title: Long-range density fluctuations in orthoterphenyl as studied by means of ultrasmall-angle x-ray scattering.
abstract: The structure factor of a fragile glass-forming liquid orthoterphenyl was measured in the previously inaccessible intermediate q range between the conventional light scattering (LS) and small-angle x-ray scattering (SAXS) q ranges using the low-angle scattering beam line at the European Synchrotron Radiation Facility. At low q the structure factor exhibits an excess scattering and matches well the LS data. This excess scattering is due to long-range density fluctuations also observed in the isotropic component of scattered light. At high q the structure factor decays to a plateau corresponding to the isothermal compressibility in agreement with the conventional SAXS data. In the intermediate q range, the structure factor exhibits a power law q dependence which indicates that the excess scattering is due to fractal aggregates of denser domains.
authors.affiliation: Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
authors.forename: A
authors.initials: A
authors.lastname: Patkowski
authors.forename: T
authors.initials: T
authors.lastname: Thurn-Albrecht
authors.forename: E
authors.initials: E
authors.lastname: Banachowicz
authors.forename: W
authors.initials: W
authors.lastname: Steffen
authors.forename: P
authors.initials: P
authors.lastname: Bösecke
authors.forename: T
authors.initials: T
authors.lastname: Narayanan
authors.forename: E W
authors.initials: EW
authors.lastname: Fischer