Adsorption of methabenzthiazuron on six allophanic and nonallophanic soils: effect of organic matter amendment.
This article reports on methabenzthiazuron [1-(1,3-benzothiazol-2-yl)-1,3-dimethylurea] (MBT) adsorption process on six agricultural allophanic and nonallophanic soils. The effect of amendment with exogenous organic matter was also studied. Adsorption kinetic fits an hyperbolic model. MBT adsorption reached an apparent equilibrium within 2 h and followed a second-order reaction. The maximum adsorbed amounts for natural soils ranged from 32 to 145 microg g(-1). Rate constants were considered relatively low (0.27-1.5 x 10(-4) [microg g(-1)](1-n) s-1); the slow process was attributed to a combined effect of difussion and adsorption. MBT adsorption fits the Freundlich model with r values > or =0.998 at P < or = 0.001 significance levels. Kf and Freundlich exponents (l/n) ranged from 5.3 to 82.1 cm3 g(-1) and from 0.66 to 0.73, respectively. Kf values for soils with a low organic matter content were lower than that obtained from the only typical allophanic soil derived from volcanic ash under study. Lineal regression analysis between Kf and organic matter content of nonallophanic soils gave a correlation coefficient of 0.980 (P = 0.02). Dispersion of Kd values together with close values of K(OM) indicate that organic matter (OM) was the principal component responsible for MBT adsorption in unamended soils. Addition of peat decreased soil pH and increased adsorption capacity for allophanic and nonallophanic soils. Kinetic experiments showed enhancements of Xmax values and lower rate constants.
Department of Inorganic and Analytical Chemistry, Faculty of Chemical and Pharmaceutical Sciences, University of Chile, Santiago. mbaez@ciq.uchile.cl
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Báez
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Rodríguez
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Vilches
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Romero
D000327:Adsorption; D052160:Benzothiazoles; D002851:Chromatography, High Pressure Liquid; D006540:Herbicides / Q000032:analysis / Q000737:chemistry*; D007700:Kinetics; D008782:Methylurea Compounds / Q000032:analysis / Q000737:chemistry*; D008956:Models, Chemical; D012987:Soil / Q000032:analysis*; D012989:Soil Pollutants / Q000032:analysis / Q000378:metabolism*; D014508:Urea / Q000031:analogs & derivatives*
D052160:Benzothiazoles; D006540:Herbicides; D008782:Methylurea Compounds; D012987:Soil; D012989:Soil Pollutants; C054306:allophanic acid; C011912:methabenzthiazuron; D014508:Urea