title: Reactions of electron-deficient alkynes and allenes under phosphine catalysis.
abstract: The development of some new synthetic reactions derived from nucleophilic addition of phosphines to electron-deficient carbon-carbon triple bonds is described. These reactions show that the phosphine plays the role of a nucleophile as well as an excellent leaving group. The central problem is to generate a 1,3-dipole from alkynoates or allenoates (2,3-butadienoates) by interaction with various phosphines. This study illuminates the unusual phenomena and shows how this understanding allows control of the reaction.
authors.affiliation: Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China.
authors.forename: X
authors.initials: X
authors.lastname: Lu
authors.forename: C
authors.initials: C
authors.lastname: Zhang
authors.forename: Z
authors.initials: Z
authors.lastname: Xu