Synthesis of polyacetylenic acids isolated from Heisteria acuminata.
Four linear polyacetylenic compounds were synthesized. Pentadeca-6,8,10-triynoic acid 1 and octadeca-8,10,12-triynoic acid 2 were synthesized by using acetylene coupling reactions. The syntheses of (Z)-hexadec-11-en-7,9-diynoic acid 3 and (Z)-octadec-12-en-7,9-diynoic acid 4 by using vinylic telluride coupling reactions were accomplished.
Zeni
G
G
Departamento de Química, Laboratório de Bioquímica Toxicológica, UFSM, 97105-900 Santa Maria, RS, Brazil. gzeni@quimica.ufsm.br
Panatieri
R B
RB
Lissner
E
E
Menezes
P H
PH
Braga
A L
AL
Stefani
H A
HA
D000114:Acetylene / Q000031:analogs & derivatives* / Q000138:chemical synthesis* / Q000302:isolation & purification; D000480:Alkynes; D005231:Fatty Acids, Unsaturated / Q000138:chemical synthesis* / Q000302:isolation & purification; D007202:Indicators and Reagents; D019684:Magnoliopsida / Q000737:chemistry; D008519:Medicine, Traditional; D015394:Molecular Structure; D008517:Phytotherapy; D018547:Plant Stems / Q000737:chemistry; D010946:Plants, Medicinal / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis* / Q000302:isolation & purification; D053279:Polyynes
D000480:Alkynes; D005231:Fatty Acids, Unsaturated; D007202:Indicators and Reagents; D011108:Polymers; D053279:Polyynes; C031203:2-hexadecynoic acid; D000114:Acetylene