The complete dechlorination of DDT by magnesium/palladium bimetallic particles.
The complete dechlorination of 1,1-bis(4-chlorophenyl)-2,2,2-trichloroethane (DDT) by a magnesium/palladium bimetallic system has been accomplished. The reaction takes place under ambient temperature and pressure and mild reaction conditions requiring only 0.25 g of magnesium and 0.3% palladium (wt/wt) to drive the dechlorination of 100 microg DDT (50 ppm in 2 ml). The process is both rapid and complete requiring less than 10 min to attain total dechlorination within the detection limit (approximately 10 pg for DDT) of electron capture detection gas chromatography (GC-ECD). The major product formed, as deduced from mass spectrometry (GC-MS) is the hydrocarbon skeleton, 1,1-diphenylethane. This technology may allow for the development of an economic and environmentally benign method of DDT remediation.
Engelmann
M D
MD
Department of Chemistry, College of Letters and Sciences, University of Idaho, Moscow 83844, USA.
Doyle
J G
JG
Cheng
I F
IF
D002713:Chlorine / Q000737:chemistry; D003634:DDT / Q000737:chemistry*; D004785:Environmental Pollutants; D004787:Environmental Pollution / Q000517:prevention & control; D008401:Gas Chromatography-Mass Spectrometry; D008274:Magnesium / Q000494:pharmacology*; D010165:Palladium / Q000494:pharmacology*; D010575:Pesticides / Q000737:chemistry*; D013057:Spectrum Analysis
D004785:Environmental Pollutants; D010575:Pesticides; D002713:Chlorine; D010165:Palladium; D003634:DDT; D008274:Magnesium