title: Separation of bisphenol A and three alkylphenols by micellar electrokinetic chromatography.
abstract: Analytical conditions of pH, surfactants, and additives were investigated for the simultaneous separation of bisphenol A and alkylphenols by micellar electrokinetic chromatography. Reproducibility of migration time was improved at higher pH (pH 8.0). When five surfactants having linear alkyl chains or four bile salts were used, the separation of hydrophobic phenols and 4-nonylphenol isomers was not achieved. In order to improve the separation, the use of additives with sodium dodecyl sulfate solution was investigated. The separation of hydrophobic phenols was improved by the addition of organic solvents, however, isomers were not separated. Their separation was achieved by the addition of beta- or gamma-cyclodextrin.
authors: Department of Energy and the Environment, Osaka National Research Institute, AIST, MITI, Ikeda, Japan.
authors: S
authors: S
authors: Takeda
authors: S
authors: S
authors: Iida
authors: K
authors: K
authors: Chayama
authors: H
authors: H
authors: Tsuji
authors: K
authors: K
authors: Fukushi
authors: S
authors: S
authors: Wakida
mesh_terms: D001559:Benzhydryl Compounds; D020374:Chromatography, Micellar Electrokinetic Capillary / Q000379:methods*; D006863:Hydrogen-Ion Concentration; D010636:Phenols / Q000302:isolation & purification*; D015203:Reproducibility of Results; D013501:Surface-Active Agents; D000098826:Bisphenol A Compounds
chemical_list: D001559:Benzhydryl Compounds; D010636:Phenols; D013501:Surface-Active Agents; C006780:bisphenol A; D000098826:Bisphenol A Compounds