Solid-phase organometallic synthesis.
A solid-phase synthesis approach for a class of molybdenum carbonyl complexes has been developed. The system can be used to perform metal-complexation, ligand substitution reactions and oxidative eliminations on the solid phase and to cleave the final complexes under mild and selective conditions. Comparison is made to corresponding soluble complexes and liquid-phase reactions.
Heinze
K
K
Anorganisch-chemisches Institut der Universität Heidelberg, Germany. katja@sun0.urz.uni-heidelberg.de
D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011108:Polymers / Q000737:chemistry; D012996:Solutions / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet
D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; D012996:Solutions; D008982:Molybdenum