Palladium-catalyzed asymmetric allylic alkylation of barbituric acid derivatives: enantioselective syntheses of cyclopentobarbital and pentobarbital.
Trost
B M
BM
Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA.
Schroeder
G M
GM
D000478:Alkylation; D000498:Allyl Compounds / Q000737:chemistry / Q000378:metabolism*; D002384:Catalysis; D003517:Cyclopentanes / Q000138:chemical synthesis* / Q000737:chemistry / Q000378:metabolism; D009682:Magnetic Resonance Spectroscopy; D010165:Palladium / Q000737:chemistry / Q000378:metabolism*; D010424:Pentobarbital / Q000031:analogs & derivatives* / Q000138:chemical synthesis* / Q000737:chemistry / Q000378:metabolism; D013237:Stereoisomerism
D000498:Allyl Compounds; D003517:Cyclopentanes; C414527:cyclopentobarbital; D010165:Palladium; D010424:Pentobarbital