A cyclic peroxide of clerodenoic acid from the Taiwanese liverwort Schistochila acuminata.
Two minor diterpenoids, 15(16)-peroxy-3, 13-clerodadien-18-oic acid (4) and totarol (7), were isolated from the liverwort Schistochila acuminata. The former is a further oxidized cyclic peroxide from the major component. The latter is a rearranged abietane alcohol which skeleton was found in liverworts for the first time.
Wu
C L
CL
Department of Chemistry, Tamkang University, Tamsui, Taiwan. clwu@mail.tku.edu.tw
Jong
J R
JR
D045784:Abietanes; D019068:Bryopsida / Q000737:chemistry*; D004224:Diterpenes / Q000737:chemistry / Q000302:isolation & purification*; D008401:Gas Chromatography-Mass Spectrometry; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D010545:Peroxides / Q000737:chemistry / Q000302:isolation & purification*; D013055:Spectrophotometry, Infrared; D013237:Stereoisomerism; D013624:Taiwan
C441664:15(16)-peroxy-3,13-clerodadien-18-oic acid; D045784:Abietanes; D004224:Diterpenes; D010545:Peroxides; C441663:clerodenoic acid; C078548:totarol