title: Effects of soil type upon metolachlor losses in subsurface drainage.
abstract: A field experiment at La Bouzule (Lorraine, France) investigated metolachlor movement to subsurface drains in two soil types, a silt loam and a heavy clay soil, under identical agricultural management practices and climatic conditions. Drainage volumes and concentrations of metolachlor in the soil plough layer and drainwater were monitored after herbicide application from May 1996 to February 1997, and from May to August 1998. Total losses in drainwater were 0.08% and 0.18% of the amount applied to the silt loam compared with 0.59% and 0.41% for the clay soil, in 1996/97 and 1998, respectively. In 1996/97, 32% of total metolachlor loss from the silt loam and 91% from the clay soil occurred during the spring/summer period following treatment. Peak concentrations were 18.5 and 171.6 microg l(-1) for the silt loam and 130.6 and 395.3 microg l(-1) for the clay soil during the spring/summer periods of 1996/97 and 1998, respectively. During the autumn/winter period, concentrations did not exceed 2.2 microg l(-1) for the silt loam and 2.6 microg l(-1) for the clay soil. The experimental results indicate that metolachlor losses in drainwater were primarily caused by preferential flow (macropore flow) which was greater in the clay soil than in the silt loam, and occurring mainly during the spring/summer periods.
authors: Centre de Pédologie Biologique, UPR 6831 du CNRS associée à l' Université Henri Poincaré, Vandoeuvre-lès-Nancy, France.
authors: S M
authors: SM
authors: Novak
authors: J M
authors: JM
authors: Portal
authors: M
authors: M
authors: Schiavon
mesh_terms: D000081:Acetamides / Q000032:analysis / Q000378:metabolism*; D000327:Adsorption; D000383:Agriculture; D001711:Biotransformation; D002980:Climate; D006540:Herbicides / Q000032:analysis / Q000378:metabolism*; D011891:Rain; D012989:Soil Pollutants / Q000032:analysis / Q000378:metabolism*
chemical_list: D000081:Acetamides; D006540:Herbicides; D012989:Soil Pollutants; C051786:metolachlor