Bis(2,2'-bipyridine)(dicyanamido)copper(II) tetrafluoroborate.
In the title compound, [Cu(C(2)N(3))(C(10)H(8)N(2))(2)]BF(4), the Cu(II) atom shows distorted trigonal-bipyramidal geometry, with the dicyanamido ligand in the equatorial plane. The two out-of-plane Cu-N bond lengths to bipyridine are 2.006 (3) and 1.998 (3) A, whereas the in-plane Cu-N distances are 2.142 (3) and 2.043 (3) A to the bipyridine, and 2.015 (3) A to the dicyanamide.
Potocnák
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Department of Inorganic Chemistry, Faculty of Science, PJ Safárik University, Moyzesova 11, 041 54 Kosice, Slovakia. potocnak@kosice.upjs.sk
Dunaj-Jurco
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Miklos
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Massa
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Jäger
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