Nitrogen removal from wastewater by a catalytic oxidation method.
The ammonia-containing waste produced in industries is usually characterized by high concentration and high temperature, and is not treatable by biological methods directly. In this study, a hydrophobic Pt/SDB catalyst was first used in a trickle-bed reactor to remove ammonia from wastewater. In the reactor, both stripping and catalytic oxidation occur simultaneously. It was found that higher temperature and higher oxygen partial pressure enhanced the ammonia removal. A reaction pathway, which involves oxidizing ammonia to nitric oxide, which then further reacts with ammonia to produce nitrogen and water, was confirmed. Small amounts of by-products, nitrites and nitrates were also detected in the resultant reaction solution. These compounds came from the absorption of nitrogen oxides. Both the minimum NO2- selectivity and maximum ammonia removal were achieved when the resultant pH of treated water was near 7.5 for a feed of unbuffered ammonia solution.
Huang
T L
TL
Department of Environment and Biotechnology, Refining & Manufacturing Research Center, Chinese Petroleum Corporation, Chia-Yi, Taiwan. huang1@rmrc.gov.tw
Macinnes
J M
JM
Cliffe
K R
KR
D000641:Ammonia / Q000302:isolation & purification; D002384:Catalysis; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D009584:Nitrogen / Q000302:isolation & purification*; D010084:Oxidation-Reduction; D010984:Platinum; D011137:Polystyrenes; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D007220:Industrial Waste; D011137:Polystyrenes; D014874:Water Pollutants, Chemical; D010984:Platinum; D000641:Ammonia; C003771:Amberlite XAD-2 resin; D009584:Nitrogen