title: Nanometer-size alpha-PbO(2)-type TiO(2) in garnet: A thermobarometer for ultrahigh-pressure metamorphism
abstract: A high-pressure phase of titanium dioxide (TiO(2)) with an alpha-PbO(2)-type structure has been identified in garnet of diamondiferous quartzofeldspathic rocks from the Saxonian Erzgebirge, Germany. Analytical electron microscopy indicates that this alpha-PbO(2)-type TiO(2) occurred as an epitaxial nanometer-thick slab between twinned rutile bicrystals. Given a V-shaped curve for the equilibrium phase boundary of alpha-PbO(2)-type TiO(2) to rutile, the stabilization pressure of alpha-PbO(2)-type TiO(2) should be 4 to 5 gigapascals at 900 degrees to 1000 degrees C. This suggests a burial of continental crustal rocks to depths of at least 130 kilometers. The alpha-PbO(2)-type TiO(2) may be a useful pressure and temperature indicator in the diamond stability field.
authors.affiliation: Department of Materials Science and Engineering, I-Shou University, Kaohsiung, Taiwan, ROC. Institute of Materials Science and Engineering, National Sun Yat-sen University, Kaohsiung, Taiwan, ROC. Central Geological Survey, Post Office Box 96.
authors.initials: SL
authors.lastname: Hwang
authors.initials: P
authors.lastname: Shen
authors.initials: HT
authors.lastname: Chu
authors.initials: TF
authors.lastname: Yui