title: Supersonic jet/multiphoton ionization/mass spectrometry of dioxins formed by the thermal reaction of phenols in the absence and presence of an FeCl3 catalyst.
abstract: Dioxins, which are thermally produced from several precursor molecules, were investigated by supersonic jet/multiphoton ionization/time-of-flight mass spectrometry (SSJ/MPI/TOF-MS). Dibenzofuran and dibenzo-p-dioxin were efficiently generated from o-chlorophenol and also from phenol after a chlorination reaction with FeCl3. The present technique was employed for the continuous monitoring of a specified isomer, e.g., m-chlorophenol, which is formed at relatively low temperatures by chlorination of phenol with FeCl3. A dimerization reaction that forms a dibenzo-p-dioxin, e.g., dichlorodibenzo-p-dioxin from 2,4-dichlorophenol, at relatively high temperatures was also investigated. The number of chlorine atoms in the dioxin molecule was largely correlated with the number of chlorine atoms in the precursor molecule. However, some unexpected compounds, which probably occur by dechlorination and rearrangement reactions, were also found. Thus, the SSJ/MPI/TOF-MS technique represents a sensitive, as well as selective, analytical method for monitoring thermally generated dioxins.
authors.affiliation: Department of Chemical Science and Technology, Faculty of Engineering, Kyushu University, Fukuoka, Japan.
authors.forename: T
authors.initials: T
authors.lastname: Uchimura
authors.forename: T
authors.initials: T
authors.lastname: Imasaka
mesh_terms: D002384:Catalysis; D002712:Chlorides; D004147:Dioxins / Q000032:analysis*; D004785:Environmental Pollutants / Q000032:analysis*; D005290:Ferric Compounds; D013058:Mass Spectrometry; D010636:Phenols / Q000737:chemistry*
chemical_list: D002712:Chlorides; D004147:Dioxins; D004785:Environmental Pollutants; D005290:Ferric Compounds; D010636:Phenols; C024555:ferric chloride