Diffusion-mediated reactions with a time-dependent absorption rate
Diffusion-mediated reactions models are particularly useful for the characterization of physical, chemical, and biological problems. In this paper we present a theoretical study of the absorption probability density, survival probability, and reaction rate for diffusion-mediated reactions models with a time-dependent finite absorption rate (an extension of a model usually referred to as the "imperfect trap model"). The results are obtained by means of the formalism of continuous time random walk on a lattice and considering a general reaction dynamics upon encounter of the reactives. First jump probability densities are included to take initial conditions into account. Previous results presented by Collins and Kimball [J. Colloid. Sci. 4, 425 (1949)] and Noyes [J. Chem. Phys. 22, 1349 (1954)] are reobtained for the particular case of a time-independent absorptivity. Short and long time behaviors are analyzed resulting, in particular, in that the long time behavior of the absorption probability density exhibits the same time dependence as the first passage time density. The results obtained are illustrated by considering a one-dimensional model with consequent discussion.
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MA
Facultad de Matematica, Astronomia y Fisica, Universidad Nacional de Cordoba, Ciudad Universitaria, 5010 Cordoba, Argentina.
Budde
CE