title: Adsorption-desorption behaviour of flufenacet in five different soils of India.
abstract: Adsorption-desorption of the herbicide flufenacet (FOE 5043) has been studied in five soils from different locations in India (Delhi, Ranchi, Nagpur, Kerala and Assam) varying in their physicochemical properties. The organic matter (OM) content varied from 0.072 to 0.864%, clay content from 2.5 to 43.7% and pH from 4.45 to 8.35. The adsorption studies were carried out using a batch equilibration technique. Ten grams of soil were equilibrated with 20 ml of aqueous 0.01 M CaCl2 solution containing different concentrations (0-30 mg litre-1) of flufenacet. After equilibration, an aliquot of supernatant was taken out for analysis. During desorption, the amount withdrawn for analysis was replenished with fresh 0.01 M CaCl2 solution and further equilibrated. Desorption studies were carried out with the 30 mg litre-1 concentration of flufenacet only. The adsorption studies revealed that there was moderate to high adsorption of flufenacet considering the comparatively low organic carbon content in the five test soils. Average Kd values ranged from 0.77 to 4.52 and Freundlich KF values from 0.76 to 4.39. The highest adsorption was observed in Kerala soil (OM 0.786%; clay 25%; pH 4.45) followed by Ranchi, Nagpur and Delhi soils, and the lowest in Assam soil (OM 0.553%; clay 2.5%; pH 6.87). The trend in adsorption could be attributed to the chemical nature of flufenacet and the physicochemical properties of the soil such as pH, OM and clay contents. OM and clay contents were positively correlated whereas pH was negatively correlated. Soils having low pH, high OM and high clay contents showed higher adsorption. Desorption studies revealed that there was a hysteresis effect in all the soils. Hysteresis coefficient values (ratio of n(ad) and n(des)) varied from 0.09 to 0.45. The study implies that, because of its moderate to high adsorption, flufenacet is likely to persist in soil for some time. However, the possibility of its movement by leaching or surface run off is less.
authors.affiliation: Division of Agricultural Chemicals, Indian Agricultural Research Institute, New Delhi-110 012, India.
authors.forename: V T
authors.initials: VT
authors.lastname: Gajbhiye
authors.forename: S
authors.initials: S
authors.lastname: Gupta
mesh_terms: D000081:Acetamides / Q000737:chemistry / Q000378:metabolism*; D000327:Adsorption; D006540:Herbicides / Q000737:chemistry / Q000378:metabolism*; D006863:Hydrogen-Ion Concentration; D007194:India; D007474:Ion Exchange; D008954:Models, Biological; D012044:Regression Analysis; D012987:Soil / Q000032:analysis; D012989:Soil Pollutants / Q000032:analysis / Q000378:metabolism*; D013830:Thiadiazoles / Q000737:chemistry / Q000378:metabolism*
chemical_list: D000081:Acetamides; D006540:Herbicides; D012987:Soil; D012989:Soil Pollutants; D013830:Thiadiazoles; C094127:FOE 5043