Triazidocobalt(III) complexes with tridentate amine ligands.
The title compounds, [N-(2-aminoethyl)-1, 3-propanediamine-kappa(3)N]triazidocobalt(III), [Co(N(3))(3)(C(5)H(15)N(3))], [N-(2-aminoethyl)-N-methyl-1, 3-propanediamine-kappa(3)N]triazidocobalt(III), [Co(N(3))(3)(C(6)H(17)N(3))], [N-(2-aminopropyl)-1, 3-propanediamine-kappa(3)N]triazidocobalt(III), [Co(N(3))(3)(C(6)H(17)N(3))], and [N-(2-aminopropyl)-N-methyl-1, 3-propanediamine-kappa(3)N]triazidocobalt(III), [Co(N(3))(3)(C(7)H(19)N(3))], each consist of a Co(III) atom, three azide ligands in a meridional configuration and a tridentate amine ligand, namely aepn [N-(2-aminoethyl)-1,3-propanediamine] or dpt [N-(3-aminopropyl)-1,3-propanediamine], or their N-methylated analogs.
Chun
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Department of Chemistry, University of Houston, Houston, TX 77204-5641, USA.
Bernal
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