Development of a reference material for routine performance monitoring of methods measuring polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans and dioxin-like polychlorinated biphenyls.
Matrix-matched environmental certified reference materials (CRMs) are one of the most useful tools to validate analytical methods, assess analytical laboratory performance and to assist in the resolution of data conflicts between laboratories. This paper describes the development of a lake sediment as a CRM for polychorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and dioxin-like polychlorinated biphenyls (DLPCBs). The presence of DLPCBs in the environment is of increased concern and analytical methods are being developed internationally for monitoring DLPCBs in the environment. This paper also reports the results of an international interlaboratory study involving thirty-five laboratories from seventeen countries, conducted to characterize and validate levels of a sediment reference material for PCDDs, PCDFs and DLPCBs.
Selliah
S S
SS
Ontario Ministry of the Environment, Laboratory Services Branch, Toronto, Canada. sathi.selliah@ene.gov.on.ca
Cussion
S
S
MacPherson
K A
KA
Reiner
E J
EJ
Toner
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D001572:Benzofurans / Q000032:analysis / Q000592:standards*; D000072338:Dibenzofurans, Polychlorinated; D004784:Environmental Monitoring / Q000379:methods / Q000592:standards*; D004785:Environmental Pollutants / Q000032:analysis / Q000592:standards*; D008401:Gas Chromatography-Mass Spectrometry; D019015:Geologic Sediments; D011078:Polychlorinated Biphenyls / Q000032:analysis / Q000592:standards*; D000072317:Polychlorinated Dibenzodioxins / Q000031:analogs & derivatives* / Q000032:analysis / Q000592:standards*; D012015:Reference Standards; D012989:Soil Pollutants / Q000032:analysis / Q000592:standards
D001572:Benzofurans; D000072338:Dibenzofurans, Polychlorinated; D004785:Environmental Pollutants; D000072317:Polychlorinated Dibenzodioxins; D012989:Soil Pollutants; D011078:Polychlorinated Biphenyls