Synthesis of a fully functionalized protected C1-C11 fragment for the synthesis of the tedanolides.
[figure: see text] The use of several non-aldol aldol processes allows one to prepare a fully functionalized and completely protected C1-C11 fragment that should be useful for the total synthesis of the tedanolides.
Jung
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Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, USA. jung@chem.ucla.edu
Lee
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CP
D000818:Animals; D000903:Antibiotics, Antineoplastic / Q000138:chemical synthesis*; D007783:Lactones / Q000138:chemical synthesis*; D018942:Macrolides; D011161:Porifera / Q000737:chemistry
D000903:Antibiotics, Antineoplastic; D007783:Lactones; D018942:Macrolides; C119775:tedanolide