title: BD monomer and elastomer production processes.
abstract: The monomer 1,3 butadiene (BD) is a product of the petrochemical industry. It is used to make several elastomers including the very high volume styrene butadiene rubber (SBR) that comprises the bulk of automobile tires. It is also used to make polybutadiene rubber that is used in parts of tires, coatings, composites and other products. The monomer can be converted to chlorobutadiene (chloroprene) and used to make polychloroprene (neoprene). BD is one of the several olefins created by cracking hydrocarbons in the presence of steam. A mixed C4 stream from the steam cracker is then sent to a BD monomer extraction unit. Modern units typically use dimethyl formamide as the extraction solvent. SBR is commonly made by the copolymerization of BD and styrene, along with various additives to control the reaction, in a water emulsion. The reaction proceeds in a continuous chain of reactors until it is 'shortstopped' by a strong reducing agent. After removing unreacted monomers from the stabilized latex, it is blended, coagulated and dewatered. The resulting dry rubber crumb is bailed, film wrapped and stored in crates. The polymerization of BD to make polybutadiene rubber can be conducted as a water suspension type polymerization similar to SBR or in a solvent system followed by solvent recovery and transfer into water suspension.
authors.affiliation: jlynch@exit109.com
authors.forename: J
authors.initials: J
authors.lastname: Lynch
mesh_terms: D002070:Butadienes / Q000138:chemical synthesis* / Q000737:chemistry*; D002617:Chemical Industry; D020724:Elastomers / Q000138:chemical synthesis* / Q000737:chemistry; D004655:Emulsions; D008722:Methods; D011108:Polymers / Q000138:chemical synthesis; D013343:Styrenes / Q000138:chemical synthesis
chemical_list: D002070:Butadienes; D020724:Elastomers; D004655:Emulsions; D011108:Polymers; D013343:Styrenes; C065815:styrene-butadiene rubber; C028834:polybutadiene; C031763:1,3-butadiene