Determination of n-alkanes and polycyclic aromatic hydrocarbons in atmospheric particulate and vapour phases in Oviedo, Spain, by GC-MS.
A GC-MS procedure for the determination of hydrocarbons in air samples from Oviedo, Spain, was developed. Air hydrocarbons were sampled with a high volume sampler equipped with a holder containing a glass fiber filter, to trap the particulate phase, and two polyurethane foams to capture hydrocarbons of the vapour phase. Compounds were extracted with CH2Cl2 by Soxhlet extraction and then fractionated using column chromatography with alumina silica. Analyses of the fractions were performed by GC-MS in the electron ionization mode. PAHs and n-alkanes were the compounds examined in this work. Samples collected in the vicinity of the Faculty of Chemistry (a semi-urban area) were analysed. The total concentration of PAHs in the air samples analysed ranged from 28 to 76 ng m(-3). The total concentration of n-alkanes and PAHs in the vapour phase exceeded the concentration in the particulate phase in the samples analysed.
Leal-Granadillo
I A
IA
Department of Physical and Analytical Chemistry, University of Oviedo, Spain.
Alonso
J I
JI
Sanz-Medel
A
A
D000397:Air Pollution / Q000032:analysis*; D000473:Alkanes / Q000032:analysis*; D002623:Chemistry Techniques, Analytical / Q000379:methods; D004784:Environmental Monitoring / Q000379:methods*; D008401:Gas Chromatography-Mass Spectrometry; D010316:Particle Size; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis*; D013030:Spain
D000473:Alkanes; D011084:Polycyclic Aromatic Hydrocarbons