Use of thallium(I) ethoxide in Suzuki cross coupling reactions.
[reaction: see text]Thallium(I) ethoxide promotes Suzuki cross couplings for a range of vinyl- and arylboronic acids with vinyl and aryl halide partners in good to excellent yields. This reagent offers distinct advantages over thallium(I) hydroxide in terms of commercial availability, stability, and ease of use.
Frank
S A
SA
Department of Chemistry, University of Michigan, Ann Arbor 48109, USA.
Chen
H
H
Kunz
R K
RK
Schnaderbeck
M J
MJ
Roush
W R
WR
D001897:Boronic Acids / Q000138:chemical synthesis; D007202:Indicators and Reagents; D009942:Organometallic Compounds / Q000737:chemistry*; D012997:Solvents; D014753:Vinyl Compounds / Q000138:chemical synthesis
D001897:Boronic Acids; D007202:Indicators and Reagents; D009942:Organometallic Compounds; D012997:Solvents; D014753:Vinyl Compounds; C062376:thallous ethoxide