Bis[mu-2-[(1,5-diaza-1-cyclooctyl)-methyl]phenolato-N,N',O:O]bis-[chlorozinc(II)]diacetone solvate: design of a square-pyramidal ZnN2O2Cl complex.
The title complex, [Zn(2)(C(13)H(19)N(2)O)(2)Cl(2)].2C(3)H(6)O, resides on a crystallographic inversion center. The two Zn(II) centers bridged by the phenoxo groups are in pentacoordinated distorted square-pyramidal coordination environments with an intramolecular Zn...Zn distance of 3.175 (3) A. The mesocyclic ligand takes a boat-chair conformation and an H atom from the 1,5-diazacyclooctane ring effectively blocks the axial coordination site opposite the Cl ligand to form the ZnN(2)O(2)Cl geometry. The crystal structure is stabilized by a N-H...O hydrogen bond between the amino group and an acetone molecule.
Xu
Q
Q
Department of Chemistry, Chongqing Teacher's College, Chongqing 402168, People's Republic of China.
Du
M
M
Guo
Y M
YM
Bu
X H
XH
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; C435284:bis(mu-2-((1,5-diaza-1-cyclooctyl)-methyl)phenolato-N,N',O-O)bis-(chlorozinc(II)); D015032:Zinc