A pseudo-trigonal bipyramidally coordinated Pt atom in dicarbonylbis(octacarbonyl-mu-dicyclohexylphosphidodirhenio)platinum(II).
In the title compound, [PtRe4(C12H22P)2(CO)18] or [(mu-PCy2)(CO)8Re2]2Pt(CO)2 (Cy is cyclohexyl), two phosphido-bridged dirhenium groups are linked by a Pt(CO)2 unit and show different bonding patterns for stereochemical reasons. The Re--Re distances are 3.2620 (15) and 3.0739 (15) A, and the Pt--Re distances are 2.9165 (12), 2.9025 (15) and 2.8548 (13) A.
Haupt
H J
HJ
Fachbereich Chemie und Chemietechnik, Universität Paderborn, Warburgerstrasse 100, D-33098 Paderborn, Germany.
Flörke
U
U
Klose
S
S
D018360:Crystallography, X-Ray / Q000379:methods; D008958:Models, Molecular; D008968:Molecular Conformation; D009944:Organoplatinum Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D009944:Organoplatinum Compounds; C435313:dicarbonylbis(octacarbonyl-mu-dicyclohexylphosphidodirhenio)platinum(II)