title: [PtCl]
abstract: The ionic complex [PtCl(3)(C(2)H(4))](-)[(S,S)-(PhMeCH)(2)NH(2)](+) containing a chiral secondary amine is a new and versatile chiral derivatizing agent (CDA) for the determination of the enantiomeric composition of several unsaturated compounds including simple olefins: the diastereoisomeric mixtures arising from the exchange of ethylene by the unsaturated analytes are easily detected by (195)Pt NMR spectroscopy.
authors.affiliation: Centro di Studio del CNR per le Macromolecole Stereordinate ed Otticamente Attive, Dipartimento di Chimica e Chimica Industriale, via Risorgimento 35, 56126 Pisa, Italy.
authors.initials: G
authors.lastname: Uccello-Barretta
authors.initials: R
authors.lastname: Bernardini
authors.initials: R
authors.lastname: Lazzaroni
authors.initials: P
authors.lastname: Salvadori