Doubly vibrationally enhanced four wave mixing: the optical analog to 2D NMR.
We report the development of the four wave mixing vibrational analog to 2D NMR and demonstrate its spectral selectivity, sensitivity to the interactions causing mode coupling, and ability to spectrally resolve isotopic mixtures. The method discriminates against uncoupled vibrational modes and isolates the features that are associated with intra- or intermolecular interactions.
Zhao
W
W
Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA.
Wright
J C
JC
D000042:Absorption; D006860:Hydrogen Bonding; D007259:Infrared Rays; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D055095:Optics and Photonics; D011506:Proteins / Q000737:chemistry; D012680:Sensitivity and Specificity; D013055:Spectrophotometry, Infrared / Q000379:methods*; D013059:Spectrum Analysis, Raman / Q000379:methods*; D014732:Vibration
D011506:Proteins