Synthesis of an L-quinovose-containing disaccharide.
The synthesis of a versatile L-rhamnose monosaccharide synthon is described. This synthon is used in the synthesis of a disaccharide containing the rare sugar, 6-deoxy-L-glucose, linked to the 3-C-hydroxymethyl group of methyl 2,3-O-isopropylidene 3-C-(hydroxymethyl)-beta-D-erythrofuranoside.
Rich
J R
JR
Department of Chemistry, University of Northern British Columbia, Prince George, Canada.
McGavin
R S
RS
Reimer
K B
KB
D002236:Carbohydrate Conformation; D004187:Disaccharides / Q000138:chemical synthesis*; D006031:Glycosylation; D006574:Heterocyclic Compounds, 2-Ring / Q000138:chemical synthesis*; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D010368:Pectins / Q000737:chemistry*
D004187:Disaccharides; D006574:Heterocyclic Compounds, 2-Ring; C430210:methyl 4-O-allyl-3-O-benzoylquinovopyranosyl-(1-3')-2,3-O-isopropylidene-3-C-(hydroxymethyl)erythrofuranoside; C042492:rhamnogalacturonan II; D010368:Pectins