Preparation and characterization of biodegradable copolyester-starch based foams.
Regular (25% amylose) and waxy corn starches blended to various ratios with Eastar Bio Copolyester 14766 (EBC) were extruded into loose-fill foams using a twin screw extruder. Included in this study were two types of corn starch, three levels of EBC content, and three levels of starch moisture content. Waxy starch produced foams with greater radial expansions and lower unit and bulk densities than regular starch. Regular starch foams had lower water solubility indices (WSIs) than waxy starch foams. Foams made of both types of starch possessed similar mechanical properties. No differences were observed in compressibilities and spring indices of either waxy or regular starch foams. Higher levels of EBC addition resulted in less radial expansion and higher unit and bulk densities. Foams made with 10% EBC had higher compressibility than foams containing 25% EBC. Spring indices of single-piece samples and compressibilities and spring indices of bulk samples were not affected by the differences in the level of EBC addition. At 19% and 22% of moisture contents, foams had greater radial expansion than at 25% moisture content. Unit and bulk densities were not affected by variations in moisture content. At 22% moisture content, a lower WSI of 18.5% was obtained. At 22% moisture content, softer foams were produced. At all three levels of moisture content, no differences were detected in the spring indices.
Fang
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Industrial Agricultural Products Center, University of Nebraska, Lincoln 68583-0730, USA. qfang@unlnotes.unl.edu
Hanna
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MA
D001672:Biocompatible Materials / Q000737:chemistry / Q000302:isolation & purification*; D001673:Biodegradation, Environmental; D001709:Biotechnology; D019245:Compressive Strength; D004548:Elasticity; D008422:Materials Testing; D011091:Polyesters / Q000737:chemistry / Q000302:isolation & purification*; D012995:Solubility; D013213:Starch / Q000737:chemistry / Q000302:isolation & purification*; D014867:Water
D001672:Biocompatible Materials; D011091:Polyesters; D014867:Water; D013213:Starch