Dynamics of critical fluctuations in a binary mixture of limited miscibility under a strong electric field
Experimental investigations of relaxation after switching off the strong electric field in a nitrobenzene-dodecane mixture are presented. Studies were conducted for mixtures of critical and noncritical concentrations using the time-resolved nonlinear dielectric effect. The decays obtained can be portrayed by means of the stretched exponential function with the value of the exponent in agreement with the dynamic droplet model predictions. It has been shown that experimental decays exhibit a universal scaling behavior. The relaxation time (scaling factor) shows a power behavior with the exponent y approximately 1.2 for the critical mixture and y-->1 for the noncritical one. These values are much smaller than theoretically predicted y=1.8-1.9. Based on the assumption that a strong electric field induces in the mixture a quasinematic structure with semiclassical critical properties, a quantitative explanation of this difference is proposed.
Rzoska
SJ
Institute of Physics, Silesian University, ulica Uniwersytecka 4, 40-007 Katowice, Poland.
Drozd-Rzoska
A
Ziolo
J