Changes in low molecular weight phenolic compounds in Spanish, French, and American oak woods during natural seasoning and toasting.
The evolution of low molecular weight polyphenols in Spanish oak heartwood of Quercus robur,Quercus petraea, Quercus pyrenaica, and Quercus faginea was studied by HPLC, in relation to the processing of wood in barrel cooperage. The polyphenolic composition of Spanish woods subjected to natural seasoning for 3 years and to the toasting process was studied in relation to those of French oak of Q. robur (Limousin) and Q. petraea (Allier) and American oak of Q. alba (Missouri), which are habitually used in cooperage. The concentrations of benzoic and cinnamic acids and aldehydes of Spanish woods increased during seasoning depending on the duration of this process and in the same way as those of French and American woods. The process having the main influence on the phenolic composition of wood was the toasting. It led to high increases in the concentration of phenolic aldehydes and acids, especially cinnamic aldehydes (sinapic and coniferylic aldehydes), followed by benzoic aldehydes (syringaldehyde and vanillin) and benzoic acids (syringic and vanillic acids). This polyphenolic composition in Spanish oak species evolved during toasting as in French and American oak, but quantitative differences were found, which were especially important in American species with respect to the others.
Cadahía
E
E
Departamento de Industrias Forestales, CIFOR-INIA, Apartado 8111, 28080 Madrid, Spain. cadahia@inia.es
Muñoz
L
L
Fernández de Simón
B
B
García-Vallejo
M C
MC
D002851:Chromatography, High Pressure Liquid; D005511:Food Handling / Q000379:methods*; D008970:Molecular Weight; D010636:Phenols / Q000032:analysis*; D013997:Time Factors; D014934:Wood
D010636:Phenols