title: cis,cis,cis-tetramethyl 1,2,4,5-cyclohexanetetracarboxylate
abstract: The title compound, C(14)H(20)O(8), was synthesized from the hydrogenation of tetramethyl 1,4-cyclohexadiene-1,2,4, 5-tetracarboxylate with a catalytic amount of palladium/carbon. All four carbonyl moieties of the methyl ester groups are on the same face of the chair-conformed ring. The substantial ring distortion associated with the 1,3-diaxial methoxycarbonyl substituents is reflected in the large difference between bond angles as well as torsion angles, respectively, that in undistorted cyclohexanes would be approximately the same.
authors: Department of Geology, Southern Illinois University-4324, Carbondale, IL 62901, USA. robinson@geo.siu.edu.
authors: PD
authors: Robinson
authors: DH
authors: Hua
authors: J
authors: Fan
authors: L
authors: Liu
authors: JW
authors: McGill
authors: M
authors: Arshid
authors: CY
authors: Meyers