Synthesis of (+/-)-11alpha-hydroxy-3-oxo-6alphaH,7alphaH, 10betaMe-eudesman-1,2-4,5-dien-6,12-olide.
The synthesis of (+/-)-11alpha-hydroxy-3-oxo-6alphaH,7alphaH, 10betaMe-eudesman-1,2-4,5-dien-6,12-olide (1), previously isolated from Melanoselinum decipiens, is described, and its structure has been corrected.
Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Cádiz, Apartado 40, 11510 Puerto Real, Cádiz, Spain.
F J
FJ
Moreno-Dorado
F M
FM
Guerra
F J
FJ
Aladro
J M
JM
Bustamante
Z D
ZD
Jorge
G M
GM
Massanet
D019661:Apiaceae / Q000737:chemistry*; D007783:Lactones / Q000138:chemical synthesis*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D012717:Sesquiterpenes / Q000138:chemical synthesis*; D045787:Sesquiterpenes, Eudesmane; D013057:Spectrum Analysis
C413029:11-hydroxy-3-oxo-6H,7H-10-methyl-eudesman-1,2-4,5-dien-6,12-olide; D007783:Lactones; D012717:Sesquiterpenes; D045787:Sesquiterpenes, Eudesmane