A novel approach for the quantitative kinetic study of reactions at solid/liquid interfaces in the presence of power ultrasound.
A novel cell and procedure is described which permits the quantitative mechanistic study of ultrasonically enhanced reactions which occur at solid/liquid interfaces. A model of a controlled and calculable time-average rate of mass transport to and from the interface is used in order to compare experimental results with theoretical predictions based on mechanistic reaction schemes. In this way concentrations of mechanistically significant species near the interface can be related to those in bulk solution and hence the sonochemical effects of ultrasound dissected from those arising purely from mass transport. The effect of ultrasound is demonstrated for the reaction dissolution of p-chloranil in the presence of aqueous base and for the reaction of the same substrate with the aromatic amine, N,N-dimethyl-phenylenediamine, both systems which have been studied previously in the absence of ultrasound. Complementary atomic force microscopy images are also reported.
Physical and Theoretical Chemistry Laboratory, Oxford University, UK.
J
J
Booth
R G
RG
Compton
E
E
Hill
F
F
Marken
T O
TO
Rebbitt