Microwave assisted extraction of polycyclic aromatic hydrocarbons from atmospheric particulate samples.
For several years, microwave assisted extraction (MAE) was applied to extract organic compounds such as polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls, etc., from soils, sediments and standard reference materials. Very few authors applied this methodology for the extraction of PAHs from atmospheric particulate matter. In the present study, MAE of polycyclic aromatic hydrocarbons with hexane/acetone (1:1) from real atmospheric particulate samples was investigated and the effect of microwave energy and irradiation time studied. The yields of extracted compounds obtained by microwave irradiation were compared with those obtained using traditional Soxhlet extraction. MAE was evaluated using spiked real atmospheric particulate samples and two standard reference materials. Analytical determinations of PAHs were carried out by high performance liquid chromatography (HPLC) with ultraviolet and fluorescence detection. The best recoveries were achieved with a microwave energy of 400 W and an irradiation time of 20 min.
Piñeiro-Iglesias
M
M
Department of Analytical Chemistry, Faculty of Sciences, University of A Coruña, Spain.
López-Mahía
P
P
Vázquez-Blanco
E
E
Muniategui-Lorenzo
S
S
Prada-Rodríguez
D
D
Fernández-Fernández
E
E
D000393:Air Pollutants / Q000032:analysis*; D001272:Atmosphere / Q000737:chemistry*; D002851:Chromatography, High Pressure Liquid; D008872:Microwaves; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis*; D012015:Reference Standards; D013997:Time Factors; D014507:Urbanization; D001335:Vehicle Emissions / Q000032:analysis
D000393:Air Pollutants; D011084:Polycyclic Aromatic Hydrocarbons; D001335:Vehicle Emissions