title: Analysis of Three-dimensional Atom-probe Data by the Proximity Histogram.
abstract: The three-dimensional (3D) atom-probe technique produces a reconstruction of the elemental chemical identities and three-dimensional positions of atoms field evaporated from a sharply pointed metal specimen, with a local radius of curvature of less than 50 nm. The number of atoms collected can be on the order of one million, representing an analysis volume of approximately 20 nm x 20 nm x 200 nm (80,000 nm(3)). This large amount of data allows for the identification of microstructural features in a sample, such as grain or heterophase boundaries, if the feature density is large enough. Correlation of the measured atomic positions with these identified features results in an atom-by-atom description of the chemical environment of crystallographic defects. This article outlines a data compilation technique for the generation of composition profiles in the vicinity of interfaces in a geometrically independent way. This approach is applied to quantitative determination of interfacial segregation of silver at a MgO/Cu(Ag) heterophase interface.
authors.affiliation: Department of Materials Science and Engineering, Northwestern University, 2225 N. Campus Drive, Evanston, IL 60208-3108
authors.forename: O C
authors.initials: OC
authors.lastname: Hellman
authors.forename: J A
authors.initials: JA
authors.lastname: Vandenbroucke
authors.forename: J
authors.initials: J
authors.lastname: Rüsing
authors.forename: D
authors.initials: D
authors.lastname: Isheim
authors.forename: D N
authors.initials: DN
authors.lastname: Seidman