title: Rb5Mo27Se31, a novel ternary reduced molybdenum selenide containing Mo12 and Mo15 clusters.
abstract: The crystal structure of Rb5Mo27Se31, pentarubidium heptacosamolybdenum hentriacontaselenium, consists of a mixture of Mo12Se14Se6 and Mo15Se17Se6 cluster units in a 1:1 ratio. Both types of cluster are interconnected through inter-unit Mo-Se bonds. Rb+ cations occupy large voids between the different cluster units.
authors.affiliation: Laboratoire de Chimie du Solide et Inorganique Moléculaire, URA CNRS No. 6511, Université de Rennes I, Avenue du Général Leclerc, 35042 Rennes CEDEX, France.
authors.forename: S
authors.initials: S
authors.lastname: Picard
authors.forename: P
authors.initials: P
authors.lastname: Gougeon
authors.forename: M
authors.initials: M
authors.lastname: Potel