[A method for determining a rate constant for biexponential processes using data on dynamics of accumulating the end product of a reaction].
A new method the rate constant determination of some biexponential processes is suggested. The method is based on the asymptotic solution of transcendental irrational equations, described such processes. This method can be used when kinetics of the final product of reaction is known. The values of the rate constants obtained by suggested method are precise, if the data used for calculation are also precise. In the other case methods of mathematical statistics should be used for evaluation of the slopes of kinetics curves in the semi-logarithmic coordinates.
Bobrovnik
S A
SA
A.V. Palladin Institute of Biochemistry, NAS of Ukraine, Kyiv. sab@biochem.kiev.ua
D055598:Chemical Phenomena; D002621:Chemistry; D007700:Kinetics; D008722:Methods