Effects of flue gas composition on the catalytic destruction of chlorinated aromatic compounds with a V-oxide catalyst.
When using catalytic flue gas cleaning, several flue gas compounds may influence oxidation reactions of hazardous volatile organic compounds, possibly leading to lower reaction rates and, thus, to an incomplete destruction. Experimental investigations were performed with regard to the influence of selected flue gas compounds, like hydrogen chloride, sulfur dioxide, oxygen, and water vapour, on the catalytic destruction behavior of chlorobenzenes under flue gas cleaning conditions of an incineration plant. For this purpose, a metal oxide catalyst was operated at different temperatures at a space velocity of 3600 h-1 in a laboratory-scale fixed bed reactor with model flue gases, and with real flue gases generated from the TAMARA waste incineration plant. The results obtained from the studies with model flue gas were analyzed with respect to reaction kinetics. These kinetics were applied for comparison with the experimental data gained in the real flue gas.
Forschungszentrum Karlsruhe GmbH, Institut für Technische Chemie-Bereich Thermische Abfallbehandlung, Postfach 3640, D-76021 Karlsruhe, Germany. stoll@itc-tab.fzk.de
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M
Stoll
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Furrer
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H
Seifert
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G
Schaub
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D
Unruh
D002384:Catalysis; D002722:Chlorobenzenes / Q000737:chemistry*; D005740:Gases / Q000737:chemistry*; D006256:Hazardous Waste / Q000032:analysis; D017745:Incineration / Q000295:instrumentation* / Q000379:methods; D007700:Kinetics; D008962:Models, Theoretical; D010084:Oxidation-Reduction; D000072317:Polychlorinated Dibenzodioxins / Q000031:analogs & derivatives* / Q000737:chemistry; D012989:Soil Pollutants; D014025:Titanium / Q000737:chemistry; D014414:Tungsten / Q000737:chemistry; D014639:Vanadium / Q000737:chemistry; D014835:Volatilization; D018505:Waste Management / Q000379:methods*
D002722:Chlorobenzenes; D005740:Gases; D006256:Hazardous Waste; D000072317:Polychlorinated Dibenzodioxins; D012989:Soil Pollutants; D014639:Vanadium; D014025:Titanium; D014414:Tungsten