title: Analysis of fountain solutions for anionic components, including alkylbenzenesulfonates, carboxylates and polyphosphates, by a combination of ion-exchange and ion-exclusion chromatography and inductively coupled plasma atomic emission spectrometry.
abstract: A method for the quantitative determination of the major anionic constituents of fountain solutions, typically mono-, di- and hydroxycarboxylates, alkylbenzenesulfonates, and inorganic anions, including orthophosphate and polyphosphates, is presented here for the first time. The analytical problems arising from extensive co-elution of many of these analytes on an ion-exchange column have been resolved through a combination of (i) careful selection of the concentration gradient of the sodium hydroxide eluent; (ii) parallel analysis by ion-exclusion chromatography; and (iii) determination of total phosphorus by inductively coupled plasma atomic emission spectrometry.
authors.affiliation: University of Manchester, Department of Earth Sciences, UK. alastair.bewsher@man.ac.uk
authors.forename: A D
authors.initials: AD
authors.lastname: Bewsher
authors.forename: D A
authors.initials: DA
authors.lastname: Polya
authors.forename: P R
authors.initials: PR
authors.lastname: Lythgoe
authors.forename: I M
authors.initials: IM
authors.lastname: Bruckshaw
authors.forename: D A
authors.initials: DA
authors.lastname: Mannin
mesh_terms: D000838:Anions; D001557:Benzenesulfonates / Q000032:analysis*; D002264:Carboxylic Acids / Q000032:analysis*; D002852:Chromatography, Ion Exchange / Q000379:methods*; D011122:Polyphosphates / Q000032:analysis*; D015203:Reproducibility of Results; D012996:Solutions; D013054:Spectrophotometry, Atomic / Q000379:methods*
chemical_list: D000838:Anions; D001557:Benzenesulfonates; D002264:Carboxylic Acids; D011122:Polyphosphates; D012996:Solutions