Quantitative analysis using steady-state free precession nuclear magnetic resonance
The use of steady-state free precession nuclear magnetic resonance (NMR) for quantitative analysis in low magnetic field is investigated and shown to exhibit substantial advantages compared to more conventional NMR methods. With only minor additional requirements, the technique permits a considerable increase in signal-to-noise ratio for a given acquisition time. The experimental conditions needed for implementation and optimization of the acquisition parameters are explored and shown to be easily accessible with unsophisticated equipment. The applicability of the technique for quantitative analysis of samples with a range of relaxation rates is tested using various examples of practical interest. Highly reproducible results can be obtained much faster and without any special sample-dependent adjustments.
Bagueira de Vasconcelos Azered
Instituto de Quimica de Sao Carlos, Universidade de Sao Paulo, Brazil.
Colnago
LA
Engelsberg
M