Molecular interpenetration within the columnar structure of crystalline anilino-beta-cyclodextrin.
A single crystal of mono(6-anilino-6-deoxy)-beta-cyclodextrin was prepared, and its crystal structure was determined by X-ray crystallographic analysis, which clearly revealed that the anilino groups are consecutively included intermolecularly into the adjacent cyclodextrin cavities in the crystal, thus giving rise to a consolidated column, located on a 2(1)-screw axis.
Liu
Y
Y
Department of Chemistry, Nankai University, Tianjin 300071, China yuliu@public.tpt.tj.cn
You
C C
CC
Zhang
M
M
Weng
L H
LH
Wada
T
T
Inoue
Y
Y