Characterization of activated carbons prepared from sugarcane bagasse by ZnCl2 activation.
Activated carbons were prepared from the agricultural waste of sugarcane bagasse by the chemical activation with zinc chloride (ZnCl2) at the activation temperature of 500 degrees C with soaking time of 0.5 hour. The influence of activation parameters on the final carbon products was examined by varying the impregnation ratio (i.e., mass ratio of added ZnCl2 to bagasse) and bagasse size. The physical properties of carbon products were characterized by nitrogen adsorption/desorption isotherms (at 77 K) and helium displacement method. The surface area and pore volume of carbons were thus obtained by the BET equation and t-plot method. Also, the particle density and porosity of carbons were estimated by the total pore volume and true density. The increases of the values of surface area and pore volume are approximately proportional to the impregnation ratio. The microporous carbon product with the BET surface area of 905 m2/g and total pore volume of 0.44 cm3/g was obtained in the present study. Further, the adsorption isotherms of two acid dyes from aqueous solutions onto the carbon products were performed at 30 degrees C. The results show that the adsorption isotherms of acid dyes with high molecular weight or large molecular size on the microporous adsorbents of activated carbons are plateau forms, indicating multilayer adsorptions, which may be attributed to the steric hindrance of the adsorbate molecules.
Tsai
W T
WT
Department of Environmental Engineering and Health, Chia Nan University of Pharmacy and Science, Tainan, Taiwan. wwtsai@mail.chna.edu.tw
Chang
C Y
CY
Lin
M C
MC
Chien
S F
SF
Sun
H F
HF
Hsieh
M F
MF
D000327:Adsorption; D000465:Algorithms; D001557:Benzenesulfonates; D002244:Carbon / Q000737:chemistry* / Q000378:metabolism; D002482:Cellulose / Q000378:metabolism; D002606:Charcoal / Q000737:chemistry; D002712:Chlorides / Q000737:chemistry*; D004396:Coloring Agents; D007700:Kinetics; D010316:Particle Size; D006109:Poaceae / Q000378:metabolism; D016062:Porosity; D018505:Waste Management / Q000379:methods; D017967:Zinc Compounds / Q000737:chemistry*
D001557:Benzenesulfonates; D002712:Chlorides; D004396:Coloring Agents; D017967:Zinc Compounds; D002606:Charcoal; D002244:Carbon; C016837:zinc chloride; D002482:Cellulose; C027433:bagasse; C006796:brilliant blue