Electrochemical methods for monitoring of environmental carcinogens.
The use of modern electroanalytical techniques, namely differential pulse polarography, differential pulse voltammetry on hanging mercury drop electrode or carbon paste electrode, adsorptive stripping voltammetry and high performance liquid chromatography with electrochemical detection for the determination of trace amounts of carcinogenic N-nitroso compounds, azo compounds, heterocyclic compounds, nitrated polycyclic aromatic hydrocarbons and aromatic and heterocyclic amines is discussed. Scope and limitations of these methods are described and some practical applications based on their combination with liquid-liquid or solid phase extraction are given.
Barek
J
J
Department of Analytical Chemistry, Charles University, Prague, Czech Republic. Barek@natur.cuni.cz
Cvacka
J
J
Muck
A
A
Quaiserová
V
V
Zima
J
J
D001391:Azo Compounds / Q000032:analysis; D002273:Carcinogens / Q000032:analysis*; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D004563:Electrochemistry / Q000379:methods*; D004784:Environmental Monitoring / Q000379:methods*; D009566:Nitrates / Q000032:analysis; D009603:Nitroso Compounds / Q000032:analysis; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis
D001391:Azo Compounds; D002273:Carcinogens; D009566:Nitrates; D009603:Nitroso Compounds; D011084:Polycyclic Aromatic Hydrocarbons