Microwave assisted extraction for trace element analysis of plant materials by ICP-AES.
Application of microwave assisted extraction for the decomposition and dissolution of plant samples for trace metal determination by ICP-AES was examined. Dried onion, leaves of spinach beet and three reference materials CTA-OTL-1, CTA-VTL-2 and CL-1 were analyzed. Water, EDTA and hydrochloric acid (0.01, 0.10 and 1.0 M, respectively) were used as leaching solutions. The extraction efficiency was investigated by comparison of the results with those obtained after microwave wet digestion. HCl was found to be very suitable for quantitative extraction of B, Ba, Cd, Cu, Mn, Ni, Pb, Sr and Zn from the samples. For reference materials, the measured concentrations are well consistent with the certified values. The use of EDTA led to a complete extraction of B, Cd, Ni, Pb, Sr and Zn. Water was found to be a good leaching solution for boron. For extraction with HCl and EDTA, the RSD values for the concentrations measured were below 8% for most of the elements.
Department of Chemistry, Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland.
J
J
Borkowska-Burnecka
D007202:Indicators and Reagents; D008872:Microwaves; D019697:Onions / Q000737:chemistry; D010944:Plants / Q000737:chemistry*; D013054:Spectrophotometry, Atomic; D018724:Spinacia oleracea / Q000737:chemistry; D014131:Trace Elements / Q000032:analysis*
D007202:Indicators and Reagents; D014131:Trace Elements