title: Filler particle leachability of experimental dental composites.
abstract: We studied the effect of matrix selection, filler composition, and filler silanization on filler leachability after storage in distilled water or artificial saliva. We evaluated 2 matrix systems, 2 filler systems and 2 silane treatment procedures, combined into 8 different dental composite materials. A total of 128 batches were made, and 2 specimens per batch were prepared. Of these 2 specimens per batch, one was stored in distilled water and the other in artificial saliva, both at 37 degrees C. We transferred the specimens each 30th day during a 3-yr period to new vials containing either freshly distilled water or newly mixed artificial saliva and analyzed the solutions the specimens had been stored in regarding Si, Ba and Al concentrations. The analyses revealed that storage solution, filler composition, and total time in the storage solution had strong effects on leachability. The average monthly leakage of the three elements was linear with time and higher in the artificial saliva. The Ba-containing filler leached Si faster in artificial saliva than in distilled water, and roughly twice as much as the quartz filler. The storage effect approached an order of magnitude, while the filler effect was roughly a factor of two. Filler leaching was linear over time.
authors.affiliation: Department of Dental Biomaterials, University of Florida, Gainesville 32610-0446, USA. ksoderholm@dental.ufl.edu
authors.forename: K J
authors.initials: KJ
authors.lastname: Söderholm
authors.forename: M C
authors.initials: MC
authors.lastname: Yang
authors.forename: I
authors.initials: I
authors.lastname: Garcea
mesh_terms: D000465:Algorithms; D000535:Aluminum / Q000032:analysis; D000537:Aluminum Oxide / Q000032:analysis / Q000737:chemistry; D001464:Barium / Q000032:analysis; D017609:Barium Compounds / Q000032:analysis / Q000737:chemistry; D017438:Bisphenol A-Glycidyl Methacrylate / Q000032:analysis / Q000737:chemistry; D003188:Composite Resins / Q000032:analysis / Q000737:chemistry*; D003764:Dental Materials / Q000032:analysis / Q000737:chemistry*; D004058:Diffusion; D006801:Humans; D008422:Materials Testing; D008689:Methacrylates / Q000032:analysis / Q000737:chemistry; D010087:Oxides / Q000032:analysis / Q000737:chemistry; D011092:Polyethylene Glycols / Q000032:analysis / Q000737:chemistry; D011109:Polymethacrylic Acids / Q000032:analysis / Q000737:chemistry; D011140:Polyurethanes / Q000032:analysis / Q000737:chemistry; D011791:Quartz / Q000032:analysis / Q000737:chemistry; D012464:Saliva, Artificial / Q000737:chemistry; D012821:Silanes / Q000032:analysis / Q000737:chemistry; D012825:Silicon / Q000032:analysis; D012822:Silicon Dioxide / Q000032:analysis / Q000737:chemistry; D013696:Temperature; D013997:Time Factors; D014867:Water / Q000737:chemistry; D014961:X-Ray Diffraction
chemical_list: D017609:Barium Compounds; D003188:Composite Resins; D003764:Dental Materials; D008689:Methacrylates; D010087:Oxides; D011109:Polymethacrylic Acids; D011140:Polyurethanes; D012464:Saliva, Artificial; D012821:Silanes; D014867:Water; C029824:urethane dimethacrylate luting resin; D011791:Quartz; C020946:triethylene glycol dimethacrylate; D001464:Barium; D011092:Polyethylene Glycols; D017438:Bisphenol A-Glycidyl Methacrylate; D012822:Silicon Dioxide; C077606:barium oxide; D000535:Aluminum; D000537:Aluminum Oxide; D012825:Silicon