3,3-Diphenyl-6-(p-toluenesulfonyl)-6-aza-3-silabicyclo[3.1.0]hexane.
The title compound, C23H23NO2SSi, at 100 K adopts a boat conformation which brings the C-H bond of an axial phenyl substituent into proximity [C...N = 3.376 (1) A] with the aziridine lone pair. The factors which favour this conformation for bicyclo[3.1.0]hexane systems are considered.
Matthews
J L
JL
Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, Scotland.
McArthur
D R
DR
Muir
K W
KW
White
D N
DN