Polychlorinated acetamides from the cyanobacterium Microcoleus lyngbyaceus.
Several new compounds were isolated from the organic extract of the cyanobacterium Microcoleus lyngbyaceus, and their structures were determined by spectroscopic means. Polychlorinated acetamidoalkynes and alkanes were the major metabolites. 6-Acetamido-1,1,1-trichloroundecane, a positional isomer of the naturally occurring 5-acetamido-1,1,1-trichloroundecane, was synthesized in six steps from delta-decanolactone.
Orsini
M A
MA
Carlson School of Chemistry and Biochemistry, Clark University, Worcester, Massachusetts 01610, USA.
Pannell
L K
LK
Erickson
K L
KL
D000081:Acetamides / Q000302:isolation & purification* / Q000494:pharmacology*; D019380:Anti-HIV Agents / Q000302:isolation & purification* / Q000494:pharmacology; D000458:Cyanobacteria / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D012997:Solvents; D016339:Spectrometry, Mass, Fast Atom Bombardment; D013055:Spectrophotometry, Infrared
C433896:6-acetamido-1,1,1-trichloroundecane; D000081:Acetamides; D019380:Anti-HIV Agents; D012997:Solvents