Preparation of activated carbons from corn cob catalyzed by potassium salts and subsequent gasification with CO2.
In the present study, granular activated carbons were prepared from agricultural waste corn cob by chemical activation with potassium salts and/or physical activation with CO2. Under the experimental conditions investigated, potassium hydroxide (KOH) and potassium carbonate (K2CO3) were effective activating agents for chemical activation during a ramping period of 10 degrees C/min and subsequent gasification (i.e., physical activation) at a soaking period of 800 degrees C. Large BET surface areas (>1,600 m2/g) of activated carbons were thus obtained by the combined activation. In addition, this study clearly showed that the porosity created in the acid-unwashed carbon products is substantially lower than that of acid-washed carbon products due to potassium salts left in the pore structure.
Tsai
W T
WT
Department of Environmental Engineering and Health, Chia Nan College of Pharmacy and Science, Taiwan, ROC. wwtsai@mail.chna.edu.tw
Chang
C Y
CY
Wang
S Y
SY
Chang
C F
CF
Chien
S F
SF
Sun
H F
HF
D002244:Carbon / Q000302:isolation & purification*; D002245:Carbon Dioxide; D002254:Carbonates; D002606:Charcoal / Q000302:isolation & purification; D006878:Hydroxides; D011188:Potassium; D017680:Potassium Compounds; D013499:Surface Properties; D003313:Zea mays / Q000737:chemistry*
D002254:Carbonates; D006878:Hydroxides; D017680:Potassium Compounds; D002245:Carbon Dioxide; D002606:Charcoal; D002244:Carbon; C037593:potassium carbonate; D011188:Potassium; C029943:potassium hydroxide