Novel acetylated triterpenoid saponins in a chromatographic fraction from Quillaja saponaria Molina.
Six novel fucose 3-O-acetylated saponins, with a quillaic acid aglycone, were isolated from a bark extract from the Quillaja saponaria Molina tree. In addition, a saponin with a novel aglycone (phytolaccagenic acid) and a novel fatty acyl group [(S)-2-methylbutanoyl] for Quillaja saponins was found. The compounds were characterised using NMR spectroscopy, mass spectrometry and chemical methods.
Nord
L I
LI
Department of Chemistry, Swedish University of Agricultural Sciences, Uppsala.
Kenne
L
L
D000107:Acetylation; D002240:Carbohydrate Sequence; D002851:Chromatography, High Pressure Liquid; D005643:Fucose / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008969:Molecular Sequence Data; D015394:Molecular Structure; D009828:Oleanolic Acid / Q000031:analogs & derivatives*; D019685:Rosales / Q000737:chemistry*; D012503:Saponins / Q000737:chemistry* / Q000302:isolation & purification*; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; D013729:Terpenes / Q000737:chemistry
D012503:Saponins; D013729:Terpenes; D005643:Fucose; C421633:phytolaccagenic acid; D009828:Oleanolic Acid