Bis[2,2'-ethylenedioxydibenzaldehyde bis(thiocarbohydrazide)] tris(pyridine) solvate.
The title compound, a novel 30-membered 2:2 macrocyclic thiocarbohydrazone, C(34)H(32)N(8)O(4)S(2) x 3C(5)H(5)N, has been prepared and crystallographically characterized. The molecule of the compound is twisted. One dioxabutane group is boat-like in shape, whereas the other is highly disordered. The crystal structure is stabilized by inter- and intramolecular hydrogen bonds.
Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla 90112, Thailand. suchada@ratree.psu.ac.th
S
S
Chantrapromma
I A
IA
Razak
H K
HK
Fun
C
C
Karalai
H
H
Zhang
F X
FX
Xie
Y P
YP
Tian
W
W
Ma
Y H
YH
Zhang
S S
SS
Ni