Efficient metallo-ene reactions in organoaqueous phase.
[reaction: see text] The easily prepared catalyst systems PdCl(2), RhCl(2)(COD)(2), NiCl(2).6H(2)O, or Ni(COD)(2)/TPPTS have been found to form a C-C bond in organoaqueous medium. Intramolecular metallo-ene reactions have been efficiently realized. Metal selectivity has been discovered.
Michelet
V
V
Laboratoire de Synthèse Organique, E.N.S.C.P., UMR7573, 11 rue P. et M. Curie, F-75231 Paris Cedex 05, France.
Galland
J C
JC
Charruault
L
L
Savignac
M
M
Genêt
J P
JP