Kinetics of nitrous acid formation in a two-phase tri-n-butylphosphate-diluent/aqueous nitric acid extraction system under the effect of power ultrasound
The kinetics of nitrous acid formation were investigated in two-phase tri-n-butylphosphate (TBP)-diluent/HNO3 (1.5-6.0 mol l-1) systems, where diluent is n-C16H34, n-C12H26, n-C9H20 and i-C8H18, under the effect of power ultrasound at 20 kHz frequency under Ar atmosphere. The rate of HNO2 sonochemical formation decreases with the rise in diluent vapor pressure. The HNO2 formed is distributed between the aqueous and organic phases due to its extraction with TBP. The kinetics of HNO2 sonochemical formation in the two-phase system exhibits induction periods due to NOx (NO + NO2) gas reactions in the HNO3 medium. This induction period decreases with increasing HNO3 concentration and ultrasound intensity. The HNO2 steady-state concentration was obtained under long-time sonication as the result of HNO2 sonochemical decomposition. HNO2 decomposes faster under sonication in the aqueous phase than in the organic phase.
Nikitenko
SI
CEA, Vallee du Rhone (Marcoule), DRRV, SEMP/LCAA, Bagnols sur Ceze, France.
Moisy
P
Venault
L
Madic
C