Infrared intensity of 1-monolaurin-water systems in the gel phase.
The infrared spectra of 1-monolaurin-water systems, where KSCN is added as the intensity standard, were observed and the infrared intensity of the bands due to acyl groups measured relatively to that of the CN stretching. The infrared intensities of the bands parallel and perpendicular to the paraffin chains decrease and increase, respectively, on going from the crystalline 1 phase to the gel phase, confirming that these intensity changes result from the long-range interaction among oscillating dipoles. The infrared spectra with no CH2 rocking and the splitting of the CH2 rocking are also discussed with the same interaction model.
Kanesaka
I
I
Faculty of Science, Toyama University, Gofuku, Japan. kanesaka@sci.toyama-u.ac.jp
Ishizaka
M
M
Shimizu
K
K
D005782:Gels; D005989:Glycerides / Q000737:chemistry*; D007848:Laurates / Q000737:chemistry*; D050178:Monoglycerides; D013055:Spectrophotometry, Infrared; D013501:Surface-Active Agents / Q000737:chemistry; D013861:Thiocyanates / Q000737:chemistry; D014867:Water
D005782:Gels; D005989:Glycerides; D007848:Laurates; D050178:Monoglycerides; D013501:Surface-Active Agents; D013861:Thiocyanates; D014867:Water; C020777:monolaurin; C009941:potassium thiocyanate