A three-dimensional inorganic/organic hybrid material, [Ni(4,4'-bipy)3-(H2O)2V4O12]*2.5H2O.
The title compound, poly[[[diaqua(mu-4,4'-bipyridyl)dinickel(II)]-bis(mu-4,4'-bipyridyl)-di-mu-hexaoxodivanadate(2-)] 2.5-hydrate], [Ni2(V2O6)2(C10H8N2)3(H2O)2]*2.5H2O, has been prepared hydrothermally and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The structure consists of [V2O6], [Ni(4,4'-bipy)4O2] and [Ni(H2O)2(4,4'-bipy)2O2] polyhedra, and water of crystallization. The Ni atoms and one bipyridyl group lie on centres of symmetry.
Yang
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Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.
Hu
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Naruke
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Yamase
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