Unusual temperature-dependent diastereoselectivity in the [2 + 2] photocycloaddition (Paternò-Büchi reaction) of benzophenone to cis- and trans-cyclooctene through conformational control.
Adam
W
W
Institute of Organic Chemistry, University of Würzburg Am Hubland, D-97074 Würzburg, Germany. adam@chemie.uni-wuerzburg.de
Stegmann
V R
VR
Weinkötz
S
S
D001577:Benzophenones / Q000737:chemistry*; D008968:Molecular Conformation; D013237:Stereoisomerism; D013696:Temperature
D001577:Benzophenones; C047723:benzophenone