Rydberg electron interferometry
A recent quantum mechanical study [W. Isaacs and M. A. Morrison, Phys. Rev. A 57, R9 (1998)] discovered pronounced oscillations in cross sections for near-resonant energy transfer collisions of rare-gas atoms with initially aligned Rydberg atoms. We analyze such collisions for 17d(m)-->18p(m(')) transitions in the Ca-He system semiclassically and show that the oscillations arise from a phase interference process unique to Rydberg target states. In addition to explaining the origin of these structures, this analysis explains their disappearance when the relative Ca-He velocity goes to infinity and/or the energy defect vanishes and their dependence on the initial and final magnetic quantum numbers of the transition.
Morrison
MA
Department of Physics and Astronomy, University of Oklahoma, Norman, Oklahoma 73019-0225, USA.
Layton
EG
Parker
GA