title: Stereocontrolled synthesis of the 22E,24 beta(S)-trifluoromethyl steroidal side chain and its application to the synthesis of fluorinated analogues of naturally occurring sterols.
authors.affiliation: Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, Peoples Republic of China. jiangb@pub.sioc.ac.cn
authors.forename: B
authors.initials: B
authors.lastname: Jiang
authors.forename: Y
authors.initials: Y
authors.lastname: Liu
authors.forename: W
authors.initials: W
authors.lastname: Zhou
mesh_terms: D018360:Crystallography, X-Ray; D003500:Cyclization; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D013237:Stereoisomerism; D013259:Steroids, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D013261:Sterols / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D007202:Indicators and Reagents; D013259:Steroids, Fluorinated; D013261:Sterols