title: Tetracarbonyl(diphenyldithiophosphinato-S,S')rhenium(I).
abstract: The title compound consists of [Re(C(12)H(10)PS(2))(CO)(4)] molecules in which the Re atom is octahedrally coordinated by four carbonyl groups and two dithiophosphinate S atoms. The main coordination distortion is imposed by the ligand bite angle of 78.29 (4) degrees. The bidentate coordination of the dithiophosphinate ligand involves almost equal Re-S [2.5366 (15) and 2.5535 (14) A] and P-S distances [2.0100 (19) and 2.0212 (19) A].
authors.affiliation: Departamento de Química Inorgánica, Facultade de Ciencias-Química, Universidade de Vigo, 36200-Vigo, Galicia, Spain.
authors.forename: S
authors.initials: S
authors.lastname: García Fontán
authors.forename: E
authors.initials: E
authors.lastname: Lamas Castro
authors.forename: P
authors.initials: P
authors.lastname: Rodríguez Seoane
authors.forename: E M
authors.initials: EM
authors.lastname: Vázquez-López