title: New polyfunctional magnesium reagents for organic synthesis
abstract: The iodine-magnesium exchange reaction allows the preparation of polyfunctional aryl, heteroaryl, or alkenyl magnesium reagents at low temperature. These reagents display the typical reactivity of Grignard compounds and undergo various copper-catalyzed reactions such as allylation or 1,4-addition. Using this halogen-metal exchange reaction, it was possible to generate polyfunctional magnesium reagents on the solid phase.
authors.affiliation: Institut fur Organische Chemie der Universitat, Munchen, Germany.
authors.initials: M
authors.lastname: Rottlander
authors.initials: L
authors.lastname: Boymond
authors.initials: L
authors.lastname: Berillon
authors.initials: A
authors.lastname: Lepretre
authors.initials: G
authors.lastname: Varchi
authors.initials: S
authors.lastname: Avolio
authors.initials: H
authors.lastname: Laaziri
authors.initials: G
authors.lastname: Queguiner
authors.initials: A
authors.lastname: Ricci
authors.initials: G
authors.lastname: Cahiez
authors.initials: P
authors.lastname: Knochel