Line Positions and Intensities in the 2nu(2)/nu(4) Vibrational System of (14)NH(3) near 5-7 µm.
Line positions and intensities belonging to the vibrational system 2nu(2)/nu(4) of ammonia (14)NH(3) are measured and analyzed between 1200 and 2200 cm(-1) in order to improve the molecular database. For this, laboratory spectra are obtained at 0.006 and 0.011 cm(-1) unapodized resolution and with 4% precisions for the intensities using Fourier transform spectrometers located at the Kitt Peak National Observatory and the Jet Propulsion Laboratory. The observed data contain transitions of the nu(4) fundamental band near 1626.276(1) and 1627.375(2) cm(-1) (for s and a inversion upper states, respectively) and the 2nu(2) overtone band near 1597.470(3) and 1882.179(5) cm(-1) (for s and a inversion states, respectively). A total of 2345 lines with J' </= 15 is assigned from which 2114 line positions with J' </= 15 are fitted using an effective rotation-inversion-rotation Hamiltonian to achieve an rms of 0.003 cm(-1) with 57 molecular parameters. Over 1200 intensity measurements are modeled to +/-4.7% using 16 terms of the dipole moment expansion. A dyad model is used in order to model all the interactions expected within the 2nu(2)/nu(4) system. The bandstrengths of 2nu(2) (s <-- a), 2nu(2) (a <-- s), and nu(4) (s <-- s and a <-- a) are estimated to be 6.68(24), 0.201(5), and 116(3) cm(-2) atm(-1), respectively, at 296 K. The prediction generated by this study is available for planetary studies. Copyright 2000 Academic Press.
Cottaz
C
Laboratoire de Photophysique Moléculaire, Université Paris Sud, Unité propre de C.N.R.S., Bâtiment 210, Orsay Cédex, 91405, France
Kleiner
I
Tarrago
G
Brown
LR
Margolis
JS
Poynter
RL
Pickett
HM
Fouchet
T
Drossart
P
Lellouch
E