Synthesis of (+/-)-methyl bishomononactate, a monomeric component of polynactin antibiotics.
The synthesis of (+/-)-methyl bishomononactate, one of the monomeric components of polynactin antibiotics (macrotetrolides), was achieved via cis-selective iodoetherification as the key step.
Hanadate
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Division of Life Science, Graduate School of Agricultural Science, Tohoku University, Sendai, Japan.
Kiyota
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H
Oritani
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D000900:Anti-Bacterial Agents / Q000138:chemical synthesis*; D018942:Macrolides / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D013237:Stereoisomerism
D000900:Anti-Bacterial Agents; D018942:Macrolides; C050476:nonactin