Thin molecular films of supramolecular porphyrins.
A relevant series of symmetric supramolecular porphyrins has been obtained by attaching four [RuII(bipy)2Cl] groups to the pyridyl substituents of meso-tetra(4-pyridyl)porphyrin and its metallated derivatives. These compounds display a rich electrochemistry and versatile catalytic, electrocatalytic and photochemical properties, associated with the ruthenium-bipyridine and the porphyrin complexes. These properties can be transferred to the electrodes by attaching thin molecular films of the compounds, by dip-coating, electrostatic assembly or electropolymerization. In this way, the interesting properties of those supermolecules and supramolecular assemblies can be used to prepare molecular devices and sensors.
Araki
K
K
Instituto de Química-USP, Brazil. koiaraki@iq.usp.br
Lima
S de S
Sde S
Winnischofer
H
H
D015374:Biosensing Techniques / Q000379:methods*; D046911:Macromolecular Substances; D013058:Mass Spectrometry; D011166:Porphyrins / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000737:chemistry
D046911:Macromolecular Substances; D011166:Porphyrins; D017975:Ruthenium Compounds