A new organic-rich soil reference material certified for its EDTA- and acetic acid- extractable contents of Cd, Cr, Cu, Ni, Pb and Zn, following collaboratively tested and harmonised procedures.
There is an increasing requirement for assessment of the bioavailable metal fraction and the mobility of trace elements in soils upon disposal. One of the approaches is the use of leaching procedures, but the results obtained are operationally defined; therefore, their significance is highly dependent on the extraction protocol performed. So, for this type of study, there is a need for reference materials that allow the quality of measurements to be controlled. This paper describes the steps involved in the certification of an organic-rich soil reference material, BCR-700, for the EDTA- and acetic acid-extractable contents of some trace elements, following collaboratively tested and harmonised extraction procedures. Details are given for the preparation of the soil, homogeneity and stability testing, analytical procedures and the statistical selection of data to be included in the certification.
Pueyo
M
M
Universidad de Barcelona, Departamento de Química Analítica, Martí Franquès, 1-11, E-08028 Barcelona, Spain.
Rauret
G
G
Bacon
J R
JR
Gomez
A
A
Muntau
H
H
Quevauviller
P
P
López-Sánchez
J F
JF
D019342:Acetic Acid / Q000737:chemistry; D001682:Biological Availability; D002614:Chelating Agents / Q000737:chemistry; D004492:Edetic Acid / Q000737:chemistry; D004784:Environmental Monitoring / Q000379:methods; D009930:Organic Chemicals; D012016:Reference Values; D012989:Soil Pollutants / Q000032:analysis / Q000493:pharmacokinetics*; D014131:Trace Elements / Q000032:analysis / Q000493:pharmacokinetics*
D002614:Chelating Agents; D009930:Organic Chemicals; D012989:Soil Pollutants; D014131:Trace Elements; D004492:Edetic Acid; D019342:Acetic Acid