title: Conjugated organometallic polymers containing Vollhardt's cyclobutadiene complex: aggregation and morphologies.
abstract: Organometallic polymers were prepared by acyclic diyne metathesis (ADIMET) or by Pd-catalyzed coupling of 1,3-diethynylcyclobutadiene(cyclopentadienyl)cobalt with a suitably substituted diiodobenzene. The polymers obtained by Heck coupling show a degree of polymerization (Pn) of 20-60. The monomers for ADIMET were made by the Pd-catalyzed coupling of [1,3-bis(trimethylsilylethynyl)-2,4-bis(trimethylsilyl)cyclobutadiene](cyclopentadienyl)cobalt to 1-bromo-2,5-dialkyl-4-propynylbenzenes in the presence of KOH in yields of 40-48%. The monomers carry hexyl, ethylhexyl, and (S)-3,7-dimethyloctyl side chains. Polymerization of the propynylated monomers furnishes organometallic polymers with a Pn of up to 230 arylene-ethynylene units. The polymers were fully characterized by polarizing microscopy, transmission electron microscopy, circular dichroism, differential scanning calorimetry, and X-ray diffraction (XRD). They show nematic, lyotropic liquid crystalline phases as well as chiroptical properties from which aggregation in poor solvents and in the solid state can be concluded. Lamellar or irregular honeycomb-shaped morphologies in these organometallic polymers can be detected by electron microscopy.
authors.affiliation: Department of Chemistry and Biochemistry, The University of South Carolina, Columbia 29208, USA.
authors.forename: W
authors.initials: W
authors.lastname: Steffen
authors.forename: B
authors.initials: B
authors.lastname: Köhler
authors.forename: M
authors.initials: M
authors.lastname: Altmann
authors.forename: U
authors.initials: U
authors.lastname: Scherf
authors.forename: K
authors.initials: K
authors.lastname: Stitzer
authors.forename: H C
authors.initials: HC
authors.lastname: zur Loye
authors.forename: U H
authors.initials: UH
authors.lastname: Bunz