title: M and P double helical complexes of copper(I) with bis-imino bis-quinoline enantiomerically pure chiral ligands.
abstract: The enantiomerically pure bis-imino bis-quinoline ligands R,R-ImQ and S,S-ImQ have been prepared by Schiff condensation of 2-quinoline carboxyaldehyde with the pure R,R and S,S enantiomers of trans-1,2-diaminocyclohexane. Both ligands form 2:2 helical complexes with CuI perchlorate, and the crystal and molecular structure of [Cu2(R,R-ImQ)2]ClO4.H2O have been determined by X-ray diffraction methods: the [Cu2(R,R-ImQ)2]2+ molecular cation is a chiral double helix of M handedness, in which the two ligands are entertwined in such an arrangement that half of each ligand is not equivalent to the other half of the same ligand. Coupled circular dichroism and 1H NMR studies reveal that in CH3CN solution a rearrangement takes place toward a more symmetric helical structure (in which the two halves of the same ligand become equivalent), which maintains the same handedness found in the solid state and is a pure M isomer. Solid state and CH3CN solution CD experiments confirm that [Cu2(S,S-ImQ)2]ClO4.H2O, both in solution and in the solid state, is a pure double helix of P handedness, i.e., the enantiomer of the species containing the R,R ligand.
authors.affiliation: Dipartimento di Chimica Generale, Università di Pavia, via Taramelli 12, I-27100 Pavia, Italy.
authors.forename: V
authors.initials: V
authors.lastname: Amendola
authors.forename: L
authors.initials: L
authors.lastname: Fabbrizzi
authors.forename: C
authors.initials: C
authors.lastname: Mangano
authors.forename: P
authors.initials: P
authors.lastname: Pallavicini
authors.forename: E
authors.initials: E
authors.lastname: Roboli
authors.forename: M
authors.initials: M
authors.lastname: Zema