Synthesis of thiophenyl substituted cyclohexa-2,4-dien-1-one and its photocleavage coupling reaction with amines.
Thiophenyl substituted cyclohexa-2,4-dien-1-ones were synthesized and photolyzed in the presence of various amines to afford the amides containing diene moeties via the ketene intermediate under visible light irradiation at 38 degrees C.
Department of Chemistry, Kyungsung University, Pusan, South Korea. twkwon@star.kyungsung.ac.kr
T W
TW
Kwon
Y M
YM
Kim
S J
SJ
Song
Y U
YU
Kwon
S K
SK
Chung
D000577:Amides / Q000737:chemistry; D000588:Amines / Q000737:chemistry*; D003512:Cyclohexanones / Q000138:chemical synthesis* / Q000737:chemistry*; D007202:Indicators and Reagents; D008027:Light; D015394:Molecular Structure; D010782:Photolysis; D013329:Structure-Activity Relationship; D013440:Sulfides / Q000138:chemical synthesis* / Q000737:chemistry*
D000577:Amides; D000588:Amines; D003512:Cyclohexanones; D007202:Indicators and Reagents; D013440:Sulfides