Preparation, chemical and crystal structures of N-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosyl)pyridinium chloride.
Preparation and isolation of N-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosyl)pyridinium chloride are described. Its structure was determined by 1H NMR spectroscopy and X-ray analysis. X-ray crystallography revealed that the salt crystallizes with one molecule of water. Ab initio calculations were used to determine charges on atoms in the cation of the title compound.
Dmochowska
B
B
Department of Chemistry, University of Gdańsk, Poland.
Bednarczyk
D
D
Nowacki
A
A
Konitz
A
A
Wojnowski
W
W
Wiśniewski
A
A
D018360:Crystallography, X-Ray; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009005:Monosaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D011726:Pyridinium Compounds / Q000138:chemical synthesis* / Q000737:chemistry*
D006027:Glycosides; D009005:Monosaccharides; C421206:N-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-glucopyranosyl)pyridinium chloride; D011726:Pyridinium Compounds