Syntheses of daidzein-7-yl beta-D-glucopyranosiduronic acid and daidzein-4',7-yl di-beta-D-glucopyranosiduronic acid.
Syntheses of the title compounds--commonly known as 'daidzein 7-glucuronide' and 'daidzein 4',7-diglucuronide'--are described. Selective 7-deacetylation of 4',7-di-O-acetyldaidzein is employed.
Needs
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PW
Institute of Food Research, Norwich Research Park, Colney, UK.
Williamson
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D000107:Acetylation; D002851:Chromatography, High Pressure Liquid; D005965:Glucuronates / Q000138:chemical synthesis*; D006031:Glycosylation; D007529:Isoflavones / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure
D005965:Glucuronates; D007529:Isoflavones; C430209:daidzein-4',7-yl diglucopyranosiduronic acid; C430208:daidzein-7-yl glucopyranosiduronic acid; C004742:daidzein