Synthesis and characterization of bis(mu-hydroxo)diiron(III) complex of N-(4-nitro-2-hydroxy)phenylmethyl-N-(2-pyridylethyl)-N-(2-pyridylmethyl)amine and hydroxylation reaction of alkane.
Bis(mu-hydroxo)diiron(III) complex, [Fe2III(mu-OH)2(NE)2](NO3)2 x 3H2O (3) (N-(4-nitro-2-hydroxy)phenylmethyl-N-(2-pyridylethyl)-N-(2-pyridylmethyl)amine = HNE, where H denotes a dissociable proton of the p-nitrophenol group), has been prepared and characterized by X-ray crystallography, electronic and magnetic spectroscopies.
Kurosaki
H
H
Faculty of Pharmaceutical Sciences, Kumamoto University, Japan.
Yoshida
H
H
Ito
M
M
Koike
H
H
Higuchi
E
E
Goto
M
M
D000473:Alkanes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005290:Ferric Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry; D006900:Hydroxylation; D008968:Molecular Conformation; D013056:Spectrophotometry, Ultraviolet
D000473:Alkanes; C429404:Bis(mu-hydroxo)diiron(III), N-(4-nitro-2-hydroxy)phenylmethyl-N-(2-pyridylethyl)-N-(2-pyridylmethyl)amine; D005290:Ferric Compounds; D006861:Hydrogen Peroxide