Excitonic funneling in extended dendrimers with nonlinear and random potentials
The mean first passage time (MFPT) for photoexcitations diffusion in a funneling potential of artificial treelike light-harvesting antennas (phenylacetylene dendrimers with generation-dependent segment lengths) is computed. Effects of the nonlinearity of the realistic funneling potential and slow random solvent fluctuations considerably slow down the center-bound diffusion beyond a temperature-dependent optimal size. Diffusion on a disordered Cayley tree with a linear potential is investigated analytically. At low temperatures we predict a phase in which the MFPT is dominated by a few paths.
Raychaudhuri
S
Department of Physics and Astronomy, University of Rochester, Rochester, New York 14627, USA.
Shapir
Y
Chernyak
V
Mukamel
S