A bulk electrolysis Raman spectroelectrochemical cell using a rotating electrode
A fast bulk electrolysis Raman spectroelectrochemical cell is described. The cell employs a large-area platinum gauze and disk assembly which can be rotated at speeds up to 5,000 rpm. The complete electrolysis of a 5-mL solution can be achieved in less than 6 min using a 2,000 rpm rotation rate. The resonance Raman spectrum of (TPP*+)Cu(II) was collected in situ in this cell.
Hu
Q
Department of Chemistry, The University of Calgary, Alberta, Canada.
Hinman
AS