[E-Z ratio and stability of halogenated benzylidene derivatives  formed during the detection of glycine conjugates].
The orange fluorescing spot formed during the detection of halogenated hippuric acids with 4-N,N-Dimethylaminobenzaldehyde on TLC-plates consists of a E/Z-mixture of the corresponding benzyliden derivatives. Intermediates are the azlactones.
Oelschläger
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Institut für Pharmazie der Friedrich-Schiller-Universität, Jena, Germany.
Seeling
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A
Radman
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Bockhard
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H
D001547:Benzaldehydes / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid; D002855:Chromatography, Thin Layer; D005456:Fluorescent Dyes / Q000737:chemistry*; D005998:Glycine / Q000032:analysis / Q000737:chemistry*; D006626:Hippurates / Q000032:analysis / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013056:Spectrophotometry, Ultraviolet
D001547:Benzaldehydes; D005456:Fluorescent Dyes; D006626:Hippurates; D005998:Glycine; C510241:p-dimethylaminobenzaldehyde