On the frequency and isotope effect in sonochemistry.
In the first part of the work, it was observed, by a relative method, that the Weissler reaction and the Br2-catalysed isomerisation of maleic acid into fumaric acid are faster at 20 kHz than at 1.7 MHz. The difference between the relative reaction rates can be considered as small when the two order magnitude difference between the two frequencies is taking into account. In the second part of the work, the frequency effect associated to an isotope effect was studied. The Weissler reaction was performed in H2O and D2O at 20 kHz and 1.7 MHz. The isotope effect is not the same at the two frequencies.
Université Libre de Bruxelles, Laboratoire de Chimie Organique EP, CP 165, Brussels, Belgium.
C
C
Dekerckheer
O
O
Dahlem
J
J
Reisse