Three new taxane diterpenoids from the seeds of the Chinese yew, Taxus chinensis var mairei.
Three new taxoids were isolated from the seeds of the Chinese yew, Taxus chinesis var mairei, their structures were established as 9alpha, 13alpha-diacetoxy-5alpha-cinnamoyloxy-11(15-->1)-abeo-taxa-4(20),11-diene-10beta, 15-diol, 2alpha,9alpha,10beta-triacetoxy-taxa-4(20),11-diene-5alpha,13alpha-diol and 2alpha,7beta,10beta-triacetoxy-5alpha-cinnamyloxy-9alpha-hydroxy-taxa-4(20),11-diene-13-one on the basis of 1D, 2D NMR, and MS spectral analyses.
Division of Life Science, Graduate School of Agricultural Science, Tohoku University, Sendai, Japan. shi@biochem.tohoku.ac.jp
Q W
QW
Shi
T
T
Oritani
J S
JS
Gu
Q Z
QZ
Meng
R L
RL
Liu
D002934:Cinnamates / Q000737:chemistry* / Q000302:isolation & purification; D004224:Diterpenes / Q000737:chemistry* / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D008968:Molecular Conformation; D010946:Plants, Medicinal; D012639:Seeds / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D020946:Taxus / Q000737:chemistry*
C426405:2,7,10-triacetoxy-5-cinnamyloxy-9-hydroxy-taxa-4(20),11-diene-13-one; C426404:2,9,10-triacetoxy-taxa-4(20),11-diene-5,13-diol; C426403:9,13-diacetoxy-5-cinnamoyloxy-11(15-1)-abeo-taxa-4(20),11-diene-10,15-diol; D002934:Cinnamates; D004224:Diterpenes