title: Reductive cleavage of heteroaryl c-halogen bonds by iodotrimethylsilane. Facile and regioselective dechlorination of antibiotic pyrrolnitrin.
authors.affiliation: Laboratory of Medicinal Chemistry, Gifu Pharmaceutical University, 5-6-1, Mitahora-higashi, Gifu 502-8585, Japan. sako@gifu-pu.ac.jp
authors.forename: M
authors.initials: M
authors.lastname: Sako
authors.forename: T
authors.initials: T
authors.lastname: Kihara
authors.forename: K
authors.initials: K
authors.lastname: Okada
authors.forename: Y
authors.initials: Y
authors.lastname: Ohtani
authors.forename: H
authors.initials: H
authors.lastname: Kawamoto
mesh_terms: D000935:Antifungal Agents / Q000737:chemistry*; D002713:Chlorine / Q000737:chemistry; D006219:Halogens / Q000737:chemistry; D010084:Oxidation-Reduction; D011764:Pyrrolnitrin / Q000737:chemistry*; D014297:Trimethylsilyl Compounds / Q000737:chemistry
chemical_list: D000935:Antifungal Agents; D006219:Halogens; D014297:Trimethylsilyl Compounds; C027752:iodotrimethylsilane; D002713:Chlorine; D011764:Pyrrolnitrin