Terephthalaldehyde bis(thiosemicarbazone) bis(dimethylformamide) solvate.
The thiosemicarbazone molecule in C(10)H(12)N(6)S(2).2C(3)H(7)NO has -1 symmetry. The thiosemicarbazone moiety and the benzene ring are essentially coplanar, with mean and maximum deviations of 0.03 and 0. 11 A, respectively. The dimethylformamide molecules bridge the thiosemicarbazone moieties, forming two-dimensional sheets through N-H.O hydrogen bonds.
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Coordination Chemistry Institute & State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China.
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