title: A pyridine-thiol ligand with multiple bonding sites for heavy metal precipitation.
abstract: There are immediate concerns with current commercial ligands that are used for heavy metal precipitation, especially the limited arrays of bonding sites. Previous research has indicated that not only do commercial reagents lack sufficient bonding criteria, but they also fail to provide long-term stability as ligand-metal complexes. For this reason, we have developed a pyridine-based thiol ligand (DTPY) which not only offers multiple bonding sites for heavy metals but also should form stable metal-ligand precipitates. In this study, we used the divalent metals cadmium and copper to model the reactivity and pH stability of divalent metal complexes with the DTPY ligand. Using inductively-coupled plasma spectrometry (ICP), results indicate that a 50.00ppm (parts per million) copper solution, pH of 4.5, can be reduced to below the ICP detection limits of 0.00093ppm (>99.99% removal), and a 50.00ppm cadmium solution, pH of 6.0, can be reduced to 0.06ppm (99.88%).
authors.affiliation: Department of Chemistry, The University of Kentucky, Lexington, KY 40506-0055, USA.
authors.forename: M M
authors.initials: MM
authors.lastname: Matlock
authors.forename: B S
authors.initials: BS
authors.lastname: Howerton
authors.forename: K R
authors.initials: KR
authors.lastname: Henke
authors.forename: D A
authors.initials: DA
authors.lastname: Atwood
mesh_terms: D011232:Chemical Precipitation; D004787:Environmental Pollution / Q000517:prevention & control; D006863:Hydrogen-Ion Concentration; D008024:Ligands; D019216:Metals, Heavy / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D008024:Ligands; D019216:Metals, Heavy; D011725:Pyridines; D013438:Sulfhydryl Compounds; D014874:Water Pollutants, Chemical; C023666:pyridine