Metal-catalyzed release of supported boronic acids for C-C bond formation.
The viability of solid-supported boronic acids as reagents for Suzuki couplings and nucleophilic additions to aldehydes and enones was successfully demonstrated. This metal-catalyzed cleavage strategy allows the synthesis of a series of functionalized biphenyl products, benzylic alcohols, and beta-substituted ketones.
Pourbaix
C
C
Université Rennes 1, Synthèse et Electrosynthèse organiques, UMR 6510 associée au CNRS, Campus de Beaulieu, 35042 Rennes Cedex, France.
Carreaux
F
F
Carboni
B
B