title: Synthetic utility and mechanistic implications of the Fries rearrangement of hydroquinone diesters in boron trifluoride complexes
abstract: Reactions of boron trifluoride methyl and ethyl etherate complexes with hydroquinone diesters yield monomethyl and monoethyl derivatives of acetylhydroquinones. The use of sterically hindered boron trifluoride etherate complexes results in acetylhydroquinone derivatives. This procedure represents a one-step synthesis of acetylhydroquinone derivatives, important building blocks for a variety of synthetic applications.
authors.affiliation: Department of Chemistry, Lebanon Valley College, Annville, Pennsylvania 17003, USA.
authors.initials: JL
authors.lastname: Boyer
authors.initials: JE
authors.lastname: Krum
authors.initials: MC
authors.lastname: Myers
authors.initials: AN
authors.lastname: Fazal
authors.initials: CT
authors.lastname: Wigal