Correlation of characteristic thermal constant and elution temperature in GC.
In a temperature-programmed analysis, the solutes that elute at higher temperatures have generally larger characterisitic thermal constants, theta(char). The change approximately matches the temperature-related increase in a carrier gas viscosity. Accounting for the effect allows reduction in the uncertainty of prediction of theta(char) by a factor or f approximately 2 and, in a constant-pressure mode, description of a linear heating ramp by the same dimensionless rate for all solutes.
Blumberg
L M
LM
Fast GC Consulting, Hockessin, Delaware 19707, USA.
Klee
M S
MS