Dichloro(d-methionine-n,s)platinum(ii) at 130 k.
The asymmetric unit of the title compound, [PtCl2(C5H11NO2S)], a D-methionine derivative, contains two molecules with opposite chirality at the S atoms. The amino acid acts as a bidentate ligand and coordinates simultaneously through the N (amino) and S (thioether) atoms. The molecules are packed in pairs which are connected through two hydrogen bonds between the protonated carboxyl groups, with O.O distances of 2.633 (10) and 2.663 (12) A.
Llorca
J
J
Departament de Quimica Inorganica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain.
Molins
E
E
Espinosa
E
E
Mata
I
I
Miravitlles
C
C
Cervantes
G
G
Caubet
A
A
Moreno
V
V
D018360:Crystallography, X-Ray / Q000379:methods; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D009944:Organoplatinum Compounds / Q000737:chemistry*
D009944:Organoplatinum Compounds; C435313:dicarbonylbis(octacarbonyl-mu-dicyclohexylphosphidodirhenio)platinum(II); C435312:dichloro(d-methionine-n,s)platinum(II)