title: Ultra-small-angle neutron scattering studies on phase separation of poly(vinyl alcohol) gels
abstract: Time-resolved light scattering measurements during the gelation process of a poly(vinyl alcohol) (PVA) solution in a mixture of dimethyl sulfoxide and water (H2O) have shown that a spinodal decomposition (SD) type phase separation takes place in the early stage of gelation. In this case the kinetics of SD is valid only before macroscopic gelation occurs because the growth rate is slowed down by gelation. Such SD type phase separation makes the solution opaque as it proceeds, and hence the structural change can no longer be followed by light scattering. To investigate the structure of the opaque PVA gel as well, we have employed an ultra-small-angle neutron scattering technique using a Bonse-Hart camera. These observations reveal that even after the macroscopic gelation the structure due to the microphase separation on a spatial scale of several &mgr;m continues to grow against the elasticity. This may be because at first the gel structure is too soft to suppress the growth of the microphase separation, but within 24 h after the quenching the growth terminates. On the basis of the results, we will discuss a possible mechanism of the microphase separation after gelation.
authors.affiliation: Institute for Chemical Research, Kyoto University, Uji, Kyoto-fu 611-0011, Japan.
authors.initials: H
authors.lastname: Takeshita
authors.initials: T
authors.lastname: Kanaya
authors.initials: K
authors.lastname: Nishida
authors.initials: K
authors.lastname: Kaji
authors.initials: T
authors.lastname: Takahashi
authors.initials: M
authors.lastname: Hashimoto