Application of high-temperature gas chromatography-mass spectrometry to the investigation of glycosidically bound components related to cashew apple (Anacardium occidentale L. Var. Nanum) volatiles.
Free and bound volatile components of a Brazilian cashew apple variety (Anacardium occidentale L. var. nanum) were obtained by simultaneous distillation-extraction (SDE) and XAD-2 adsorption. According to gas chromatography-mass spectrometry (GC-MS) analyses and retention indices, 62 free volatile constituents were characterized and quantified. They were esters (40%), terpenes (20%), hydrocarbons (14%), fatty acids (9%), aldehydes (8%), alcohols (3%), lactones (3%), ketones (1%), phenols (1%), and norisoprenoids (1%). The glycosidically bound volatile precursors were analyzed by high-temperature GC-MS, after room temperature silylation. Several conjugated alcohols and cinnamic acids were detected and reported as cashew apple glycosyl constituents for the first time.
Bicalho
B
B
Ilha do Fundão, Centro de Tecnologia, Bloco A, Instituto de Química, Departamento de Química Orgânica, lab. 621/607, Universidade Federal do Rio de Janeiro, Rio de Janeiro, RJ 21949-900, Brazil. beatriz@iqm.unicamp.br
Pereira
A S
AS
Aquino Neto
F R
FR
Pinto
A C
AC
Rezende
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CM
D000438:Alcohols / Q000032:analysis; D000447:Aldehydes / Q000032:analysis; D004952:Esters / Q000032:analysis; D005227:Fatty Acids / Q000032:analysis; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D006027:Glycosides / Q000032:analysis*; D006358:Hot Temperature; D006838:Hydrocarbons / Q000032:analysis; D007659:Ketones / Q000032:analysis; D007783:Lactones / Q000032:analysis; D009754:Nuts; D010636:Phenols / Q000032:analysis; D011137:Polystyrenes; D013729:Terpenes / Q000032:analysis; D014197:Trees / Q000737:chemistry*
D000438:Alcohols; D000447:Aldehydes; D004952:Esters; D005227:Fatty Acids; D006027:Glycosides; D006838:Hydrocarbons; D007659:Ketones; D007783:Lactones; D010636:Phenols; D011137:Polystyrenes; D013729:Terpenes; C003771:Amberlite XAD-2 resin