title: Rh(I)-catalyzed coupling cyclization of N-aryl trifluoroacetimidoyl chlorides with alkynes: one-pot synthesis of fluorinated quinolines.
abstract: [reaction: see text]. Rh(I) complexes were found to catalyze the coupling cyclization of N-aryl trifluoroacetimidoyl chlorides with alkynes to afford 2-trifluoromethylated quinolines in good yields. Various alkynes were applied to this cyclization coupling with regioselectivity.
authors.affiliation: Department of Applied Chemistry, Faculty of Engineering, Okayama University 3-1-1 Tsushimanaka, Okayama 700-8530, Japan.
authors.forename: H
authors.initials: H
authors.lastname: Amii
authors.forename: Y
authors.initials: Y
authors.lastname: Kishikawa
authors.forename: K
authors.initials: K
authors.lastname: Uneyama
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D003460:Crystallization; D007097:Imines / Q000737:chemistry*; D008956:Models, Chemical; D008958:Models, Molecular; D011804:Quinolines / Q000737:chemistry*
chemical_list: D000480:Alkynes; D002712:Chlorides; D007097:Imines; D011804:Quinolines; C037219:quinoline