Synthesis of terpenoid unsaturated 1,4-dialdehydes. Pi-facial selectivity in the Diels-Alder reaction of the 1-vinyl-2-methylcyclohexene moiety of polycyclic systems with DMAD.
Abad
A
A
Departamento de Química Orgánica, Facultad de Químicas, Universidad de Valencia, C/Dr. Moliner 50, E-46100 Burjassot, Valencia, Spain.
Agulló
C
C
Castelblanque
L
L
Cuñat
A C
AC
Navarro
I
I
Ramírez De Arellano
M C
MC
D000114:Acetylene / Q000031:analogs & derivatives*; D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes; D007202:Indicators and Reagents; D008968:Molecular Conformation; D015394:Molecular Structure; D013729:Terpenes / Q000138:chemical synthesis* / Q000737:chemistry*; D014753:Vinyl Compounds / Q000737:chemistry*
D000447:Aldehydes; D000480:Alkynes; D007202:Indicators and Reagents; D013729:Terpenes; D014753:Vinyl Compounds; C022918:acetylenedicarboxylic acid dimethyl ester; D000114:Acetylene