Two distinct raman profiles of glassy dilute LiCl solution
We make glass of dilute LiCl aqueous solution by cooling micrometer-sized droplets of the solution extremely quickly and measure the Raman spectra of the glass. It is found that the OH stretching vibration mode of the glass of dilute solution is composed of the OH stretching vibration mode of pure glassy water and that of the glass of solvent water in the highly concentrated solution. This is consistent with the possibility of the existence of two distinct glassy states of water in dilute LiCL solution at low temperature.
Suzuki
Y
National Institute for Research in Inorganic Materials (NIRIM), 1-1, Namiki, Tsukuba, Ibaraki 305-0044, Japan and and Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Corporation (JST), Kawaguchi, Saita.
Mishima
O