alpha-thiocyanation of carbonyl and beta-dicarbonyl compounds using (dichloroiodo)benzene-lead(II) thiocyanate.
The combination reagent (dichloroiodo)benzene and lead(II) thiocyanate in dichloromethane effects oxidation of various enol silyl ethers, ketene silyl acetals, and beta-dicarbonyl compounds, thereby providing an efficient and convenient method for alpha-thiocyanation of carbonyl and beta-dicarbonyl compounds.
Prakash
O
O
Department of Chemistry, Kurukshetra University, Kurukshetra 136119, Haryana, India. chem@granth.kuk.ernet.in
Kaur
H
H
Batra
H
H
Rani
N
N
Singh
S P
SP
Moriarty
R M
RM
D002722:Chlorobenzenes / Q000737:chemistry*; D007202:Indicators and Reagents / Q000737:chemistry*; D007462:Iodobenzenes / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D013057:Spectrum Analysis; D013861:Thiocyanates / Q000737:chemistry*
D002722:Chlorobenzenes; D007202:Indicators and Reagents; D007462:Iodobenzenes; D007659:Ketones; D013861:Thiocyanates; C427477:lead(II) thiocyanate