Bis(tetrahydrofuran-kappa O)(meso-5,10,15,20-tetraisopropylporphyrinato-kappa(4)N)iron(III) perchlorate.
The title complex, [Fe(C(32)H(36)N(4))(C(4)H(8)O)(2)]ClO(4), shows an S(4)-ruffled porphyrin ring, where the maximum deviation of the meso-carbon from the least-squares plane of the [Fe(C(20)N(4))] core is as high as 0.675 (9) A. This is the highest class of deviation among S(4)-ruffled iron(III) porphyrin complexes. The average Fe-N(p) bond distance is 1.967 (12) A (N(p) denotes an N atom of the equatorial ligand).
Ohgo
Y
Y
Department of Chemistry, Toho University School of Medicine, 5-21-16 Omorinishi, Ota-ku, Tokyo 143-8540, Japan. yohgo@med.toho-u.ac.jp
Saitoh
T
T
Nakamura
M
M
D018360:Crystallography, X-Ray; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation
C428905:Bis(tetrahydrofuran-kappa O)(meso-5,10,15,20-tetraisopropylporphyrinato-kappa(4)N)iron(III) perchlorate; D008665:Metalloporphyrins