The formation of 2-chlorobenzamide upon hydrolysis of the benzoylphenylurea insecticide 1-(2-chlorobenzoyl)-3-(4-chlorophenyl) urea in different water systems.
It has been reported that 1-(2-chlorobenzoyl)-3-(4-chlorophenyl) urea (CCU), an insect growth regulator, has no measurable toxicity to nontarget organisms and is essentially harmless to humans. However, one of its degradation products, 2-chlorobenzamide (CBA), is suspected of being a carcinogen. Therefore, the maximum concentration of CBA formed and the dynamics of its formation need to be given careful attention after CCU is used in the field. This paper describes the degradation of CCU to form CBA in three different water systems (distilled water, spring water, and simulated seawater) and the effects of temperature on the dynamics of CBA formation. The results indicate that the maximum level of CBA concentration is different in the different systems (highest in spring water) and that the temperature has a significant impact on the process (higher temperature leads to higher and earlier peak of CBA concentration). The maximum concentration of CBA after application of CCU was approximately 3.8% of the initial concentration of CCU at 35 degrees C in distilled water, and 2.4% in spring water at 25 degrees C.
Guoguang
L
L
College of Chemistry and Environmental Sciences, The Key Laboratory of Environmental Sciences and Technology of High Education of Henan Province, Henan Normal University, Xinxiang 453002, Henan, People's Republic of China. ggliu@public.xxptt.ha.cn
Qingxiang
Z
Z
Wenying
L
L
D001549:Benzamides / Q000032:analysis / Q000737:chemistry*; D005618:Fresh Water; D006801:Humans; D006868:Hydrolysis; D007605:Juvenile Hormones / Q000737:chemistry*; D007700:Kinetics; D010671:Phenylurea Compounds / Q000737:chemistry*; D012623:Seawater; D014874:Water Pollutants, Chemical / Q000032:analysis
D001549:Benzamides; D007605:Juvenile Hormones; D010671:Phenylurea Compounds; D014874:Water Pollutants, Chemical; C012666:1-(4-chlorophenyl)-3-(2,6-dichlorobenzoyl)urea; C412475:2-chlorobenzamide