title: Silver Nitrate/Oligo(ethylene Oxide) Surfactant/Mesoporous Silica Nanocomposite Films and Monoliths.
abstract: A lyotropic, liquid crystalline (LC) phase of a silver nitrate/oligo(ethylene oxide), water, and acid mixture was used for one-pot synthesis of mesoporous silica materials in which Ag(+) ions are uniformly distributed. We established that the AgNO(3)-to-surfactant mole ratio is very important in a 50 wt% surfactant/water system to preserve the hexagonal LC phase before and after the addition of the silica source. Below a 0.6 AgNO(3)-to-surfactant mole ratio, the mixture is liquid crystalline and serves as a template for silica polymerization. However, between 0.6 and 0.8 AgNO(3)-to-surfactant mole ratios, one must control the composition of the mixture during the polymerization processes. Above a 0.8 mole ratio, Ag(+) ions undergo phase separation from the reaction mixture by complexing with the surfactant molecules. The resulting silica materials obtained from AgNO(3)/surfactant ratios above 0.8 have anisotropy but without a hexagonal mesophase. Here, we establish a AgNO(3) concentration range in which the LC phase is preserved to template the synthesis of mesoporous silica, and we discuss the structural behavior of the mixtures at AgNO(3)/surfactant mole ratios of 0.00-2.00, using POM, PXRD, FTIR, and UV-Vis absorption spectroscopy. Copyright 2001 Academic Press.
authors.affiliation: Department of Chemistry, Faculty of Science, Bilkent University, Ankara, 06533, Turkey
authors.forename: Olga
authors.initials: O
authors.lastname: Samarskaya
authors.forename: Ömer
authors.lastname: Dag Ö