Synthesis of expanded graphdiyne substructures
Graphdiyne (1) is a member of a novel family of interesting and potentially important allotropes of carbon. Reported herein are the synthesis and spectroscopic characterization of model substructures 2-6. The macrocycles were prepared by the intramolecular cyclization of suitable alpha,omega-polyynes. Key to the success of this approach was the development of an in situ protiodesilylation/alkynylation reaction utilizing reactive phenylbutadiyne synthons. This new method has allowed for the preparation of the largest, most complete substructures of the graphdiyne network to date (3-6).
Wan
WB
Department of Chemistry, University of Oregon, Eugene 97403-1253, USA.
Brand
SC
Pak
JJ
Haley
MM