title: Stereocontrol in solid-phase radical reactions: radical addition to oxime ether anchored to polymer support
abstract: A high degree of stereocontrol in solid-phase radical reactions was achieved by using triethylborane and diethylzinc as a radical initiator at low reaction temperature. Alkyl radical addition to Oppolzer's camphorsultam derivatives of oxime ether anchored to polymer support proceeded smoothly to give the alpha-amino acid derivatives with excellent diastereoselectivities.
authors.affiliation: Kobe Pharmaceutical University, Motoyamakita, Higashinada, Kobe 658-8558, Japan.
authors.initials: H
authors.lastname: Miyabe
authors.initials: C
authors.lastname: Konishi
authors.initials: T
authors.lastname: Naito