title: Reactivity of stable trifluoroacetaldehyde hemiaminals. 1. An unexpected reaction with enolizable carbonyl compounds.
abstract: In the presence of enolizable carbonyl compounds, hemiaminals of fluoral and related polyfluoroaldehydes behave as equivalents of fluoroalkyl iminium compounds and provide beta-polyfluoroalkyl beta-dialkylamino ketones, which are easily transformed, under acidic conditions, into beta-polyfluoroalkylenones.
authors.affiliation: Laboratoire SERCOF (UMR CNRS 5622), Université Claude Bernard - Lyon1, 43 Bd du 11 novembre 1918, 69622 Villeurbanne, France.
authors.forename: G
authors.initials: G
authors.lastname: Blond
authors.forename: T
authors.initials: T
authors.lastname: Billard
authors.forename: B R
authors.initials: BR
authors.lastname: Langlois