title: Direct evidence of ionic fluxes across ion-selective membranes: a scanning electrochemical microscopic and potentiometric study.
abstract: Scanning electrochemical microscopy (SECM) supplemented with potentiometric measurements was used to follow the time-dependent buildup of a steady-state diffusion layer at the aqueous-phase boundary of lead ion-selective electrodes (ISEs). Differential pulse voltammetry is adapted to SECM for probing the local concentration profiles at the sample side of solvent polymeric membranes. Major factors affecting the membrane transport-related surface concentrations were identified from SECM data and the potentiometric transients obtained under different experimental conditions (inner filling solution composition, membrane thickness, surface pretreatment). The amperometrically determined surface concentrations correlated well with the lower detection limits of the lead ion-selective electrodes.
authors.affiliation: Hungarian Academy of Sciences, Institute of General and Analytical Chemistry, Budapest University of Technology and Economics.
authors.forename: R E
authors.initials: RE
authors.lastname: Gyurcsányi
authors.forename: E
authors.initials: E
authors.lastname: Pergel
authors.forename: R
authors.initials: R
authors.lastname: Nagy
authors.forename: I
authors.initials: I
authors.lastname: Kapui
authors.forename: B T
authors.initials: BT
authors.lastname: Lan
authors.forename: K
authors.initials: K
authors.lastname: Tóth
authors.forename: I
authors.initials: I
authors.lastname: Bitter
authors.forename: E
authors.initials: E
authors.lastname: Lindner
mesh_terms: D017736:Ion-Selective Electrodes; D007476:Ionophores / Q000737:chemistry; D007854:Lead / Q000032:analysis; D008567:Membranes, Artificial; D008855:Microscopy, Electron, Scanning / Q000295:instrumentation* / Q000379:methods*; D011199:Potentiometry / Q000379:methods
chemical_list: D007476:Ionophores; D008567:Membranes, Artificial; D007854:Lead