Incorporation of stable organic radicals into cyclotriphosphazene: preparation and characterization of mono- and diradical adducts.
Stable cyclotriphosphazenes 4 and 5, incorporating one and two carbon radical centers, respectively, have been easily prepared and characterized. EPR spectroscopic studies in fluid solution at room temperature were carried out for both compounds and also for diradical 5 in frozen solvent matrixes. Spectral results are consistent with a triplet or degenerate singlet triplet ground state for 5. Reductive cyclic voltammetry shows a redox couple, being monoelectronic for 4 and bielectronic for 5.
Carriedo
G A
GA
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Oviedo 33071, Spain.
Alonso
F J
FJ
Elipe
P G
PG
Brillas
E
E
Juliá
L
L