1,6-anhydro-2, 3-di-O-benzyl-5C-[(R)-ethoxycarbonyl(hydroxy)methyl]-beta-L-altrofur ano se.
The crystal structure of the title compound, C(24)H(28)O(8), has been determined. The conformation of the furanose ring can be described as 58% ideal envelope (O)E conformer and 42% ideal twisted (O)T(1) conformer. The 1,3-dioxane ring adopts a chair conformation with the anhydro-O atom pointing upwards. Both phenyl rings are quasi-perpendicular to the mean plane of the furanose ring. The hydrogen bonding is intermolecular and consists of infinite chains parallel to the a axis.
Taillefumier
C
C
Groupe SUCRES, Unité Mixte CNRS 7565 - Université Henri Poincaré - Nancy I, BP 239, 54506 Vandoeuvre-lès-Nancy, France.
Charron
C
C
Chapleur
Y
Y
Aubry
A
A
D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D004791:Enzyme Inhibitors / Q000138:chemical synthesis* / Q000737:chemistry; D013186:Farnesyl-Diphosphate Farnesyltransferase / Q000037:antagonists & inhibitors; D008958:Models, Molecular; D008968:Molecular Conformation
C414940:1,6-anhydro-2,3-di-O-benzyl-5C-(ethoxycarbonyl(hydroxy)methyl)altrofuranose; D019086:Bridged Bicyclo Compounds, Heterocyclic; D004791:Enzyme Inhibitors; D013186:Farnesyl-Diphosphate Farnesyltransferase