title: Orbital liquid in three-dimensional mott insulator: LaTiO3
abstract: We present a theory of spin and orbital states in Mott insulator LaTiO3. The spin-orbital superexchange interaction between d(1)(t(2g)) ions in cubic crystal suffers from a pathological degeneracy of orbital states at the classical level. Quantum effects remove this degeneracy and result in the formation of the coherent ground state, in which the orbital moment of t(2g) level is fully quenched. We find a finite gap for orbital excitations. Such a disordered state of local degrees of freedom on unfrustrated, simple cubic lattice is highly unusual. Orbital liquid state naturally explains observed anomalies of LaTiO3.
authors.affiliation: Max-Planck-Institut fur Festkorperforschung, Heisenbergstrasse 1, D-70569 Stuttgart, Germany and Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan.
authors.initials: G
authors.lastname: Khaliullin
authors.initials: S
authors.lastname: Maekawa