title: Role of the 2D surface state continuum and projected band gap in charge transfer in front of a Cu(111) surface
abstract: Electron capture by Li+ and H projectiles in grazing scattering from Cu(111) and Cu(110) surfaces is studied experimentally and theoretically. Whereas data for Cu(110) can be described by established theoretical methods treating resonant charge transfer with a free-electron metal, data for Cu(111) show pronounced deviations from this approach. We interpret our observations by the effect of the projected L-band gap of the Cu(111) surface. In particular, the quantum states of reduced dimension (2D surface state continuum) play a dominant role in electron transfer.
authors.affiliation: Institut fur Physik, Humboldt-Universitat zu Berlin, Invalidenstrasse 110, D-10115 Berlin, Germany.
authors.initials: T
authors.lastname: Hecht
authors.initials: H
authors.lastname: Winter
authors.initials: AG
authors.lastname: Borisov
authors.initials: JP
authors.lastname: Gauyacq
authors.initials: AK
authors.lastname: Kazansky