title: Fourier transform Raman and infrared spectra and normal coordinate analysis of organo-arsenic(III), -antimony(III) and -bismuth(III) thiolates.
abstract: The FT-Raman and infrared spectra of (PhS)BiPh2, (PhS)2BiPh, (PhS)3Sb, (PhS)3Sb, (PhS)3As and (PhSe)BiPh2 were measured in the range 3600-100 cm(-1). A normal coordinate analysis was performed for all substances in terms of the calculation and discussion of the force constants which are dependent on the element-sulphur and element-selenium group using a modified valence force field. Furthermore, for all compounds 1H-NMR, 13C-NMR and MS data were also given. The investigation of the microbiological activity of some substances against Escherichia coli was an additional aspect because of their strong bactericidal and fungicidal effects.
authors.affiliation: Department of Analytical Chemisrtry, Ruhr-University Bochum, Germany.
authors.forename: C
authors.initials: C
authors.lastname: Ludwig
authors.forename: M
authors.initials: M
authors.lastname: Dolny
authors.forename: H J
authors.initials: HJ
authors.lastname: Götze
mesh_terms: D002244:Carbon / Q000737:chemistry; D018011:Chalcogens / Q000737:chemistry; D008826:Microbial Sensitivity Tests; D009942:Organometallic Compounds / Q000737:chemistry* / Q000494:pharmacology; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods*; D013059:Spectrum Analysis, Raman / Q000379:methods*; D013440:Sulfides / Q000737:chemistry* / Q000494:pharmacology; D013455:Sulfur / Q000737:chemistry
chemical_list: D018011:Chalcogens; D009942:Organometallic Compounds; D013440:Sulfides; C411142:antimonytrithious acid triphenyl ester; C411141:arsenotrithious acid triphenyl ester; D013455:Sulfur; D002244:Carbon