Performance-enhanced "tunable" capillary microwave-induced plasma mass spectrometer for gas chromatography detection.
Improvements in the stability and performance of a capillary microwave-induced plasma-mass spectrometer (MIP-MS) were achieved by optimizing power transfer to the cavity using a tunable coaxial MIP. The MIP, operating at atmospheric pressure, was sustained with 30 mL/min He and 60 W of power. Measurement precision and sensitivity for the standard waveguide and coaxial systems were determined using 16 organochlorine pesticide solutions separated by gas chromatography (GC). The linear dynamic range obtained with the tunable MIP-MS extended over 3 orders of magnitude, a 10 time improvement with respect to the standard MIP. Detection limits were between 3 and 19 pg of Cl mol(-1) s(-1), 7 times lower than the detection limits obtained with the nontunable MIP-MS. Analysis of pesticides containing sulfur atoms was also possible, further demonstrating multielement MIP-MS detection. Excellent accuracy (10% recovery) and precision (5% RSD) were found for the detection of the pesticides in a petroleum-contaminated reference soil. By placing the GC column at the plasma expansion stage, molecular fragmentation of a mixture of volatile organic compounds was also demonstrated. With the MS operated in the selected ion monitoring mode, measurement sensitivity was approximately 500 pg/s per compound.
Zapata
A M
AM
Department of Chemistry, Center for Field Analytical Studies and Technology, Tufts University, Medford, Massachusetts 02155, USA.
Robbat
A
A
D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D008872:Microwaves; D009930:Organic Chemicals / Q000032:analysis; D010575:Pesticides / Q000032:analysis*; D010578:Petroleum; D012987:Soil / Q000032:analysis; D012989:Soil Pollutants / Q000032:analysis
D009930:Organic Chemicals; D010575:Pesticides; D010578:Petroleum; D012987:Soil; D012989:Soil Pollutants