New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation Of carbonyl compounds with N-formylmorpholine derivatives
A new stable equivalent of the trifluoromethyl anion has been synthesized from fluoroform. It reacts with nonenolizable carbonyl compounds such as the Ruppert's reagent.
Billard
T
Synthese, Electrosynthese et Reactivite des Composes Organiques Fluores (SERCOF), UMR CNRS 5622, Universite Claude Bernard-Lyon I, 43 Bd du 11 Novembre 1918, F-69622 Villeurbanne, France.
Bruns
S
Langlois
BR