Intensity Measurements and Collision-Broadening Coefficients for the Oxygen A Band Measured by Intracavity Laser Absorption Spectroscopy.
High-sensitivity, high-resolution intracavity laser absorption spectroscopy (ICLAS) has been used to measure line intensities, nitrogen-broadening coefficients, and self-broadening coefficients in the A band (b(1)Sigma(+)(g) <-- X(3)Sigma(-)(g)) of oxygen. Both linear cavity and ring cavity ICLAS configurations were used for these measurements, and the results were intercompared. The results were compared to values measured using long-path multiple-reflection cells by K. D. Ritter and T. D. Wilkinson [J. Mol. Spectrosc. 121, 1-19 (1987)] and L. Brown and C. Plymate, [J. Mol. Spectrosc. 199, 166-179 (2000)]. New results are included for weakly absorbing transitions, not observed in the earlier measurements, such as high rotational states (up to J = 39), hot-band transitions (v' = 1 <-- v" = 1), and isotopically substituted species ((18)O(2) and (16)O(18)O). Isotopic variants ((16)O(2), (18)O(2), and (16)O(18)O) have similar broadening coefficients for corresponding rotational levels, but the self-broadening coefficients are larger in the hot band (v' = v" = 1) as compared with v' = v" = 0 transitions. An ECS-EP scaling analysis of the v' = v" = 0 self-broadening data accurately represents the available data, with the exception of the N = 0 and N = 1 levels. Copyright 2000 Academic Press.
Yang
S
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts, 02139
Canagaratna
MR
Witonsky
SK
Coy
SL
Steinfeld
JI
Field
RW
Kachanov
AA