Atomic transport and chemical stability during annealing of ultrathin Al2O3 films on Si.
Ultrathin films of Al2O3 deposited on Si were submitted to rapid thermal annealing in vacuum or in oxygen atmosphere, in the temperature range from 600 to 800 degrees C. Nuclear reaction profiling with subnanometric depth resolution evidenced mobility of O, Al, and Si species, and angle-resolved x-ray photoelectron spectroscopy revealed the formation of Si-Al-O compounds in near-surface regions, under oxidizing atmosphere at and above 700 degrees C. Under vacuum annealing all species remained essentially immobile. A model is presented based on diffusion-reaction equations capable of explaining the mobilities and reproducing the obtained profiles.
Krug
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Instituto de Física, UFRGS, Av. Bento Gonçalves, 9500, Porto Alegre, RS, Brazil.
da Rosa
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de Almeida
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Morais
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Baumvol
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Salgado
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Stedile
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