title: Spectroscopy of UO(2)Cl(4)(2)(-) in basic aluminum chloride-1-ethyl-3-methylimidazolium chloride.
abstract: The optical absorption, emission, FT Raman, one-photon excitation, two-photon excitation, and luminescence lifetime measurements are reported for UO(2)Cl(4)(2)(-) in 40:60 AlCl(3)-EMIC (where EMIC identical with 1-ethyl-3-methylimidazolium chloride), a room-temperature ionic liquid. Comparison of the spectra with previous results from single crystals containing UO(2)Cl(4)(2)(-) allowed the characterization of four ground-state vibrational frequencies, two excited-state vibrational frequencies, and the location of eight electronic excited-state energy levels. The vibrational frequencies and electronic energy levels are found to be consistent with the UO(2)Cl(4)(2)(-) ion. Comparison of the one-photon and two-photon excitation spectra, and the relative intensities of the transitions in the emission spectrum indicate that the center of symmetry is perturbed by an interaction with the solvent.
authors: Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.
authors: T A
authors: TA
authors: Hopkins
authors: J M
authors: JM
authors: Berg
authors: D A
authors: DA
authors: Costa
authors: W H
authors: WH
authors: Smith
authors: H J
authors: HJ
authors: Dewey