Spectroscopic study of low temperature interactions in metal-organic co-condensates.
The results on spectroscopic study of low temperature interactions of metal atoms, small clusters and nanoparticles with different organic and inorganic substances in the temperature range 12-300 K are presented. Complexation and reactions of atoms and clusters of magnesium, samarium and silver with carbon dioxide, ethylene and some mesogenic cyanophenyls were studied by the technique of matrix isolation and low temperature co-condensation of metal and ligand vapors, low temperature UV-Vis, IR- and ESR-spectroscopy in combination with quantum chemistry calculations. It was shown that cryochemical reactions of metal particles of different sizes reflected the system's redundant energy.
Sergeev
G B
GB
Department of Chemistry, Moscow State University, Russia. gbs@kinet.chem.msu.ru
Shabatina
T I
TI
Solov'ev
V N
VN
Nemukhin
A V
AV
D002245:Carbon Dioxide / Q000737:chemistry*; D005030:Ethylenes / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry*; D008670:Metals / Q000737:chemistry; D012493:Samarium / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization / Q000379:methods; D013055:Spectrophotometry, Infrared / Q000379:methods; D013056:Spectrophotometry, Ultraviolet / Q000379:methods
D005030:Ethylenes; D008670:Metals; D002245:Carbon Dioxide; D012834:Silver; D012493:Samarium; C036216:ethylene; D008274:Magnesium