Simultaneous Analysis of the Rovibrational Levels upsilon(4)=1, 2, and 3 of HCCI and DCCI Based on Infrared Spectra.
The energy levels upsilon(4)=1, upsilon(4)=2, and upsilon(4)=3 of DCCI have been analyzed by using the fundamental nu(4)(1) (470-520 cm(-1)) and the overtone 2nu(4)(0) (955-1005 cm(-1)) bands together with the hot bands 2nu(4)(0,2)<--nu(4)(1), 3nu(4)(1,3)<--2nu(4)(0,2), and 3nu(4)(1)<--nu(4)(1). In the case of HCCI the previously studied hot bands connected to nu(4) have been completed by adding 3nu(4)(1)<--nu(4)(1) into the analysis. The various l-type resonances have been taken into account in the analyses of both the isotopomers. Furthermore, the Coriolis resonance between the close-lying nu(3) and nu(4) of DCCI has been considered. Altogether, accurate values for the molecular constants and the resonance parameters have been obtained from simultaneous analysis and they have been compared with those from separate analyses for different levels. Copyright 2001 Academic Press.
Sarkkinen
H.
H
Department of Physical Sciences, University of Oulu, Oulu, FIN-90014, Finland