title: fac-Trichloro(quinolin-8-ylimido-N,N')(triphenylphosphine-P)rhenium(V).
abstract: The Re atom in [Re(C(9)H(6)N(2))Cl(3)(C(18)H(15)P)] is octahedrally coordinated by three Cl atoms in facial positions, two N atoms from 8-imidoquinoline (imq) and one P atom from triphenylphosphine. The Re-N(imido) distance [1.760 (9) and 1.772 (8) A] for imq is very short and implies double-bond character. The trans influence of the P atom is indicated. Intra- and intermolecular pi-pi interactions between the pi-rings in the complex are also observed.
authors.affiliation: Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan.
authors.forename: Y
authors.initials: Y
authors.lastname: Miyashita
authors.forename: N
authors.initials: N
authors.lastname: Mahboob
authors.forename: S
authors.initials: S
authors.lastname: Tsuboi
authors.forename: Y
authors.initials: Y
authors.lastname: Yamada
authors.forename: K
authors.initials: K
authors.lastname: Fujisawa
authors.forename: K
authors.initials: K
authors.lastname: Okamoto