Synthesis of new bicyclic P-N ligands and their application in asymmetric Pd-catalyzed pi-allyl alkylation and Heck reaction.
[structure: see text] The synthesis of phosphine oxazoline ligands based on P-chiral 1-phosphanorbornadienes is reported. The use of these ligands in palladium catalyzed asymmetric allylation and Heck reaction is described.
Gilbertson
S R
SR
Department of Chemistry, Washington University, One Brookings Drive, Campus Box 1034, St. Louis, Missouri 63170-4899, USA. srg@wuchem.wustl.edu
Genov
D G
DG
Rheingold
A L
AL