Isotopic Study of Rotational Spectra of the Ar-Acetylene Complex.
Rotational spectra of the weakly bound complex Ar-acetylene were measured using a Fourier transform microwave spectrometer. Eight additional transitions of the normal isotopomer were detected, following the earlier radiofrequency and microwave investigations [R. L. DeLeon and J. S. Muenter, J. Chem. Phys. 72, 6020-6023 (1980); Y. Ohshima, M. Iida, and Y. Endo, Chem. Phys. Lett. 161, 202-206 (1989)]. Spectra of four minor isotopomers, namely Ar-DCCD, Ar-H(13)C(13)CH, Ar-DCCH, and Ar-H(13)C(12)CH, were newly assigned and analyzed. A semirigid rotor model was employed to obtain the rotational and centrifugal distortion constants, which were in turn used to extract structural information about the complex. The unusually large standard deviations of the spectroscopic fits are indicators of large-amplitude internal motions of the acetylene subunit. Separate fits of the individual K-stacks yielded lower standard deviations, and their results were used to interpret some of the unusual spectroscopic observations. Copyright 2001 Academic Press.
Liu
Y
Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2, Canada
Jäger
W