title: First synthesis of a alpha-trifluoromethyl allenol ether via the Julia-Lythgoe process.
abstract: Alpha-trifluoromethyl allenol ethers 9a-e were prepared in moderate to good yields by the Julia-Lythgoe process using beta-ethoxy-beta-trifluoromethyl vinylic sulfone 3. Several reactions of 9c were examined to give alpha,beta-unsaturated trifluoromethyl ketone derivatives 11 and 12.
authors.affiliation: Department of Chemistry, Faculty of Education, Gifu University, Japan. yoshimae@cc.gifu-u.ac.jp
authors.forename: M
authors.initials: M
authors.lastname: Yoshimatsu
authors.forename: M
authors.initials: M
authors.lastname: Hibino
mesh_terms: D004987:Ethers / Q000138:chemical synthesis*; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis*; D006868:Hydrolysis; D009682:Magnetic Resonance Spectroscopy; D013450:Sulfones; D014753:Vinyl Compounds
chemical_list: D004987:Ethers; D006845:Hydrocarbons, Fluorinated; D013450:Sulfones; D014753:Vinyl Compounds