Rearrangement of sugar 1,2-orthoesters to glycosidic products: a mechanistic implication.
The identification of cross-over products in the rearrangement of two structurally similar sugar 1,2-orthoesters to glycosidic products is reported.
Yang
Z
Z
State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, PR China.
Lin
W
W
Yu
B
B
D002851:Chromatography, High Pressure Liquid; D004187:Disaccharides / Q000737:chemistry*; D004952:Esters / Q000737:chemistry*; D006031:Glycosylation; D015394:Molecular Structure; D013402:Sugar Alcohols / Q000737:chemistry*
D004187:Disaccharides; D004952:Esters; D013402:Sugar Alcohols