Stabilizing grafted colloids in a polymer melt: favorable enthalpic interactions
The interactions between spherical colloids covered with end-grafted polymers (brushes) immersed in a polymer melt are studied theoretically. We show that attractive enthalpic interactions between the two polymer species, characterized by a negative Flory parameter (chi<0), can stabilize the colloidal dispersion. The stabilizing mechanism is a result of a structural change from a dry brush, where the melt chains do not penetrate deeply into the brush, to a wet brush, where the free chains penetrate the brush and force the grafted chains to extend into the melt.
Borukhov
I
Unite Mixte de Recherche CNRS/Elf Atochem (UMR 167), 95 rue Danton, B.P. 108, 92303 Levallois-Perret Cedex, France.
Leibler
L