title: N-(tert-butoxycarbonyl)-N-[4-(dimethylazaniumylidene)-1,4-dihydropyridin-1-ylsulfonyl]azanide: a new sulfamyolating agent. Structure and reactivity toward amines.
abstract: [structure: see text] Synthesis, structure, and reactivity toward amines of the new sulfamoylating reagent 2 are described. Compound 2 allowed sulfamoylation of amines under very mild conditions to give sulfamide derivatives in good yields.
authors: Laboratoire de Chimie Biomoléculaire, UMR 5032, Université Montpellier II, Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex, France. winumj@crit.univ-montp2.fr
authors: J Y
authors: JY
authors: Winum
authors: L
authors: L
authors: Toupet
authors: V
authors: V
authors: Barragan
authors: G
authors: G
authors: Dewynter
authors: J L
authors: JL
authors: Montero
mesh_terms: D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D004095:Dihydropyridines / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D015394:Molecular Structure; D013329:Structure-Activity Relationship; D013449:Sulfonamides / Q000737:chemistry*
chemical_list: D000588:Amines; D004095:Dihydropyridines; C432705:N-(tert-butoxycarbonyl)-N-(4-(dimethylazaniumylidene)-1,4-dihydropyridin-1-ylsulfonyl)azanide; D013449:Sulfonamides