[H3N]
The structure of the title compound, pentane-1,5-diammonium aluminium(III) hydrogen bis(phosphate), (C(5)H(16)N(2))[AlP(2)O(8)H], obtained solvothermally at 473 K, has been determined by single-crystal X-ray diffraction. It consists of one-dimensional [AlP(2)O(8)H](2-) macroanions, connected to each other by pentanediammonium cations. Contrary to similar compounds with P/Al = 2, the three-dimensional structure is mainly obtained via a network of hydrogen bonds.
Phan Thanh S
Laboratoire des Fluorures - UPRES-A 6010 Faculte des Sciences, Universite du Maine, Avenue Olivier-Messiaen, 72085 Le Mans CEDEX 9, France.
Marrot
J
Renaudin
J
Maisonneuve
V