title: Reaction of D-glycals with azidotrimethylsilane.
abstract: The treatment of 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabino-hex-1-enitol with azidotrimethylsilane by the aid of a catalytic amount of Yb(OTf)(3) afforded 2,4,6-tri-O-acetyl-2,3-dideoxy-alpha-D-erythro-hex-2-enopyranosyl azide in high yield.
authors.affiliation: Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan.
authors.forename: H
authors.initials: H
authors.lastname: Kawabata
authors.forename: S
authors.initials: S
authors.lastname: Kubo
authors.forename: M
authors.initials: M
authors.lastname: Hayashi
mesh_terms: D001089:Arabinose / Q000031:analogs & derivatives / Q000737:chemistry*; D001386:Azides / Q000737:chemistry*; D015394:Molecular Structure; D009005:Monosaccharides / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D015018:Ytterbium / Q000737:chemistry
chemical_list: C438545:2,3,4,6-tetra-O-acetyl-1,5-anhydro-arabino-hex-1-enitol; C438546:2,4,6-tri-O-acetyl-2,3-dideoxy-erythro-hex-2-enopyranosyl azide; D001386:Azides; D009005:Monosaccharides; D012821:Silanes; C438544:azidotrimethylsilane; D001089:Arabinose; D015018:Ytterbium