Nematic-wetted colloids in the isotropic phase: pairwise interaction, biaxiality, and defects.
We calculate the interaction between two spherical colloidal particles embedded in the isotropic phase of a nematogenic liquid. The surface of the particles induces wetting nematic coronas that mediate an elastic interaction. In the weak wetting regime, we obtain exact results for the interaction energy and the texture, showing that defects and biaxiality arise, although they are not topologically required. We evidence rich behaviors, including the possibility of reversible colloidal aggregation and dispersion. Complex anisotropic self-assembled phases might be formed in dense suspensions.
Galatola
P
P
LBHP, Université Paris 7-Denis Diderot, Case 7056, 2 place Jussieu, F-75251 Paris Cedex 05, France.
Fournier
J B
JB