Predicting electrospray response from chromatographic retention time.
The relationship between electrospray ionization response and HPLC retention time was explored. For the series of small peptides studied, higher ESI response was observed for analytes with longer reversed-phase HPLC retention times. This correlation existed for both experimentally measured retention times and those calculated from amino acid retention coefficients. This study is useful t
Cech
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NB
Department of Chemistry, The University of New Mexico, Albuquerque 87131-1096, USA.
Krone
J R
JR
Enke
C G
CG
D000465:Algorithms; D009842:Oligopeptides / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization / Q000706:statistics & numerical data*
D009842:Oligopeptides