Behavioral patterns of heterometallic cuboidal derivatives of [M3Q4(H2O)9]4+ (M = Mo, W; Q = S, Se).
This Account reports recent progress in the study of some approximately 20 heterometal derivatives of [Mo3S4(H2O)9]4+ with reference also to W and Se analogues. Single cubes (3:1) and corner-shared double cubes (6:1), as well as dimers of the 3:1 single cubes, are considered. A classification of the heterometals as subtypes A, B, and C is introduced.
Departamento de Quimica Inorganica, Universidad de la Laguna, 38200 La Laguna, Islas Canarias, Spain.
R
R
Hernandez-Molina
M N
MN
Sokolov
A G
AG
Sykes
D000388:Air / Q000032:analysis; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D009942:Organometallic Compounds; D008982:Molybdenum