Tetracarbonyl(diphenyldithiophosphinato-S,S')rhenium(I).
The title compound consists of [Re(C(12)H(10)PS(2))(CO)(4)] molecules in which the Re atom is octahedrally coordinated by four carbonyl groups and two dithiophosphinate S atoms. The main coordination distortion is imposed by the ligand bite angle of 78.29 (4) degrees. The bidentate coordination of the dithiophosphinate ligand involves almost equal Re-S [2.5366 (15) and 2.5535 (14) A] and P-S distances [2.0100 (19) and 2.0212 (19) A].
García Fontán
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Departamento de Química Inorgánica, Facultade de Ciencias-Química, Universidade de Vigo, 36200-Vigo, Galicia, Spain.
Lamas Castro
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Rodríguez Seoane
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Vázquez-López
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