Influence of Calcination Procedure on Porosity and Surface Fractal Dimensions of Silica Xerogels Prepared under Different Evaporation Conditions.
Silica xerogels were prepared under three different solvent evaporation conditions before gelation and two calcination procedures after aging and drying, using a hydrochloric acid-catalyzed tetraethyl orthosilicate system with acetone as the solvent. The influence of calcination procedures on the percentage porosity and surface fractal dimensions of the resultant xerogels is investigated. The evaluation of percentage porosity and surface fractal dimensions based on field emission gun-scanning electron microscopy indicates that calcination generally causes an increase in percentage porosity and surface fractal dimensions. Calcination at 700 degrees C without an intermediate stay at 600 degrees C leads to larger extent of further condensation that hinders the increase of porosity and surface fractal dimensions, in comparison with calcination with an intermediate stay. The difference in porosity and surface fractal dimensions derived from calcination procedures is also influenced by the solvent evaporation conditions before gelation in preparation of the samples. When the solvent evaporation rate is slower, the difference is slight because further condensation in the resultant finer gel textures proceeds more efficiently. Copyright 2000 Academic Press.
Huang
WL
Department of Materials Science and Engineering, Tsinghua University, Beijing, 100084, People's Republic of China
Liang
KM
Cui
SH
Gu
SR