Bis-triiodide von 1,2-ethandiaminkomplexen am beispiel des metalls kupfer
In bis(1,2-ethanediamine-N,N')bis[triiodo(1-)-I]copper, [Cu(I(3))(2)(C(2)H(8)N(2))(2)], the triiodide anions form chains parallel to [001]. The central metal ion (site symmetry 2/m) of the complex cation is coordinated to four N atoms and to two I atoms. The geometry of the square-bipyramidal complex is as expected, with d(Cu-N) = 2.006 (5) and d(Cu-I) = 3.3600 (9) A.
Wieczorrek
C
Institut fur Anorganische Chemie, Universitat zu Koln, Greinstrasse 6, D-50939 Koln, Deutschland. cwieczorrek@macherey-nagel.de.