Palladium-catalyzed additions of silyl-element bonds to bicyclopropylidene-A new access to bicyclopropyl and functionally substituted cyclopropylidenepropane derivatives
Palladium-catalyzed additions of disilanes, silylboranes, silylstannanes, and silyl cyanides across the double bond of bicyclopropylidene proceed with remarkable ease by two modes yielding either bicyclopropyl or cyclopropylidenepropane derivatives.
Pohlmann
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Institut fur Organische Chemie der Georg-August-Universitat Gottingen, Tammannstrasse 2, D-37077 Gottingen, Germany.
de Meijere A