Polymers and surfactants on the basis of renewable resources.
A new strategy for the preparation of different polymers and special surfactants was developed. First, unsaturated fatty acid methyl esters obtained from plant oils were converted to terminally unsaturated esters and alpha-olefins by metathesis with ethylene using heterogeneous rhenium or homogeneous ruthenium catalysts. These esters were directly copolymerized with ethylene by an insertion-type palladium-catalyzed polymerization to functionalized polyolefins. Polyesters were synthesized by metathetical dimerization of omega-unsaturated esters and subsequent polycondensation of the produced internally unsaturated dicarboxylic esters or by acidic transesterification with petrochemical diols and additional acyclic diene metathesis polymerization. Omega-epoxy fatty acid methyl esters, achieved by a new method of chemo-enzymatic epoxidation, were converted into polyethers with comb-structure catalyzed by aluminoxanes on the one hand and into sugar surfactants by nucleophilic ring-opening with amino carbohydrates on the other hand.
Warwel
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Federal Centre for Cereal, Potato and Lipid Research, Institute for Biochemistry and Technology of Lipids, HP Kaufmann-Institute, Münster, Germany. ibtfett@uni-muenster.de
Brüse
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Demes
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Kunz
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Rüsch gen Klaas
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D050260:Carbohydrate Metabolism; D003247:Conservation of Natural Resources; D005227:Fatty Acids / Q000378:metabolism; D010938:Plant Oils; D011091:Polyesters; D011108:Polymers / Q000138:chemical synthesis*; D013501:Surface-Active Agents / Q000138:chemical synthesis*
D005227:Fatty Acids; D010938:Plant Oils; D011091:Polyesters; D011108:Polymers; D013501:Surface-Active Agents