Hydrogen bonds in the framework of bis(2-[bis(2-aminoethyl)amino]ethanol)nickel(II) diperchlorate.
The title molecule, [Ni(C6H17N3O)2](ClO4)2, possesses a crystallographic centre of symmetry at the Ni(II) position. The coordination geometry around the Ni(II) atom is distorted octahedral, consisting of six N atoms from two tripodal polyamine ligands, while the ethanol O atoms of the ligands remain uncoordinated. The crystal packing shows two-dimensional layers and an infinite three-dimensional framework which is stabilized by a hydrogen-bonded network.
Xia
J
J
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China.
Sun
W Y
WY
Xu
Y
Y
Yu
K B
KB
Tang
W X
WX
D004247:DNA / Q000737:chemistry; D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010472:Perchlorates / Q000737:chemistry*; D015032:Zinc
D009942:Organometallic Compounds; D010472:Perchlorates; C425403:bis(2-aminoethyl)aminoethanol nickel(II) diperchlorate; D004247:DNA; D015032:Zinc