title: Determination of hydrogen ion by ion chromatography (IC) with sulfonated cation-exchange resin as the stationary phase and aqueous EDTA (ethylenediamine-N,N,N',N'-tetraacetic acid) solution as the mobile phase.
abstract: An ion chromatographic (IC) method has been developed for determination of hydrogen ion (H+). It is based on the use of sulfonated cation-exchange resin as stationary phase, aqueous ethylenediamine-N,N,N',N'-tetraacetic acid (dipotassium salt, EDTA-2K, written as K2H2Y) solution as mobile phase, and conductivity for detection. H+ was separated mainly by cation-exchange, but its elution was accelerated by the presence of EDTA. The order of elution for the model cations was H+ > Li+ > Na+ > NH4+ > Ca2+ > > Mg2+. A sharp and highly symmetrical peak was obtained for H+ and this was attributed to the capacity of H2Y2(2-) to receive and bind H+. H+ was detected conductiometrically and detector response (reduction in conductivity as a result of H+ +H2Y2- --> H3Y-) was linearly proportional to the concentration of H+ in the sample. The detection limit for H+ with this IC system was better than 4.7 micromol L(-1). A significant advantage of this method was the ability to separate and determine, in one step, H+ and other cations. The successful determination of H+ and other cation species in real acid-rain samples demonstrated the usefulness of this method.
authors.affiliation: Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, Japan. hu@ees.hokudai.ac.jp
authors.forename: W
authors.initials: W
authors.lastname: Hu
authors.forename: A
authors.initials: A
authors.lastname: Iles
authors.forename: K
authors.initials: K
authors.lastname: Hasebe
authors.forename: H
authors.initials: H
authors.lastname: Matsukami
authors.forename: S
authors.initials: S
authors.lastname: Cao
authors.forename: K
authors.initials: K
authors.lastname: Tanaka
mesh_terms: D015258:Acid Rain / Q000032:analysis*; D002411:Cation Exchange Resins; D002851:Chromatography, High Pressure Liquid; D002852:Chromatography, Ion Exchange / Q000379:methods*; D004492:Edetic Acid / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D013464:Sulfuric Acids / Q000737:chemistry; D014867:Water / Q000737:chemistry*
chemical_list: D015258:Acid Rain; D002411:Cation Exchange Resins; D013464:Sulfuric Acids; D014867:Water; D004492:Edetic Acid