[Characterization of Ru(bpy)(3)2+ and Ru(phen)(3)2+ complexes with silver(i) ion of ground state in propylene-carbonate].
Phosphorescent bimolecular and termolecular exciplexes of 3Ru(bpy)(3)2+ and Ru(phen)(3)2+ (bpy = 2,2'-bipyridine, and phen = 1,10-phenathroline) formed by silver ions of ground state in propylene carbonate solution are identified and characterized. Formation constants, lifetime, radiative and non-radiative decay constats of exciplexes are determined. Temperature-dependent luminescence lifetime measurements have revealed that exciplex formation causes a decrease in the energy level of the luminescent excited state.
Fodor
L
L
Veszprémi Egyetem, Altalános és Szervetlen Kémia Tanszék, H-8200 Veszprém, Egyetem u. 10.
Horváth
A
A
D003432:Cross-Linking Reagents / Q000737:chemistry*; D007700:Kinetics; D008163:Luminescent Measurements; D009942:Organometallic Compounds / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013816:Thermodynamics
D003432:Cross-Linking Reagents; D009942:Organometallic Compounds; C415768:tris(2,2'-bipyridyl)ruthenium(II); D012834:Silver