Lipase-catalysed production of biodiesel fuel from some Nigerian lauric oils.
Fatty acids esters were produced from two Nigerian lauric oils, palm kernel oil and coconut oil, by transesterification of the oils with different alcohols using PS30 lipase as a catalyst. In the conversion of palm kernel oil to alkyl esters (biodiesel), ethanol gave the highest conversion of 72%, t-butanol 62%, 1-butanol 42%, n-propanol 42% and iso-propanol 24%, while only 15% methyl ester was observed with methanol. With coconut oil, 1-butanol and iso-butanol achieved 40% conversion, 1-propanol 16% and ethanol 35%, while only traces of methyl esters were observed using methanol. Studies on some fuel properties of palm kernel oil and its biodiesel showed that palm kernel oil had a viscosity of 32.40 mm2/s, a cloud point of 28 degrees C and a pour point of 22 degrees C, while its biodiesel fuel had a viscosity of 9.33 mm2/s, a cloud point of 12 degrees C and a pour point of 8 degrees C. Coconut oil had a viscosity of 28.58 mm(2)/s, a cloud point of 27 degrees C and a pour point of 20 degrees C, while its biodiesel fuel had a viscosity of 7.34 mm2/s, a cloud point of 5 degrees C and a pour point of -8 degrees C. Some of the fuel properties compared favourably with international biodiesel specifications.
Abigor
R D
RD
Eastern Regional Research Center, USDA, 600 East Mermaid Lane, Wyndmoor, PA 19038, USA. rdabigor@benin.nipost.com.ng
Uadia
P O
PO
Foglia
T A
TA
Haas
M J
MJ
Jones
K C
KC
Okpefa
E
E
Obibuzor
J U
JU
Bafor
M E
ME
D000438:Alcohols / Q000378:metabolism; D002384:Catalysis; D000074263:Coconut Oil; D004952:Esters; D005742:Gasoline; D007850:Lauric Acids / Q000378:metabolism; D008049:Lipase / Q000378:metabolism; D009549:Nigeria; D000073878:Palm Oil; D010938:Plant Oils; D013379:Substrate Specificity
D000438:Alcohols; D004952:Esters; D005742:Gasoline; D007850:Lauric Acids; D010938:Plant Oils; C030358:lauric acid; D000073878:Palm Oil; D008049:Lipase; D000074263:Coconut Oil