Aggregation Behavior of Nonionic Surfactants Synperonic A7 and A50 in Aqueous Solution.
The aggregation behavior of Synperonic A7 and A50, fatty alcohol ethoxylate nonionic surfactants (C(m)E(n)) with mean polyoxyethylene chain lengths of 7 and 50, respectively, was investigated in aqueous solution by means of surface tension, laser light scattering, steady-state fluorescence, and fluorescence quenching experiments. Surface tension measurements at room temperature indicate that the critical micelle concentration of A7 is 0.1 g/L (0.22 mM) and that of A50 is 0.17 g/L (0.07 mM). Static light scattering measurements reveal that the averaged aggregation number of A7 in water is 417 and that of A50 is 23. When solutions of A7 were allowed to age over a period of months at room temperature, the micelle M(w) and hydrodynamic radius increased. The aggregation numbers found from fluorescence quenching measurements, using excimer formation from 1-ethylpyrene as a probe, were about 300 for freshly prepared solutions of A7 and about 40 for A50. We also found that the presence of air has a strong effect on the data obtained from the fluorescence quenching measurements. Copyright 2001 Academic Press.
Li
Mei
M
Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, M5S 3H6, Canada
Rharbi
Yahya
Y
Winnik
Mitchell A.
MA
Hahn
Kenneth G.
KG