title: Measurement and modeling of diclosulam runoff under the influence of simulated severe rainfall.
abstract: A runoff study was conducted near Tifton, GA to measure the losses of water, sediment, and diclosulam (N-(2,6-dichlorophenyl)-5-ethoxy-7-fluoro-[1,2,4]triazolo-[1,5c]-pyrimidine- 2-sulfonamide), a new broadleaf herbicide, under a 50-mm-in-3-h simulated rainfall event on three separate 0.05-ha plots. Results of a runoff study were used to validate the Pesticide Root Zone Model (PRZM, v. 3.12) using field-measured soil, chemical, and weather inputs. The model-predicted edge-of-field diclosulam loading was within 1% of the average observed diclosulam runoff from the field study; however, partitioning between phases was not as well predicted. The model was subsequently used with worst-case agricultural practice inputs and a 41-yr weather record from Dublin, GA to simulate edge-of-field runoff losses for the two most prevalent soils (Tifton and Bibb) in the southeastern U.S. peanut (Arachis hypogaea L.) market for 328 simulation years, and showed that the 90th percentile runoff amounts, expressed as percent of applied diclosulam, were 1.8, 0.6, and 5.2% for the runoff study plots and Tifton and Bibb soils, respectively. The runoff study and modeling indicated that more than 97% of the total diclosulam runoff was transported off the field by water, with < 3% associated with the sediment. Diclosulam losses due to runoff can be further reduced by lower application rates, tillage and crop residue management practices that reduce edge-of-field runoff, and conservation practices such as vegetated filter strips.
authors: Dow AgroSciences, Bldg. 306/A2, 9330 Zionsville Road, Indianapolis, IN 46268, USA. iwesenbeeck@dowagro.com
authors: I J
authors: IJ
authors: van Wesenbeeck
authors: A L
authors: AL
authors: Peacock
authors: P L
authors: PL
authors: Havens
mesh_terms: D000383:Agriculture; D019015:Geologic Sediments / Q000737:chemistry; D006540:Herbicides / Q000032:analysis*; D008962:Models, Theoretical; D011891:Rain; D012989:Soil Pollutants / Q000032:analysis*; D013449:Sulfonamides / Q000032:analysis*; D014230:Triazoles / Q000032:analysis*; D014872:Water Movements
chemical_list: D006540:Herbicides; D012989:Soil Pollutants; D013449:Sulfonamides; D014230:Triazoles; C415325:diclosulam