title: Acetyl coenzyme A synthesis from unnatural methylated corrinoids: requirement for "base-off" coordination at cobalt.
authors.affiliation: Department of Biochemistry, Beadle Center, University of Nebraska, Lincoln, Nebraska 68588, USA.
authors.forename: J
authors.initials: J
authors.lastname: Seravalli
authors.forename: K L
authors.initials: KL
authors.lastname: Brown
authors.forename: S W
authors.initials: SW
authors.lastname: Ragsdale
mesh_terms: D000106:Acetate-CoA Ligase / Q000378:metabolism*; D000105:Acetyl Coenzyme A / Q000096:biosynthesis*; D001426:Bacterial Proteins / Q000378:metabolism*; D003035:Cobalt / Q000378:metabolism*; D003038:Cobamides / Q000378:metabolism; D045728:Corrinoids; D019605:Euryarchaeota / Q000378:metabolism; D007506:Iron-Sulfur Proteins / Q000378:metabolism*; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000378:metabolism*
chemical_list: D001426:Bacterial Proteins; C080269:C-Fe-SP protein, Moorella thermoacetica; D003038:Cobamides; D045728:Corrinoids; D007506:Iron-Sulfur Proteins; D011166:Porphyrins; C017142:cobinamide; D003035:Cobalt; D000105:Acetyl Coenzyme A; D000106:Acetate-CoA Ligase