title: Interfacial strength of compression-molded specimens between PMMA powder and PMMA/MMA monomer solution-treated ultra-high molecular weight polyethylene (UHMWPE) powder.
abstract: The interface between bone cement and ultra-high molecular weight polyethylene (UHMWPE) has been considered a weak link of cemented UHMWPE acetabular cup in total hip replacement (THR). For the improvement of this weak interface, adhesion between the UHMWPE acetabular cup and bone cement made of polymethylmethacrylate (PMMA) has been investigated in our laboratory. Virgin UHMWPE powders were treated with methyl methacrylate (MMA) monomer and PMMA/MMA solution. The treated UHMWPE powders were then compression-molded with virgin UHMWPE powders or PMMA powders, creating two different interfaces, i. e., treated/virgin UHMWPE powder and treated UHMWPE/PMMA powder. For the present study, the interfacial strengths between PMMA powder and the treated UHMWPE power were investigated following the same protocol previously set. The maximum interfacial strength was 17.0 +/- 0.25MPa with the same molding condition of 166.5 degrees C, 38.7 MPa and l h. In addition to the molding condition, we tested the strengths for the treated UHMWPE powders, which have different ratios between PMMA/MMA solution and MMA-treated UHMWPE powders. Significant differences on the interfacial strengths resulted due to the ratio change; more PMMA in the PMMA/MMA solution-treated UHMWPE powder exhibited higher interfacial strength. Scanning electron microscopic (SEM) pictures showed that the interface is composed of three major portions: PMMA powder, UHMWPE, and coated PMMA, indicating strong mechanical interlocking of UHMWPE and PMMA powder matrix and chemical bonding between PMMA powder and the precoated PMMA onto the UHMWPE. In addition, another interfacial strength between PMMA powder, which is equivalent to the outermost part of the cup, and bone cement was investigated. The average strength reached up to 42.4 +/- 3.6 MPa, close to the tensile strength of bone cement itself.
authors.affiliation: Department of Biomedical Engineering, University of Iowa, Iowa City, Iowa 52242-1527, USA.
authors.forename: K D
authors.initials: KD
authors.lastname: Park
authors.forename: J B
authors.initials: JB
authors.lastname: Park
mesh_terms: D001843:Bone Cements; D006622:Hip Prosthesis; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning; D008970:Molecular Weight; D011095:Polyethylenes; D019904:Polymethyl Methacrylate; D011208:Powders; D011312:Pressure; D012996:Solutions; D013314:Stress, Mechanical; D013696:Temperature; D013718:Tensile Strength; D013997:Time Factors
chemical_list: D001843:Bone Cements; D011095:Polyethylenes; D011208:Powders; D012996:Solutions; C111601:ultra-high molecular weight polyethylene; D019904:Polymethyl Methacrylate