Diffuse Double-Layer Interaction between Two Identical Spherical Colloidal Particles.
A simple method is given for calculating the potential energy of the diffuse double-layer interaction between two identical spherical colloidal particles in a symmetrical electrolyte solution with the help of Derjaguin's approximation. This method uses accurate analytic expressions for the corresponding interaction energy between two parallel similar plates obtained previously (Colloids Surf. A Physicochem. Eng. Asp. 146, 213 (1999); J. Colloid Interface Sci. 212, 130 (1999)). Agreement with numerical data provided by Honig and Mul (J. Colloid Interface Sci. 36, 258 (1971)) is excellent particularly for small particle separations. Copyright 2000 Academic Press.
Ohshima
H
Faculty of Pharmaceutical Sciences and Institute of Colloid and Interface Science, Science University of Tokyo, 12 Ichigaya Funagawara-machi, Shinjuku-ku, Tokyo, 162-0826, Japan