A cavitand-porphyrin hybrid.
[structure: see text] Host-guest complexes of a new open-ended cavitand show unprecedented stabilities. Simultaneous binding in the cavity and at the metalloporphyrin affects both the kinetics and the thermodynamics of caviplex formation.
Starnes
S D
SD
The Skaggs Institute for Chemical Biology and The Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.
Rudkevich
D M
DM
Rebek
J
J
D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D011166:Porphyrins / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet
D007202:Indicators and Reagents; D011166:Porphyrins; D011725:Pyridines