Bis(O,O'-di-p-tolyldithiophosphato-S,S')(1,10-phenanthroline-N,N')nickel(II).
The title coordination complex, [Ni(C14H14O2PS2)2(C12H8N2)] or [Ni(pMePh-dtp)2(phen)] (phen is 1,10-phenanthroline; dtp is diaryldithiophosphate), has a non-crystallographic twofold axis of symmetry through the Ni atom and the phen moiety. Two O,O-di-p-tolyldithiophosphate (dtp) ions act as bidentate ligands. The central metal atom is coordinated by four S atoms from two dtp groups and two N atoms from the phen ligand. The title compound displays distorted octahedral geometry around the central Ni atom.
Hao
Q
Q
Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094, People's Republic of China.
Fun
H K
HK
Chantrapromma
S
S
Razak
I A
IA
Jian
F
F
Yang
X
X
Lu
L
L
Wang
X
X
D000975:Antioxidants / Q000737:chemistry*; D018360:Crystallography, X-Ray; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
D000975:Antioxidants; D009942:Organometallic Compounds; C433952:bis(O,O'-di-p-tolyldithiophosphato-S,S')(1,10-phenanthroline-N,N')nickel(II); D009532:Nickel