Ozonolysis in the presence of Lewis acids: directed addition to carbonyl oxides.
The presence of Lewis acids strongly influences the distribution of products from alkene ozonolysis. Delivery of alkoxide and phenoxide ligands to a coordinated carbonyl oxide affords hydroperoxyacetals under aprotic conditions.
Dussault
P H
PH
Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0304, USA. pdussault1@unl.edu
Raible
J M
JM
D000143:Acids / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D010126:Ozone / Q000737:chemistry*; D013237:Stereoisomerism
D000143:Acids; D010087:Oxides; D010126:Ozone