title: Use of deactivated fused-silica capillary precolumns in pesticide analysis by gas chromatography with electron-capture detection.
abstract: The advantages and disadvantages of coupling a retention gap of fused-silica between the injection port and the chromatographic column are discussed. The influence on the peak width and height of several factors such as the solvent (n-hexane, acetone, ethyl acetate and methanol), the gap (length, inner diameter, deactivation mode), the injection volume and the pesticide concentration has been examined. Those factors have very different incidences so, it is not possible to extract a general recommendation about the use of gaps. For this reason, checking its viability in each particular case is more advisable.
authors.affiliation: Department of Analytical Chemistry, Faculty of Sciences, University of Valladolid, Spain.
authors.forename: J J
authors.initials: JJ
authors.lastname: Jiménez
authors.forename: J L
authors.initials: JL
authors.lastname: Bernal
authors.forename: M J
authors.initials: MJ
authors.lastname: del Nozal
authors.forename: L
authors.initials: L
authors.lastname: Toribio
authors.forename: A L
authors.initials: AL
authors.lastname: Mayorga
mesh_terms: D002849:Chromatography, Gas / Q000379:methods*; D010575:Pesticides / Q000032:analysis*
chemical_list: D010575:Pesticides