N-(2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy-alpha-D-galactopyranosyloxy)succinimide.
The crystal structure of the title compound, C18H24N2O11, a GalNAc mimic containing an alpha-glycosyloxysuccinimide linkage, has been determined. The pyranose ring geometry is an almost perfect (4)C(1) chair. The torsion angle of the exocyclic hydroxymethyl group is shown to be gauche-trans with respect to O1 and C4, respectively.
Renaudet
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O
LEDSS, UMR CNRS 5616, Université Joseph Fourier, BP 53, 38041 Grenoble CEDEX 9, France.
Dumy
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P
Philouze
C
C
Averbuch-Pouchot
M T
MT
D000116:Acetylgalactosamine / Q000737:chemistry; D002236:Carbohydrate Conformation; D005688:Galactosamine / Q000031:analogs & derivatives / Q000737:chemistry*; D005690:Galactose / Q000031:analogs & derivatives*; D018716:Molecular Mimicry; D015394:Molecular Structure; D013388:Succinimides / Q000737:chemistry*
C431300:N-(2-acetamido-3,4,6-tri-O-acetyl--2-deoxygalactopyranosyloxy)succinimide; D013388:Succinimides; D005688:Galactosamine; D000116:Acetylgalactosamine; D005690:Galactose