Enantioselective syntheses of (13)C-labeled (2R)- and (2S)-phytochromobilin dimethyl ester.
(2R)- and (2S)-phytochromobilin dimethyl ester have been prepared in enantiomerically pure form, specifically (13)C-labeled at C(10) or C(15).
Jacobi
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Burke Chemical Laboratory, Dartmouth College, Hanover, New Hampshire 03755, USA. peter.a.jacobi@dartmouth.edu
Pippin
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D001664:Biliverdine / Q000031:analogs & derivatives* / Q000138:chemical synthesis*; D002247:Carbon Isotopes; D004952:Esters / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D007553:Isotope Labeling / Q000379:methods; D008968:Molecular Conformation; D015394:Molecular Structure; D013237:Stereoisomerism
D002247:Carbon Isotopes; D004952:Esters; D007202:Indicators and Reagents; C075811:phytochromobilin; D001664:Biliverdine