title: Palladium(II) acetate catalyzed stereoselective C-glycosidation of peracetylated glycals with arylboronic acids.
abstract: [reaction: see text] Addition of a variety of arylboronic acids to peracetylated glycals takes place in the presence of a catalytic amount of Pd(OAc)(2). The reaction involves the syn addition of a sigma-aryl-Pd complex to the glycal double bond followed by anti elimination of Pd(OAc)(2) to provide a carbon-Ferrier type product. This method provides a practical and convenient stereoselective synthesis of C-arylglycosides.
authors: MCR Research Inc., York University, 4700 Keele Street, Toronto, Ontario, Canada M3J 1P3.
authors: J
authors: J
authors: Ramnauth
authors: O
authors: O
authors: Poulin
authors: S
authors: S
authors: Rakhit
authors: S P
authors: SP
authors: Maddaford