title: A study of C-F.M+ interaction: alkali metal complexes of the fluorine-containing cage compound.
abstract: The C-F.M(+) interaction was investigated by employing a cage compound 1 that has four fluorobenzene units. The NMR ((1)H, (13)C, and (19)F) spectra and X-ray crystallographic analyses of 1 and its metal complexes showed clear evidence of the interaction. Short C-F.M(+) distances (C-F.K(+), 2.755 and 2.727 A; C-F.Cs(+), 2.944 and 2.954 A) were observed in the crystalline state of K(+) subset 1 and Cs(+) subset 1. Furthermore, the C-F bond lengths were elongated by the interaction with the metal cations. By calculating Brown's bond valence, it is shown that the contribution of the C-F unit to cation binding is comparable or greater than the ether oxygen in the crystalline state. Representative spectroscopic changes implying the C-F.M(+) interaction were observed in the NMR ((1)H, (13)C, and (19)F) spectra. In particular, (133)Cs-(19)F spin coupling (J = 54.9 Hz) was observed in the Cs(+) complex.
authors: Department of Chemistry, Faculty of Science, Kyushu University, Ropponmatsu 4-2-1, Chuo-ku, Fukuoka 810-8560, Japan. takemura@rc.kyushu-u.ac.jp
authors: H
authors: H
authors: Takemura
authors: N
authors: N
authors: Kon
authors: M
authors: M
authors: Kotoku
authors: S
authors: S
authors: Nakashima
authors: K
authors: K
authors: Otsuka
authors: M
authors: M
authors: Yasutake
authors: T
authors: T
authors: Shinmyozu
authors: T
authors: T
authors: Inazu