Chemical characterization of bohrium (element 107)
The arrangement of the chemical elements in the periodic table highlights resemblances in chemical properties, which reflect the elements' electronic structure. For the heaviest elements, however, deviations in the periodicity of chemical properties are expected: electrons in orbitals with a high probability density near the nucleus are accelerated by the large nuclear charges to relativistic velocities, which increase their binding energies and cause orbital contraction. This leads to more efficient screening of the nuclear charge and corresponding destabilization of the outer d and f orbitals: it is these changes that can give rise to unexpected chemical properties. The synthesis of increasingly heavy elements, now including that of elements 114, 116 and 118, allows the investigation of this effect, provided sufficiently long-lived isotopes for chemical characterization are available. In the case of elements 104 and 105, for example, relativistic effects interrupt characteristic trends in the chemical properties of the elements constituting the corresponding columns of the periodic table, whereas element 106 behaves in accordance with the expected periodicity. Here we report the chemical separation and characterization of six atoms of element 107 (bohrium, Bh), in the form of its oxychloride. We find that this compound is less volatile than the oxychlorides of the lighter elements of group VII, thus confirming relativistic calculations that predict the behaviour of bohrium, like that of element 106, to coincide with that expected on the basis of its position in the periodic table.
Eichler
R
Departement fur Chemie und Biochemie, Universitat Bern, Switzerland.
Bruchle
W
Dressler
R
Dullmann
CE
Eichler
B
Gaggeler
HW
Gregorich
KE
Hoffman
DC
Hubener
S
Jost
DT
Kirbach
UW
Laue
CA
Lavanchy
VM
Nitsche
H
Patin
JB
Piguet
D
Schadel
M
Shaughnessy
DA
Strellis
DA
Taut
S
Tobler
L
Tsyganov
YS
Turler
A
Vahle
A
Wilk
PA
Yakushev
AB