Light-scattering spectra of supercooled molecular liquids.
The light-scattering spectra of molecular liquids are derived within a generalized hydrodynamics. The wave-vector and scattering-angle dependencies are given in the most general case and the change of the spectral features from liquid to solidlike is discussed without phenomenological model assumptions for (general) dielectric systems without long-ranged order. Exact microscopic expressions are derived for the frequency dependent transport kernels, generalized thermodynamic derivatives, and the background spectra.
Franosch
T
T
Physik-Department, Technische Universität München, D-85747 Garching, Germany.
Fuchs
M
M
Latz
A
A