Bis(2,2-bipyridine-N,N')tetra-mu-chloro-tetracopper(I).
A novel centrosymmetric chair-like dimer, bis(2,2'-bipyridine)-1kappa(2)N,N';3kappa(2)N,N'-tetra-mu-chloro-1:2kappa(2)Cl;2:3kappa(2)Cl;3:4kappa(2)Cl;1:4kappa(2)Cl-tetracopper(I), [Cu(4)Cl(4)(C(10)H(8)N(2))(2)], has been solvothermally synthesized and structurally characterized. The complex self-assembles into a three-dimensional network via C-H.Cl hydrogen bonds, pi-pi stacking and weak Cu.Cl electrostatic interactions.
Cui
Y
Y
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China. ycui@ustc.edu.cn
Chen
J
J
Chen
G
G
Ren
J
J
Yu
W
W
Qian
Y
Y