High-Resolution Spectroscopy and Analysis of the nu(3) and nu(4) Fundamentals of Monoisotopic (70)GeF(4).
The first high-resolution study on germanium tetrafluoride is reported. We used a monoisotopic sample of (70)GeF(4). The FTIR spectra of the two infrared active fundamentals, namely the nu(4) (bending) and nu(3) (stretching) modes, were recorded at a temperature of ca. 210 K and a resolution (1/maximum optical path difference) of 0.0031 and 0.0023 cm(-1), respectively. These spectra were analyzed using the STDS software developed in Dijon. In both cases, we obtained a fit with a root mean square better than 1x10(-3) cm(-1). Both bands show very regular structures with no detectable perturbation. Copyright 2001 Academic Press.
Boudon
V.
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Laboratoire de Physique de l'Université de Bourgogne, UMR CNRS No. 5027, 9, Avenue Alain Savary, Dijon Cedex, F-21078, France
Bürger
H.
H
Mkadmi
E. B.
EB