Influence of the conformation of methoxy-(2-naphthyl)acetates (2NMA esters) on their chemical reactions.
An SN2 reaction (NaI) of 1,7-di(methanesulfoxyl)heptadien-4-yl methoxy-(2-naphthyl)acetate and a tributyltin hydride reduction of 1,7-diiodo-4-yl methoxy-(2-naphthyl)acetate (2NMA) is crucial for determination of the absolute configuration of secondary alcohols.
Fukuyoshi
S
S
Faculty of Pharmaceutical Sciences, Tokushima University, Japan.
Ooi
T
T
Kusumi
T
T
D000085:Acetates / Q000737:chemistry*; D000438:Alcohols / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D009281:Naphthalenes / Q000737:chemistry*
D000085:Acetates; D000438:Alcohols; D009281:Naphthalenes