Mechanistic Rationale of a Palladium-Catalyzed Allylic Substitution Polymerization-Carbon-Carbon Bond-Forming Polycondensation out of Stoichiometric Control by Cascade Bidirectional Allylation This work was supported by a Grant-in-Aid for Scientific Research (No. 12750778) from the Ministry of Education, Science, Sports, and Culture, Japan. A fellowship to K.T. from the Japan Society for the Promotion of Science for Young Scientists is gratefully acknowledged. In this contribution, the term "out of stoichiometric control" means that when reagent 2 a is used in excess, the polymerization is under stoichiometric control, whereas when 1 is in excess, the polymerization is not under stoichiometric control.
Nomura
Nobuyoshi
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Laboratory of Polymer Chemistry, Graduate School of Bioagricultural Sciences Nagoya University Nagoya 464-8601 (Japan).
Tsurugi
Ko
K
Okada
Masahiko
M