Comparison of two extraction methods independently developed on two conceptually different automated supercritical fluid extraction systems for the determination of polychlorinated biphenyls in sediments.
Two extraction methods that independently have been developed on conceptually different automated supercritical fluid extraction systems, ISCO SFX 3560 (syringe pump and liquid trapping) and Hewlett-Packard 7680T SFE (reciprocating pump and solid-phase trapping), were compared for the extraction of polychlorinated biphenyls from two Swedish sediments. The results demonstrated that the high-temperature ISCO method in some cases yields a more exhaustive extraction, but also less clean extracts due to co-extraction of unwanted matrix components which are all present in the trapping solvent. The medium-temperature Hewlett-Packard method may sometimes cause problems with quantitative recoveries, but on the other hand it yields very clean extracts due to the extra selectivity resulting from collection on a solid-phase trap.
Nilsson
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Department of Analytical Chemistry, Lund University, Sweden. tobias.nilsson@analykem.lu.se
Björklund
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Bøwadt
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D001331:Automation; D002845:Chromatography / Q000379:methods*; D011078:Polychlorinated Biphenyls / Q000032:analysis*; D012015:Reference Standards; D012989:Soil Pollutants / Q000032:analysis*
D012989:Soil Pollutants; D011078:Polychlorinated Biphenyls