The E(2)Sigma(+) --> C(2)Pi Transition of NO and Term Values for the A, D, E, and C Lowest Rydberg Levels.
The E(2)Sigma(+) --> C(2)Pi Rydberg-Rydberg transition of (14)N(16)O near 8492 cm(-1) has been studied by Fourier transform spectrometry in the emission from a dc excited supersonic jet expansion and from a dc discharge under equilibrium conditions. The same transition has also been observed in laser-induced stimulated emission. Line wavenumbers of the 0-0, 1-1, and 2-2 bands, together with data for previously published near-infrared transitions, have been reduced to consistent sets of rovibronic term values for v = 0, 1, and 2 of the A(2)Sigma(+), D(2)Sigma(+), E(2)Sigma(+), and C(2)Pi states which frequently serve as intermediates in the multiphoton excitation of higher Rydberg levels of NO. Copyright 2000 Academic Press.
Steacie Institute for Molecular Sciences, National Research Council of Canada, 100 Sussex Drive, Ottawa, Ontario, K1A 0R6, Canada
KP
Huber
M
Vervloet
C
Amiot
J
Vergès
K
Tsukiyama