New syntheses of the rice moth and stink bug pheromones by employing (2R, 6S)-7-acetoxy-2,6-dimethyl-1-heptanol as a building block.
(2R, 6R, 10R)-6,10,14-Trimethyl-2-pentadecanol, the female pheromone of the rice moth (Corcyra cephalonica), methyl (2R, 6R, 10R)-2,6,10-trimethyltridecanoate, the male pheromone of the stink bug (Euschistus heros) were synthesized by employing (2R, 6S)-7-acetoxy-2,6-dimethyl-1-heptanol as the common chiral building block.
Nakamura
Y
Y
Department of Chemistry, Faculty of Science, Science University of Tokyo, Japan.
Mori
K
K
D000818:Animals; D003651:Decanoates / Q000138:chemical synthesis*; D005233:Fatty Alcohols / Q000138:chemical synthesis*; D005260:Female; D019850:Heptanol / Q000031:analogs & derivatives*; D008297:Male; D008956:Models, Chemical; D009036:Moths; D012724:Sex Attractants / Q000138:chemical synthesis*
C419345:6,10,14-trimethyl-2-pentadecanol; C419344:7-acetoxy-2,6-dimethyl-1-heptanol; D003651:Decanoates; D005233:Fatty Alcohols; D012724:Sex Attractants; C419346:methyl-2,6,10-trimethyltridecanoate; D019850:Heptanol