title: Chemoselective cross-metathesis reaction. Application to the synthesis of the C1-C14 fragment of amphidinol 3.
abstract: [reaction: see text] An efficient synthesis of the C1-C14 fragment of amphidinol 3 is described. The synthesis is based on chemoselective cross-metathesis reactions and enantioselective allyltitanations.
authors.affiliation: Laboratoire de Chimie Organique associé au CNRS, ESPCI, 10 rue Vauquelin, 75231 - Paris Cedex 05, France.
authors.forename: S
authors.initials: S
authors.lastname: BouzBouz
authors.forename: J
authors.initials: J
authors.lastname: Cossy
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis*; D000818:Animals; D000935:Antifungal Agents / Q000138:chemical synthesis*; D004141:Dinoflagellida / Q000737:chemistry*; D015394:Molecular Structure; D011714:Pyrans / Q000138:chemical synthesis*; D013237:Stereoisomerism; D000095722:Amphidinols
chemical_list: D000475:Alkenes; D000935:Antifungal Agents; D011714:Pyrans; C438973:amphidinol 3; D000095722:Amphidinols