title: Determination of porphyrin carbon isotopic composition using gas chromatography-isotope ratio monitoring mass spectrometry.
abstract: Carbon isotopic compositions of aetio I occurring in the form of free-base, nickel, demetallation, dihydroxysilicon(IV) and bis(tert.-butyldimethylsiloxy)silicon(IV) [(tBDMSO)2Si(IV)] have shown that it has experienced no obvious isotope fractionation during the synthesis of [(tBDMSO)2Si(IV)] porphyrin from aetio I. Here, aetio I porphyrin species such as free-base, nickel, demetallated and dihydroxysilicon were analyzed by the conventional method, namely it is combusted in sealed system, and followed by isotope ratio monitoring mass spectrometric analysis. [(tBDMSO)2Si(IV)] aetio I was assayed by gas chromatography-isotope ratio monitoring mass spectrometry (GC-IRMS). A porphyrin mixture of [(tBDMSO)2Si(IV)] aetio I and octaethylporphyrin was also prepared. Their carbon isotopic compositions measured by GC-IRMS indicate that no isotope exchange took place between the porphyrins during the synthesis of [(tBDMSO)2Si(IV)] porphyrins. This method is employed for delta13C determination of geoporphyrins from the Maoming and Jianghan oil shales.
authors.affiliation: Guangzhou Institute of Geochemistry, Chinese Academy of Sciences.
authors.forename: Z
authors.initials: Z
authors.lastname: Yu
authors.forename: G
authors.initials: G
authors.lastname: Sheng
authors.forename: J
authors.initials: J
authors.lastname: Fu
authors.forename: P
authors.initials: P
authors.lastname: Peng
mesh_terms: D002247:Carbon Isotopes / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D011166:Porphyrins / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
chemical_list: D002247:Carbon Isotopes; D011166:Porphyrins