Two iridanonaborane compounds.
Two iridanonaborane compounds, 4-carbonyl-5,6:8,9-bis-muH-4-hydrido-4-bis(trimethylphosphine)-4-irida-arachno-nonaborane(12), [IrH(B8H12)(C3H9P)2(CO)], (Ia), and 2-carbonyl-2,5:6,9:8,9-tri-muH-4-chloro-2-bis(trimethylphosphine)-2-irida-nido-nonaborane(11), [Ir(B8H10Cl)(C3H9P)2(CO)], (II), are described. Compound (II) shows evidence of effective chlorine-substituent migration during its formation.
Bould
J
J
School of Chemistry, The University of Leeds, Leeds LS2 9JT, England. bould@chem.leeds.ac.uk
Kennedy
J D
JD
Thornton-Pett
M
M
Barton
L
L
Rath
N P
NP