Intramolecular cyclizations of imines bearing the 2-(thiomethyl)-3-trimethylsilyl-1-propenyl terminator. An efficient new procedure for the stereocontrolled synthesis of functionalized pyrrolidine derivatives.
Duncan
D
D
Department of Chemistry and Biochemistry, Montana State University, Bozeman, Montana 59717, USA.
Livinghouse
T
T
D003500:Cyclization; D007097:Imines / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D011759:Pyrrolidines / Q000138:chemical synthesis*; D014025:Titanium / Q000737:chemistry; D014297:Trimethylsilyl Compounds
C433404:2-(thiomethyl)-3-trimethylsilyl-1-propenyl; D007097:Imines; D007202:Indicators and Reagents; D011759:Pyrrolidines; D014297:Trimethylsilyl Compounds; D014025:Titanium