Spin-locking mechanism of spin I = 3/2 quadrupolar nuclei undergo magic angle spinning.
The spin-locking mechanism of the spin I = 3/2 quadrupolar nuclei under magic angle spinning (MAS) has been theoretically and experimentally investigated, and the criterion of adiabatic passage around zero-crossings of the quadrupole splitting was inferred from the time-dependent Shrödinger equation in this article. The theory, numerical simulations, and experiments conducted in this work all indicated that second-order quadrupole interaction and off-resonance play important roles in the spin-locking of the quadrupolar nuclei, and they were responsible for the great loss of the spin-locking signals. The spin-locking for a spin I = 3/2 nucleus might be achieved by minimizing the effect of the second-order quadrupole interaction by using a radio frequency (RF) offset. This offset was realized by setting the RF to the opposite position of the isotropic second-order quadrupolar shift of single quantum coherences.
Zhang
Y
Y
Laboratory of Nuclear Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences.
Deng
F
F
Qiu
J
J
Ye
C
C
D009682:Magnetic Resonance Spectroscopy