Structural stability of simple fluids and accuracy of integral-equation theories
The ability to describe the structural stability of a fluid may represent a stringent test for the overall physical soundness of an integral-equation theory. The accuracy of some approximate closures of the Ornstein-Zernike equation is discussed in relation to the estimates of the density threshold of structural stability of the fluid that are obtained through an analysis of the iterative form of the integral equation. The connection with the random-close-packing threshold of hard spheres is also investigated.
Malescio
G
Dipartimento di Fisica, Istituto Nazionale per la Fisica della Materia and Universita degli Studi di Messina, Contrada Papardo, 98166 Messina, Italy.
Giaquinta
PV