title: A novel two-dimensional model for colloid transport in physically and geochemically heterogeneous porous media.
abstract: A two-dimensional model for colloid transport in geochemically and physically heterogeneous porous media is presented. The model considers patchwise geochemical heterogeneity, which is suitable to describe the chemical variability of many surficial aquifers with ferric oxyhydroxide-coated porous matrix, as well as spatial variability of hydraulic conductivity, which results in heterogeneous flow field. The model is comprised of a transient fluid flow equation, a transient colloid transport equation, and an equation for the dynamics of colloid deposition and release. Numerical simulations were carried out with the model to investigate the colloid transport behavior in layered and randomly heterogeneous porous media. Results demonstrate that physical and geochemical heterogeneities markedly affect the colloid transport behavior. Layered physical or geochemical heterogeneity can result in distinct preferential flow paths of colloidal particles. Furthermore, the combined effect of layered physical and geochemical heterogeneity may result in enhanced or reduced preferential flow of colloids. Random distribution of physical heterogeneity (hydraulic conductivity) results in a random flow field and an irregularly distributed colloid concentration profile in the porous medium. Contrary to random physical heterogeneity, the effect of random patchwise geochemical heterogeneity on colloid transport behavior is not significant. It is mostly the mean value of geochemical heterogeneity rather than its distribution that governs the colloid transport behavior.
authors: Environmental Engineering Program, Department of Chemical Engineering, Yale University, P.O. Box 208286, New Haven, CT 06520-8286, USA.
authors: N
authors: N
authors: Sun
authors: M
authors: M
authors: Elimelech
authors: N Z
authors: NZ
authors: Sun
authors: J N
authors: JN
authors: Ryan
mesh_terms: D003102:Colloids / Q000737:chemistry*; D003198:Computer Simulation; D020342:Finite Element Analysis; D005618:Fresh Water / Q000737:chemistry; D008956:Models, Chemical; D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry; D014873:Water Pollutants
chemical_list: D003102:Colloids; D014873:Water Pollutants; D012822:Silicon Dioxide