Structure, synthesis, and biosynthesis of fumonisin B1 and related compounds.
The absolute stereochemical description of fumonisin B1 (FB1) and presumably of its congeners is now secure. In this article I summarize studies leading to this conclusion and outline the biosynthetic and synthetic studies of FB1.
ApSimon
J W
JW
Department of Chemistry, Ottawa-Carleton Chemistry Institute, Carleton University, Ottawa, Ontario, Canada. john_apsimon@carleton.ca
D002264:Carboxylic Acids / Q000138:chemical synthesis / Q000737:chemistry* / Q000378:metabolism; D037341:Fumonisins; D008968:Molecular Conformation; D015394:Molecular Structure; D009183:Mycotoxins / Q000096:biosynthesis* / Q000138:chemical synthesis / Q000737:chemistry*
D002264:Carboxylic Acids; D037341:Fumonisins; D009183:Mycotoxins; C056934:fumonisin B2; C092631:fumonisin A1; C056933:fumonisin B1