beta-scission of the N-O bond in alkyl hydroxamate radicals: a fast radical trap.
[reaction--see text ] The rate of the beta-scission of the N-O bond in the alkyl hydroxamate radical is faster than 2 x 10(8) s(-)(1). This reaction may be useful as a radical trap.
Wu
M
M
Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, USA.
Begley
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TP
D004798:Enzymes / Q000378:metabolism*; D005609:Free Radicals; D006877:Hydroxamic Acids / Q000737:chemistry*; D015394:Molecular Structure; D011393:Procollagen-Proline Dioxygenase / Q000037:antagonists & inhibitors
D004798:Enzymes; D005609:Free Radicals; D006877:Hydroxamic Acids; D011393:Procollagen-Proline Dioxygenase