title: Corrections to moving chemical reaction boundary equation for weak reactive electrolytes under the existence of background electrolyte KCl in large concentrations.
abstract: In this report, the moving chemical reaction boundary (MCRB) was formed by the weak reaction electrolytes of NH3.H2O and CH3COOH under the existence of background electrolyte KCl in large concentrations, the experiments were compared with the predictions by the moving chemical reaction boundary equation (MCRBE) for weak reactive electrolytes. It was found that the experimental results are far from the predictions with the MCRBE. So the MCRBEs must be corrected under the given experimental conditions. The corrected MCRBEs are given for the MCRB formed with weak reactive electrolytes coupled with KCl at high concentrations.
authors.affiliation: Department of Chemistry, University of Science and Technology of China, Hefei. cxcao@mail.ustc.edu.cn
authors.forename: C X
authors.initials: CX
authors.lastname: Cao
authors.forename: S L
authors.initials: SL
authors.lastname: Zhou
authors.forename: Y Z
authors.initials: YZ
authors.lastname: He
authors.forename: Y T
authors.initials: YT
authors.lastname: Qian
authors.forename: L
authors.initials: L
authors.lastname: Yang
authors.forename: Q S
authors.initials: QS
authors.lastname: Qu
authors.forename: W E
authors.initials: WE
authors.lastname: Gan
authors.forename: L
authors.initials: L
authors.lastname: Dong
authors.forename: Y Q
authors.initials: YQ
authors.lastname: Zhao
authors.forename: W K
authors.initials: WK
authors.lastname: Chen
mesh_terms: D004573:Electrolytes / Q000737:chemistry*; D011189:Potassium Chloride / Q000737:chemistry*
chemical_list: D004573:Electrolytes; D011189:Potassium Chloride