title: Entropically driven colloidal crystallization on patterned surfaces
abstract: We investigate the self-assembly of colloidal spheres on periodically patterned templates. The surface potentials and the surface phases are induced entropically by the presence of dissolved, nonadsorbing polymers. A rich variety of two-dimensional fluidlike and solidlike phases was observed to form on template potentials with both one- and two-dimensional symmetry. The same methodology was then used to nucleate an oriented single fcc crystal more than 30 layers thick. The general approach provides a new route for directed self-assembly of novel mesoscopic structures.
authors.affiliation: Department of Physics and Astronomy, University of Pennsylvania, 209 S. 33rd Street, Philadelphia, Pennsylvania 19104-6396, USA.
authors.initials: Kh
authors.lastname: Lin
authors.initials: JC
authors.lastname: Crocker
authors.initials: V
authors.lastname: Prasad
authors.initials: A
authors.lastname: Schofield
authors.initials: DA
authors.lastname: Weitz
authors.initials: TC
authors.lastname: Lubensky
authors.initials: AG
authors.lastname: Yodh