title: Total synthesis of (+)-amphidinolide P. [corrected].
abstract: The convergent enantiocontrolled total synthesis of the 15-membered macrolactone (-)-amphidinolide P is reported. Key transformations include a Sakurai allylation, a Stille coupling for the formation of a fully functionalized acyclic precursor, and intramolecular transesterification.
authors.affiliation: Department of Chemistry, Indiana University, Bloomington 47405-7102, USA. williamd@indiana.edu
authors.forename: D R
authors.initials: DR
authors.lastname: Williams
authors.forename: B J
authors.initials: BJ
authors.lastname: Myers
authors.forename: L
authors.initials: L
authors.lastname: Mi
mesh_terms: D000818:Animals; D000970:Antineoplastic Agents / Q000138:chemical synthesis*; D004141:Dinoflagellida / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D018942:Macrolides; D000097442:Amphidinolides
chemical_list: D000970:Antineoplastic Agents; D006571:Heterocyclic Compounds; D007202:Indicators and Reagents; D018942:Macrolides; C407987:amphidinolide P; D000097442:Amphidinolides