Facile synthesis of a comb-like mannohexaose: a trimer of the disaccharide repeating unit of the cell-wall mannans of Aphanoascus mephitatus and related species.
An efficient method for the preparation of a comb-like mannohexaose having alpha-(1-->6) and alpha-(1-->2) linkages has been described using 6-O-acetyl-2-O-benzoyl-3,4-di-O-benzyl-alpha-D-mannopyranosyl trichloroacetimidate as the key glycosyl donor in an 'inverse Schmidt' procedure.
Heng
L
L
Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, People's Republic of China.
Ning
J
J
Kong
F
F
D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D002473:Cell Wall / Q000737:chemistry*; D008351:Mannans / Q000138:chemical synthesis*; D008969:Molecular Sequence Data; D009844:Oligosaccharides / Q000138:chemical synthesis*; D020036:Onygenales / Q000737:chemistry*
D008351:Mannans; D009844:Oligosaccharides