Unknown bisethylisooctanollactone isomers in industrial waste water. Isolation, identification and occurrence in surface water.
Unknown bisethylisooctanollactone isomers (BIOL isomers) which are chemical by-products of butyraldehyde synthesis, were isolated from industrial waste water applying various purification methods with subsequent semi-preparative high-performance liquid chromatography. Through interpretation of mass spectra after gas chromatographic separation the individual BIOL isomers were identified as stereoisomers of 2,4-diethyl-3-n-propyl-delta-valerolactone. Thus, it was possible for the first time to quantify the BIOL isomers in the river Rhine, Germany, with a mean sum concentration of 1.6 microg l(-1). A regular analysis performed over a period of almost two years of the river Rhine always gave the same ratio among the individual isomers. Drinking water production out of such water was studied, revealing that activated carbon filtration led to a 95% reduction of the BIOL concentration. Additional subsoil passage and a subsequent slowsand filtration led to a total elimination due to microbial degradation. Even if the BIOL isomers proved not to be relevant to drinking water, their behavior in the aquatic environment needs to be more thoroughly investigated since these compounds have been discharged for many years in high amounts into the river Rhine.
Knepper
T P
TP
ESWE Institute for Water Research and Water Technology, Wiesbaden, Germany. thomas.knepper@stadtwerke-wiesbaden.de
Müller
J
J
Wulff
T
T
Maes
A
A
D002138:Calibration; D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D007220:Industrial Waste / Q000032:analysis*; D007783:Lactones / Q000032:analysis / Q000302:isolation & purification*; D009795:Octanes / Q000032:analysis / Q000302:isolation & purification*; D020033:Protein Isoforms / Q000032:analysis / Q000302:isolation & purification; D012722:Sewage / Q000032:analysis; D014867:Water / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000302:isolation & purification*; D018508:Water Purification
D007220:Industrial Waste; D007783:Lactones; D009795:Octanes; D020033:Protein Isoforms; D012722:Sewage; D014874:Water Pollutants, Chemical; D014867:Water