Core-Penetrating Rydberg Series of BaF: Single-State and Two-State Fits of New Electronic States in the 4.4 </= n* </= 14.3 Region.
We report results of optical-optical double-resonance studies of the Rydberg states of the BaF molecule in the energy region of E = 33 100-38 200 cm(-1) (4.4 </= n* </= 14.3). Barium monofluoride molecules have been produced in a resistively heated high-temperature oven from BaF(2) powder mixed with a small amount of boron powder. We have observed more than 50 new electronic states. Forty-nine of them have been rotationally analyzed and assigned to eight Rydberg series (four (2)Sigma(+), one (2)Pi, two (2)Delta, and one (2)Phi). Single-state and two-state fits have been carried out. Multiple local perturbations have been analyzed. Formation of supercomplexes in the Rydberg spectrum of BaF has been discussed. Copyright 2001 Academic Press.
Jakubek
Zygmunt J.
ZJ
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts, 02139
Field
Robert W.
RW