A short and efficient enantiospecific synthesis of (+)-(2R, 6S)-cis-gamma-irone via a highly diastereoselective protonation.
Laval
G
G
Laboratoire de Réactivité Organique Sélective associé au CNRS Faculté des Sciences de St-Jérôme, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France.
Audran
G
G
Galano
J M
JM
Monti
H
H
D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D045792:Norisoprenoids; D009822:Oils, Volatile / Q000737:chemistry*; D010476:Perfume / Q000737:chemistry*; D010944:Plants / Q000737:chemistry*; D011522:Protons; D013237:Stereoisomerism; D013729:Terpenes / Q000138:chemical synthesis* / Q000737:chemistry
C410863:(2R,6S)-irone; D045792:Norisoprenoids; D009822:Oils, Volatile; D010476:Perfume; D011522:Protons; D013729:Terpenes