title: Interstellar ices as a source of CN-bearing molecules in protoplanetary disks.
abstract: A reliable model for the composition and evolution of interstellar ices in regions of active star formation is fundamental to our quest to determine the organic inventory of planetesimals in the early Solar System. This has become a realistic goal since the launch of the Infrared Space Observatory, which provides a facility for infrared spectroscopy unhindered by telluric absorption over the entire spectral range of vibrational modes in solids of exobiological interest. Interstellar molecules detected in the solid phase to date include H2O, NH3, CO, CO2, CH3OH, CH4, H2CO, OCS and HCOOH, together with a C identical to N-bonded absorber generically termed 'XCN'. In this article, we focus on cosmic synthesis of CN-bearing species, as this important class of prebiotic molecules may not have formed endogenously in significant quantities on early Earth if conditions were not highly reducing. Experiments in which interstellar ice analogs are subject to UV photolysis or energetic ion bombardment yield CN-rich residues with a spectral signature that matches a corresponding feature observed in young protostars enshrouded in dust and gas. CN-bearing species are also present in cometary ices, with a combined abundance comparable to the lower end of the range observed in protostars. Energetic processing of interstellar ices is thus a viable and potentially significant source of CN compounds in protoplanetary disks.
authors: New York Center for Studies on the Origins of Life, and Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180, USA. doug@whittet.phys.rpi.edu
authors: D C
authors: DC
authors: Whittet
authors: E L
authors: EL
authors: Gibb
authors: A
authors: A
authors: Nummelin
mesh_terms: D019418:Evolution, Chemical; D019419:Evolution, Planetary; D005118:Extraterrestrial Environment; D005544:Forecasting; D007053:Ice; D019110:Meteoroids; D009570:Nitriles / Q000737:chemistry*; D016082:Solar System
chemical_list: D007053:Ice; D009570:Nitriles; C011206:cyanogen