-dideoxy-alpha-D-arabino-hexopyranoside.
abstract: The synthesis, crystal structure data and 1H and 13C NMR spectroscopy of methyl 3-azido-2,3-dideoxy-alpha-D-arabino-hexopyranoside (5b) is reported. This compound adopts the 4C1 conformation. Hydrogen-bonded molecules of 5b form helices around the crystallographic 4(1) axis.
authors.affiliation: Department of Chemistry, University of Gdańsk, Poland.
authors.forename: A
authors.initials: A
authors.lastname: Dabrowska
authors.forename: P
authors.initials: P
authors.lastname: Dokurno
authors.forename: A
authors.initials: A
authors.lastname: Konitz
authors.forename: Z
authors.initials: Z
authors.lastname: Smiatacz
mesh_terms: D001386:Azides / Q000138:chemical synthesis*; D002241:Carbohydrates / Q000138:chemical synthesis*; D018360:Crystallography, X-Ray; D006027:Glycosides / Q000138:chemical synthesis*; D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular
chemical_list: D001386:Azides; D002241:Carbohydrates; D006027:Glycosides; C410156:methyl 3-azido-2,3-dideoxyhexopyranoside