p-methyltetrahomodioxacalix[4]arene.
The title compound, 7,13,21,27-tetramethyl-3,17-dioxapentacyclo[23.3.1.1(5,9).1(11,15).1(9,23)]ditriaconta-1(29),5,7,9(30),11(31),-12,14,19(32),20,22,25,27-dodecaene-29,30,31,32-tetraol, C34H36O6, assumes in the solid state a very distorted cone-like conformation stabilized by intramolecular simple and bifurcated hydrogen bonds involving both phenolic and ether O atoms. One part of the molecule, comprising an ether link, is included in the cavity of an adjacent calixarene related by a screw axis, giving rise to a one-dimensional self-inclusion polymer.
Thuéry
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CEA/Saclay, SCM, CNRS URA 331, Bâtiment 125, 91191 Gif-sur-Yvette, France. thuery@drecam.cea.fr
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Vicens
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Masci
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