Redox reactions via vanadium-induced electron transfer.
One-electron reduction and oxidation induced by vanadium complexes are demonstrated to be useful in oxidative and reductive transformations of carbonyl compounds. The redox interaction between vanadium complexes and redox-active ligands is achieved with coenzyme PQQ and polyanilines that afford the corresponding redox systems.
Hirao
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Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Japan.
D004579:Electron Transport; D008024:Ligands; D008956:Models, Chemical; D015394:Molecular Structure; D010084:Oxidation-Reduction; D045542:PQQ Cofactor; D015363:Quinolones / Q000737:chemistry; D011809:Quinones / Q000737:chemistry; D017968:Vanadium Compounds / Q000737:chemistry*
D008024:Ligands; D015363:Quinolones; D011809:Quinones; D017968:Vanadium Compounds; D045542:PQQ Cofactor