title: Enantiopure eta4-(1-sulfinyldiene)iron(0) tricarbonyl complexes as templates for carbocycle construction via ring-closing metathesis
abstract: [reaction: see text] Enantiomerically pure 1-(1Z,3E)-sulfinyl iron(0) dienols have been elaborated to bis-olefins capable of undergoing ring-closing metathesis chemistry. Using Grubbs' ruthenium carbene catalyst, a six-membered carbocycle (with one chiral center) and seven-, eight-, and nine-membered carbocycles (with two chiral centers) have been prepared. Novel transformations include the LiClO4-promoted allylation of an alkylidene malonate and a reductive sulfur-carbon bond cleavage to convert a vinyl sulfoxide into an alkene with SmI2.
authors.affiliation: Department of Chemistry, Swarthmore College, Pennsylvania 19081, USA. rpaley1@swarthmore.edu
authors.initials: RS
authors.lastname: Paley
authors.initials: LA
authors.lastname: Estroff
authors.initials: JM
authors.lastname: Gauguet
authors.initials: DK
authors.lastname: Hunt
authors.initials: RC
authors.lastname: Newlin