Complexation of sucrose with cobalt(III)bis(phenanthroline).
The delta-[Co(III)bis(phenanthroline)(sucrose)]3+ complex forms with little perturbation of the sucrose conformation, and complexation by HO-2(g) and HO-1(f).
Parada
J
J
Departamento de Quimica Inorganica y Analitica, Facultad de Ciencias Quimicas y Farmaceuticas, Universidad de Chile, Santiago.
Bunel
S
S
Ibarra
C
C
Larrazabal
G
G
Moraga
E
E
Gillitt
N D
ND
Bunton
C A
CA
D002236:Carbohydrate Conformation; D002942:Circular Dichroism; D003035:Cobalt / Q000737:chemistry* / Q000378:metabolism; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry* / Q000378:metabolism; D010618:Phenanthrolines / Q000737:chemistry* / Q000378:metabolism; D013395:Sucrose / Q000737:chemistry* / Q000378:metabolism; D014867:Water
D008024:Ligands; D009942:Organometallic Compounds; D010618:Phenanthrolines; C421919:delta-bis(phenanthroline)(sucrose)cobalt(III); D014867:Water; D003035:Cobalt; D013395:Sucrose