Thermal isomerization pathway of 1-(4-nitrophenyl)-2-phenylimino-2,5-dihydro-1H-pyrido[3,2-b]indole-3-carbonitrile discovered by laboratory powder data.
The evidence for thermal isomerization of the title compound, C(24)H(15)N(5)O(2), into 2-[(4-nitrophenyl)phenylamino]-5H-pyrido[3,2-b]indole-3-carbonitrile has been obtained as a consequence of crystal structure determinations from laboratory powder data.
Chernyshev
V V
VV
Chemistry Department, Moscow State University, 119899 Moscow, Russia. cher@biocryst.phys.msu.su
Tafeenko
V A
VA
Ryabova
S Y
SY
Sonneveld
E J
EJ
Schenk
H
H
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D007211:Indoles / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D011208:Powders; D011725:Pyridines / Q000737:chemistry*; D013816:Thermodynamics
C435294:1-(4-nitrophenyl)-2-phenylimino-2,5-dihydro-1H-pyrido(3,2-b)indole-3-carbonitrile; D007211:Indoles; D011208:Powders; D011725:Pyridines