Frequency of OH in solutions of n-butanol in carbon tetrachloride: effect of dilution.
It is noted that the 1 <-- 0 transition for nuOH shows a blue shift as the relative concentration of n-butanol in a CCl4-n-butanol is reduced. The magnitude of the shift decreases for the 2 <-- 0 transition and there is almost no shift for the 3 <-- 0 transition. These observations are consistent with the observed red shift [Y. Mizugai, F. Takimoto, M. Katayama, Chem. Phys. Lett. 76 (1980) 615] on dilution for the 5 <-- 0 transition in n-butanol. The observations have been interpreted on the basis of formation of O-H....Cl hydrogen bond.
Srivastava
P K
PK
Department of Physics, Banaras Hindu University, Varanasi, India.
Rai
D K
DK
Rai
S B
SB
D020001:1-Butanol / Q000737:chemistry*; D002251:Carbon Tetrachloride / Q000737:chemistry*; D006859:Hydrogen; D012996:Solutions
D012996:Solutions; D006859:Hydrogen; D020001:1-Butanol; D002251:Carbon Tetrachloride