Infrared intensity and morphology of l-monolaurin-water systems.
The infrared spectra for some metastable states in 1-monolaurin water systems were observed at room temperature, where the relative intensity of bands due to paraffin chains changed considerably, especially in the CH2 rockings, which disappear in some cases. It is considered that the spectral changes result from the morphology change on going from the crystal to the liquid crystal, smectic B phase, so-called gel phase, which consists of the lipid bilayers with ordered paraffin chains alternating with water layers. The model for explaining the intensity change is proposed on the basis of the interaction among oscillating dipoles.
Kanesaka
I
I
Faculty of Science, Toyama University, Gofuku, Japan. kanesaka@sci.toyama-u.ac.jp
Shimizu
K
K
D005989:Glycerides / Q000737:chemistry*; D007848:Laurates / Q000737:chemistry*; D050178:Monoglycerides; D010232:Paraffin / Q000737:chemistry; D013055:Spectrophotometry, Infrared / Q000379:methods*; D013696:Temperature; D014867:Water / Q000737:chemistry
D005989:Glycerides; D007848:Laurates; D050178:Monoglycerides; D014867:Water; C020777:monolaurin; D010232:Paraffin