title: Enantiomer separation of hydrocarbons in preparation for ROSETTA's "chirality-experiment".
abstract: Until now the favored method for separating racemic pairs of underivatized alcohols, diols, and phenylsubstituted amines has been gas chromatography on cyclodextrin phases. However, certain enantiomers of saturated chiral hydrocarbons could not be resolved in this way because they lack the functional groups necessary to undergo "intensive" diastereomeric interactions with the cyclodextrins. The present study describes a gas-chromatographic technique for resolution of saturated aliphatic hydrocarbons into their enantiomers and presents a brief discussion of the possible applications. The (enantiomer) separations were performed in preparation for the Cometary Sampling and Composition Experiment on board the cometary lander RoLand, part of ESA's cornerstone mission ROSETTA. This experiment has been designed to investigate the hypotheses that biomolecular asymmetry has an interstellar origin and to separate and identify a wide range of organic enantiomers in situ on the surface of a comet's nucleus.
authors.affiliation: University of Bremen, Dept. Phys. Chemistry, Bremen, Germany. mhenrich@cnrs-orleans.fr
authors.forename: U J
authors.initials: UJ
authors.lastname: Meierhenrich
authors.forename: W H
authors.initials: WH
authors.lastname: Thiemann
authors.forename: F
authors.initials: F
authors.lastname: Goesmann
authors.forename: R
authors.initials: R
authors.lastname: Roll
authors.forename: H
authors.initials: H
authors.lastname: Rosenbauer
mesh_terms: D000473:Alkanes / Q000737:chemistry / Q000302:isolation & purification*; D002849:Chromatography, Gas / Q000379:methods; D006586:Hexanes / Q000302:isolation & purification; D019110:Meteoroids; D008968:Molecular Conformation; D013237:Stereoisomerism
chemical_list: D000473:Alkanes; D006586:Hexanes