Reaction of D-glycals with azidotrimethylsilane.
The treatment of 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabino-hex-1-enitol with azidotrimethylsilane by the aid of a catalytic amount of Yb(OTf)(3) afforded 2,4,6-tri-O-acetyl-2,3-dideoxy-alpha-D-erythro-hex-2-enopyranosyl azide in high yield.
Kawabata
H
H
Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan.
Kubo
S
S
Hayashi
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M
D001089:Arabinose / Q000031:analogs & derivatives / Q000737:chemistry*; D001386:Azides / Q000737:chemistry*; D015394:Molecular Structure; D009005:Monosaccharides / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D015018:Ytterbium / Q000737:chemistry
C438545:2,3,4,6-tetra-O-acetyl-1,5-anhydro-arabino-hex-1-enitol; C438546:2,4,6-tri-O-acetyl-2,3-dideoxy-erythro-hex-2-enopyranosyl azide; D001386:Azides; D009005:Monosaccharides; D012821:Silanes; C438544:azidotrimethylsilane; D001089:Arabinose; D015018:Ytterbium