Astemizole tetrachlorocuprate(II).
The structure of ¿3-[(4-fluorophenyl)methyl]-1H-benzimidazol-2-ylidene¿¿1-[2-(4- methox yphenyl)ethyl]-4-piperidin-1-io¿ammonium tetrachlorocuprate(II), (C(28)H(33)FN(4)O)[CuCl(4)], contains diprotonated cations of astemizole hydrogen bonded to three Cl atoms in two different CuCl(4)(2-) anions, with Cl.N distances in the range 3.166 (4)-3.203 (4) A. The geometry around copper is flattened tetrahedral with significantly different Cu-Cl distances which lie in the range 2.1968 (14)-2.2861 (12) A. The phenylethyl C atoms of the (4-methoxyphenyl)ethyl group are disordered indicating the presence of two conformers in the crystals.
Parvez
M
M
Department of Chemistry, The University of Calgary, 2500 University Drive NW, Calgary, Alberta, Canada T2N 1N4. parvez@ucalgary.ca.
Braitenbach
K
K
D016589:Astemizole / Q000031:analogs & derivatives* / Q000737:chemistry; D018360:Crystallography, X-Ray; D006634:Histamine H1 Antagonists / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*
D006634:Histamine H1 Antagonists; D009942:Organometallic Compounds; C417514:astemizole tetrachlorocuprate(II); D016589:Astemizole