title: Effect of optical purity on the critical heat capacity at the smectic-A-(chiral)-smectic-C transition in an antiferroelectric liquid crystal
abstract: High resolution ac calorimetric measurements have been carried out near the smectic-A-chiral-smectic-C phase transition in the antiferroelectric liquid crystal 4-(1-methylheptyloxycarbonyl)phenyl 4(')-octyloxybiphenyl-4-carboxylate (MHPOBC). Data on samples with different optical purities have been analyzed in detail using a renormalization-group expression with corrections-to-scaling terms. The chiral-smectic-C(alpha)-chiral-smectic-C phase transition is first order, while the smectic-A-chiral-smectic-C(alpha) phase transition is second order. A direct smectic-A-chiral-smectic-C phase transition, which occurs in near-racemic mixtures, was found to be quasitricritical and weakly first order. This implies that the smectic-A-smectic-C transition in the racemate locates at a special point where four critical lines intersect.
authors.affiliation: Department of Physics, Faculty of Science, Tokyo Institute of Technology, 2-12-1 Oh-okayama, Meguro, Tokyo 152-8551, Japan.
authors.initials: K
authors.lastname: Ema
authors.initials: M
authors.lastname: Kanai
authors.initials: H
authors.lastname: Yao
authors.initials: Y
authors.lastname: Takanishi
authors.initials: H
authors.lastname: Takezoe