Stereocontrolled Synthesis of Optically Active beta-D-glucopyranosides of 3-Hydroxy-7,8-didehydro-beta-ionol.
A stereocontrolled synthesis of optically active beta-D-glucopyranosides 1-4 of 3-hydroxy-7,8-didehydro-beta-ionol utilizing an asymmetric transfer hydrogenation to alpha,beta-acetylenic ketones catalyzed by chiral ruthenium complexes as the key step is described.
Yamano
Y
Y
Kobe Pharmaceutical University, Kobe, Japan.
Watanabe
Y
Y
Watanabe
N
N
Ito
M
M
D000480:Alkynes / Q000737:chemistry*; D005960:Glucosides / Q000138:chemical synthesis* / Q000737:chemistry; D006865:Hydrogenation; D008968:Molecular Conformation; D009904:Optical Rotation; D017975:Ruthenium Compounds / Q000737:chemistry
D000480:Alkynes; D005960:Glucosides; D017975:Ruthenium Compounds