Chloroprene as a source of fine chemicals: palladium-catalyzed synthesis of terminal allenes.
[reaction: see text] Several functionalized terminal allenes were prepared in moderate to excellent yield by a palladium-catalyzed reaction of chloroprene (2-chloro-1,3-butadiene) with soft nucleophiles.
Ogasawara
M
M
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.
Ikeda
H
H
Nagano
T
T
Hayashi
T
T