Gold electrodes from recordable CDs
Gold electrodes are widely used in electrochemistry and electroanalytical chemistry. The notable performance when used in stripping analysis of many ionic species and the extraordinary affinity of thio compounds for its surface make these electrodes very suitable for many applications. This paper reports a simple and novel way to construct gold electrodes (CDtrodes) using recordable CDs as the gold source. The nanometer thickness of the gold layer of recordable disks (50-100 nm) favors the construction of band nanoelectrodes with areas as small as 10(-6) cm2. The plane surface can be easily used for the construction of conventional-sized gold electrodes for batch or flow injection analysis or even to obtain electrodes as large as 100 cm2. The low price of commercial recordable CDs allows a "one way use". The evaluation and applicability of these electrodes in the form of nanoelectrodes, in batch and associated with flow cells, are illustrated in this paper.
Angnes
L
Departmento de Quimica Fundamental, Universidade de Sao Paulo, Brazil. luangnes@iq.usp.br
Richter
EM
Augelli
MA
Kume
GH