QSRR correlation of free-radical polymerization chain-transfer constants for styrene.
Quantitative structure-reactivity relationships (QSRR) are deduced for kinetic chain-transfer constants for 90 agents on styrene polymerization at 60 degrees C. Three- and five-parameter correlations were obtained with R2 of 0.725 and 0.818, respectively. The descriptors involved in the correlations are consistent with the proposed mechanism of the chain-transfer reactions.
Ignatz-Hoover
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Flexsys America L.P., 260 Springside Drive, P.O. Box 5444, Akron, Ohio 44334-0444, USA.
Petrukhin
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Karelson
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Katritzky
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D005609:Free Radicals; D011137:Polystyrenes / Q000138:chemical synthesis; D021281:Quantitative Structure-Activity Relationship; D020058:Styrene / Q000737:chemistry*
D005609:Free Radicals; D011137:Polystyrenes; D020058:Styrene