Restudy of the Ground Vibrational State of Hydrazine Using the Generalized IAM-like Treatment for the Amino-Wagging Tunneling Motion.
The amino-wagging tunneling process in hydrazine was treated using the generalized IAM-like method developed by Hougen and Coudert, and Hamiltonian matrix elements were derived for each symmetry species in the combined group-theoretical and IAM-like treatment. Ground state microwave absorption transition data of hydrazine were least squares analyzed again in this treatment to determine axis switching angles for the amino-wagging tunneling process. Copyright 2001 Academic Press.
Pyka
Jan
J
Department of Physics, Faculty of Science, Kanazawa University, Kamuka, Kanazawa, 920-1192, Japan
Ohashi
Nobukimi
N