title: 1,6-anhydro-2, 3-di-O-benzyl-5C-[(R)-ethoxycarbonyl(hydroxy)methyl]-beta-L-altrofur ano se.
abstract: The crystal structure of the title compound, C(24)H(28)O(8), has been determined. The conformation of the furanose ring can be described as 58% ideal envelope (O)E conformer and 42% ideal twisted (O)T(1) conformer. The 1,3-dioxane ring adopts a chair conformation with the anhydro-O atom pointing upwards. Both phenyl rings are quasi-perpendicular to the mean plane of the furanose ring. The hydrogen bonding is intermolecular and consists of infinite chains parallel to the a axis.
authors.affiliation: Groupe SUCRES, Unité Mixte CNRS 7565 - Université Henri Poincaré - Nancy I, BP 239, 54506 Vandoeuvre-lès-Nancy, France.
authors.forename: C
authors.initials: C
authors.lastname: Taillefumier
authors.forename: C
authors.initials: C
authors.lastname: Charron
authors.forename: Y
authors.initials: Y
authors.lastname: Chapleur
authors.forename: A
authors.initials: A
authors.lastname: Aubry
mesh_terms: D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D004791:Enzyme Inhibitors / Q000138:chemical synthesis* / Q000737:chemistry; D013186:Farnesyl-Diphosphate Farnesyltransferase / Q000037:antagonists & inhibitors; D008958:Models, Molecular; D008968:Molecular Conformation
chemical_list: C414940:1,6-anhydro-2,3-di-O-benzyl-5C-(ethoxycarbonyl(hydroxy)methyl)altrofuranose; D019086:Bridged Bicyclo Compounds, Heterocyclic; D004791:Enzyme Inhibitors; D013186:Farnesyl-Diphosphate Farnesyltransferase