title: Capillary electrophoresis for measuring major and trace anions in thermal water and condensed-steam samples from hydrothermal springs and fumaroles.
abstract: A new application of capillary electrophoresis for measuring major and trace anions in thermal water and condensed-steam samples is presented. Ten fluid samples were collected from hydrothermal springs and fumaroles located in a volcanic zone of Deception Island, Antarctica. Anion separation was achieved in less than 6 min using indirect UV detection at 254 nm with a negative power supply (-15 kV). The electrolyte consisted of 4.7 mM sodium chromate, 4.0 mM electroosmotic flow modifier (OFM) hydroxide, 10 mM 2-(N-cyclohexylamino)ethanesulfonic acid and 0.1 mM calcium gluconate (pH 9.1). Major anions (Cl-, SO4(2), PO4H2+, and CO3H-) were measured using hydrostatic injection (10 cm for 30 s) at 25 degrees C. Trace amounts of anions (F-, Br-, and NO3-) were better determined by electromigration injection (4 kV, 10 s) at 15 degrees C. Good reproducibility of the migration times (<0.72% RSD), a satisfactory linear response and accuracy as well as acceptable detection limits were successfully obtained.
authors.affiliation: Centro de Investigación en Energía, Universidad Nacional Autónoma de Mexico, Temixco, Mor. esg@mazatl.cie.unam.mx
authors.forename: E
authors.initials: E
authors.lastname: Santoyo
authors.forename: R
authors.initials: R
authors.lastname: García
authors.forename: R
authors.initials: R
authors.lastname: Abella
authors.forename: A
authors.initials: A
authors.lastname: Aparicio
authors.forename: S P
authors.initials: SP
authors.lastname: Verma
mesh_terms: D000838:Anions / Q000032:analysis*; D019075:Electrophoresis, Capillary / Q000379:methods*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D013056:Spectrophotometry, Ultraviolet; D014867:Water / Q000737:chemistry*
chemical_list: D000838:Anions; D014867:Water