Crossover behavior for long reptating polymers.
The Rubinstein-Duke model for polymer reptation is analyzed by means of density matrix renormalization techniques. It is found that the crossover in the scaling behavior of polymer renewal time (or viscosity) arises from the competing effect of the contribution due to tube length fluctuations and higher-order corrections, which are of opposite sign. Experiments which ought to emphasize both contributions are suggested. The exponent describing the subleading scaling behavior of the diffusion coefficient is also investigated.
Carlon
E
E
INFM, Dipartimento di Fisica, Università di Padova, I-35131 Padova, Italy.
Drzewiński
A
A
van Leeuwen
J M
JM