title: Dichloro(d-methionine-n,s)platinum(ii) at 130 k.
abstract: The asymmetric unit of the title compound, [PtCl2(C5H11NO2S)], a D-methionine derivative, contains two molecules with opposite chirality at the S atoms. The amino acid acts as a bidentate ligand and coordinates simultaneously through the N (amino) and S (thioether) atoms. The molecules are packed in pairs which are connected through two hydrogen bonds between the protonated carboxyl groups, with O.O distances of 2.633 (10) and 2.663 (12) A.
authors.affiliation: Departament de Quimica Inorganica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain.
authors.forename: J
authors.initials: J
authors.lastname: Llorca
authors.forename: E
authors.initials: E
authors.lastname: Molins
authors.forename: E
authors.initials: E
authors.lastname: Espinosa
authors.forename: I
authors.initials: I
authors.lastname: Mata
authors.forename: C
authors.initials: C
authors.lastname: Miravitlles
authors.forename: G
authors.initials: G
authors.lastname: Cervantes
authors.forename: A
authors.initials: A
authors.lastname: Caubet
authors.forename: V
authors.initials: V
authors.lastname: Moreno
mesh_terms: D018360:Crystallography, X-Ray / Q000379:methods; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D009944:Organoplatinum Compounds / Q000737:chemistry*
chemical_list: D009944:Organoplatinum Compounds; C435313:dicarbonylbis(octacarbonyl-mu-dicyclohexylphosphidodirhenio)platinum(II); C435312:dichloro(d-methionine-n,s)platinum(II)