Infrared and polarized Raman spectra of (CH3)2NH2Al(SO4)2 x 6H2O.
FTIR and single crystal Raman spectra of (CH3)2NH2Al(SO4)2 x 6H2O have been recorded at 300 and 90 K and analysed. The shifting of nu1 mode to higher wavenumber and its appearance in Bg species contributing to the alpha(xz) and alpha(yz) polarizability tensor components indicate the distortion of SO4 tetrahedra. The presence of nu1 and nu2 modes in the IR spectrum and the lifting of degeneracies of nu2, nu3, and nu4 modes are attributed to the lowering of the symmetry of the SO4(2-) ion. Coincidence of the IR and Raman bands for different modes suggest that DMA+ ion is orientationally disordered. One of the H atoms of the NH2 group of the DMA+ ion forms moderate hydrogen bonds with the SO4(2-) anion. Al(H2O)6(3+) ion is also distorted in the crystal. The shifting of the stretching modes to lower wavenumbers and the bending mode to higher wavenumber suggest that H2O molecules form strong hydrogen bonds with SO4(2-) anion. The intensity enhancement and the narrowing of nu1SO4, deltaC2N and Al(H2O)6(3+) modes at 90 K confirm the settling down of the protons in the hydrogen bonds formed with H2O molecules and NH2 groups. This may be one of the reasons for the phase transition observed in the crystal.
Pillai
V P
VP
Department of Physics, St. Gregorios College, Quilon, Kerala, India.
Nayar
V U
VU
Jordanovska
V B
VB
D000534:Alum Compounds / Q000737:chemistry*; D000645:Ammonium Sulfate / Q000737:chemistry*; D004123:Dimethylamines / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods; D013059:Spectrum Analysis, Raman / Q000379:methods; D013696:Temperature; D014867:Water
D000534:Alum Compounds; D004123:Dimethylamines; C412247:dimethylammonium aluminum sulfate; D014867:Water; D000645:Ammonium Sulfate