Matrix effects during potassium and calcium determinations in rice saplings using X-ray spectrometery.
For selectively excited calcium K X-rays in rice saplings, the relations alpha = N(KR)[1 + A gamma + B beta/(1 + alpha)] and 1/N(Ca) = alpha/beta + b + c beta are found to support the enhancement of potassium K X-rays and N(Ca) calcium K X-ray counts during potassium and calcium determinations, respectively. Here alpha, beta and gamma are weight fractions of potassium, calcium and the matrix substrate, respectively, N(KR) is the relative potassium K X-ray counts of the sample to that of pure potassium and A, B, a, b and c are constants. Tests of these relations, using eight known mixtures of CaCO3, KNO3 and Na2B4O7 10H2O (borax), have further supported the findings.
Vandana
Physics Department, Punjabi University, Patiala, India.
Mittal
R
R
D002118:Calcium / Q000032:analysis*; D012275:Oryza / Q000737:chemistry*; D011188:Potassium / Q000032:analysis*; D013052:Spectrometry, X-Ray Emission / Q000379:methods* / Q000706:statistics & numerical data
D011188:Potassium; D002118:Calcium