Milolides, new briarane diterpenoids from the western Pacific octocoral Briareum stechei.
Eleven new briarane-type diterpene lactones, designated milolides (1--8, 10--12), together with four known diterpene lactones (9, 13--15), were isolated from the Micronesian octocoral Briareum stechei collected at Yap, Federated States of Micronesia. One aspect of the stereochemistry of one of the known compounds, solenolide C (9), is revised. Structures of the new compounds were determined from spectral data.
Kwak
J H
JH
Department of Chemistry and Biochemistry, University of Oklahoma, Norman, Oklahoma 73019, USA.
Schmitz
F J
FJ
Williams
G C
GC
D000818:Animals; D003063:Cnidaria / Q000737:chemistry*; D004224:Diterpenes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008849:Micronesia; D008968:Molecular Conformation; D013055:Spectrophotometry, Infrared
D004224:Diterpenes