Barium oxoaluminate hydride.
The crystal structure of Ba(3)(AlO(4))H is isotypic with Ba(3)SiS(5) and contains AlO(4)(5-) and H(-) anions. The hydride and oxide anions are coordinated by six Ba and five Ba/one Al atoms in an octahedral geometry. The hydrogen content was examined by MAS-NMR experiments of the deuterated compound.
Zumdick
M
M
Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstrasse 21, D-79104 Freiburg, Germany.
Althoff
G
G
Röhr
C
C