Method for determining novolac glycidyl ether (NOGE) and its chlorohydrins in oily canned foods.
In order to be analysed, NOGE components with epoxy groups must be separated from polar food material to prevent losses through uncontrolled reactions. Samples are homogenized minimally and extracted into a phase of minimized polarity. The NOGE components are then separated from the oil by extraction into acetonitrile and analysed by RPLC with fluorescence detection. Hydrolysis of the epoxy, and chlorohydroxy functions to diols may help the analysis. Application and limitations of the method are illustrated by examples. Detection limits vary widely, depending on interfering food components, but legal limits below 1 mg/kg can hardly be reliably enforced.
Brem
S
S
Official Food Control Authority of the Canton of Zurich, Switzerland.
Grob
K
K
Biedermann
M
M
D000818:Animals; D002728:Chlorohydrins / Q000032:analysis*; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D004852:Epoxy Compounds / Q000032:analysis*; D005519:Food Preservation; D006868:Hydrolysis; D008460:Meat / Q000032:analysis*; D010647:Phenyl Ethers / Q000032:analysis*; D014413:Tuna; D003313:Zea mays / Q000737:chemistry*
D002728:Chlorohydrins; D004852:Epoxy Compounds; D010647:Phenyl Ethers; C420695:novolac glycidyl ether