title: Synthesis, enantiomeric conformations, and stereodynamics of aromatic ortho-substituted disulfones.
abstract: [structure in text] Aromatic ortho-disulfone derivatives are readily accessible from diiodide precursors by Cu(I)-mediated reactions with sodium sulfinate salts. The sulfone substituents adopt C(2)-symmetric enantiomeric conformations (lambda and delta) as evidenced by X-ray structural analysis and (1)H and (31)P NMR on chiral bis(sulfonyl)veratrol derivatives and hexacoordinated tris(benzenediolato)phosphate anions. Slow dynamic conformational isomerism (DeltaG(++) > or = 19.8 kcal mol(-1)) was detected in solution.
authors.affiliation: Département de Chimie Organique, Université de Genève, quai Ernest-Ansermet 30, CH-1211 Genève 4, Switzerland. jerome.lacour@chiorg.unige.ch
authors.forename: J
authors.initials: J
authors.lastname: Lacour
authors.forename: D
authors.initials: D
authors.lastname: Monchaud
authors.forename: G
authors.initials: G
authors.lastname: Bernardinelli
authors.forename: F
authors.initials: F
authors.lastname: Favarger