Enantiomer separation by capillary electrophoresis utilizing noncyclic mono-, oligo- and polysaccharides as chiral selectors.
Various noncyclic mono-, oligo- and polysaccharides have been successfully used for enantiomer separation in the analytical sciences such as HPLC and capillary electrophoresis (CE). This review presents enantiomer separation by CE utilizing mainly polysaccharides as chiral additives. The operation conditions that affect the enantioselectivity are briefly discussed.
Nishi
H
H
Analytical Chemistry Department, Product Technology Development Laboratory, Tanabe Seiyaku Co., Ltd., 16-89, Kashima 3-chome, Osaka 532-8505, Yodogawa, Japan. nish-h@tanabe.co.jp
Kuwahara
Y
Y
D002240:Carbohydrate Sequence; D002809:Chondroitin Sulfates / Q000737:chemistry; D003911:Dextrans / Q000737:chemistry; D003912:Dextrins / Q000737:chemistry; D019075:Electrophoresis, Capillary / Q000379:methods*; D006493:Heparin / Q000737:chemistry; D008956:Models, Chemical; D009005:Monosaccharides / Q000737:chemistry*; D009844:Oligosaccharides / Q000737:chemistry*; D011134:Polysaccharides / Q000737:chemistry*; D013237:Stereoisomerism; D013997:Time Factors
D003911:Dextrans; D003912:Dextrins; D009005:Monosaccharides; D009844:Oligosaccharides; D011134:Polysaccharides; D006493:Heparin; D002809:Chondroitin Sulfates