Synthesis of (+/-)-11alpha-hydroxy-3-oxo-6alphaH,7alphaH, 10betaMe-eudesman-1,2-4,5-dien-6,12-olide.
The synthesis of (+/-)-11alpha-hydroxy-3-oxo-6alphaH,7alphaH, 10betaMe-eudesman-1,2-4,5-dien-6,12-olide (1), previously isolated from Melanoselinum decipiens, is described, and its structure has been corrected.
Moreno-Dorado
F J
FJ
Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Cádiz, Apartado 40, 11510 Puerto Real, Cádiz, Spain.
Guerra
F M
FM
Aladro
F J
FJ
Bustamante
J M
JM
Jorge
Z D
ZD
Massanet
G M
GM
D019661:Apiaceae / Q000737:chemistry*; D007783:Lactones / Q000138:chemical synthesis*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D012717:Sesquiterpenes / Q000138:chemical synthesis*; D045787:Sesquiterpenes, Eudesmane; D013057:Spectrum Analysis
C413029:11-hydroxy-3-oxo-6H,7H-10-methyl-eudesman-1,2-4,5-dien-6,12-olide; D007783:Lactones; D012717:Sesquiterpenes; D045787:Sesquiterpenes, Eudesmane