title: Enantiopure 2,3-dihydro-4-pyridones as synthetic intermediates: a concise asymmetric synthesis of (+)-allopumiliotoxin 267A.
abstract: [figure: see text] A concise asymmetric synthesis of (+)-allopumillotoxin 267A has been accomplished using an enantiopure dihydropyridone building block. The synthesis is highly stereoselective and requires 10 steps from readily available material.
authors: Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA. daniel_comins@ncsu.edu
authors: D L
authors: DL
authors: Comins
authors: S
authors: S
authors: Huang
authors: C L
authors: CL
authors: McArdle
authors: C L
authors: CL
authors: Ingalls
mesh_terms: D000470:Alkaloids / Q000138:chemical synthesis*; D000818:Animals; D001001:Anura; D007212:Indolizines; D010880:Piperidines; D011728:Pyridones / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000470:Alkaloids; D007212:Indolizines; D010880:Piperidines; D011728:Pyridones; C431592:allopumiliotoxin 267A; C035482:pumiliotoxin A