title: beta-scission of the N-O bond in alkyl hydroxamate radicals: a fast radical trap.
abstract: [reaction--see text ] The rate of the beta-scission of the N-O bond in the alkyl hydroxamate radical is faster than 2 x 10(8) s(-)(1). This reaction may be useful as a radical trap.
authors.affiliation: Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, USA.
authors.forename: M
authors.initials: M
authors.lastname: Wu
authors.forename: T P
authors.initials: TP
authors.lastname: Begley
mesh_terms: D004798:Enzymes / Q000378:metabolism*; D005609:Free Radicals; D006877:Hydroxamic Acids / Q000737:chemistry*; D015394:Molecular Structure; D011393:Procollagen-Proline Dioxygenase / Q000037:antagonists & inhibitors
chemical_list: D004798:Enzymes; D005609:Free Radicals; D006877:Hydroxamic Acids; D011393:Procollagen-Proline Dioxygenase