Difluoroboroxymolybdenum Fischer carbene complexes as precursors of acyl radicals: dimerization and trapping with electron-deficient alkenes
Pentacarbonyl acyl molybdates 1 react with boron trifluoride to give difluoroboroxy Fischer carbene complexes 2, which undergo loss of the metal fragment at room temperature to form 1,2-diketones 3, 1,2-hydroxy ketones 4, or dimers 5 through a dimerization or decarbonylation-dimerization process of acyl radicals. Decomposition of 2 in the presence of electron-deficient alkenes 11 and 18 furnishes the two-, three-, and four-component coupling products 12, 13, 19, 20, and 21.
Barluenga
J
Instituto Universitario de Quimica Organometalica, Enrique Moles, Unidad Asociada al CSIC, Spain. barluenga@sauron.quimica.uniovi.es
Rodriguez
F
Fananas
FJ