title: Immobilization of chiral ligands on polymer fibers by electron beam induced grafting and applications in enantioselective catalysis.
abstract: [reaction: see text] Styrenic TADDOL and L-prolinol-derived monomers were immobilized on polyethylene fibers by electron beam induced preirradiation grafting using styrene as comonomer. The polymer-supported chiral ligands were utilized as catalysts in the asymmetric addition of diethylzinc to benzaldehyde. Fiber-bound titanium TADDOLate gave a quantitative conversion of benzaldehyde to 1-phenylpropan-1-ol in a 97:3 S/R enantiomeric ratio. The catalyst was successfully regenerated and employed in subsequent reactions with retention of high enantioselectivities.
authors.affiliation: Laboratory of Polymer Technology, Abo Akademi University, FIN-20500 Abo, Finland.
authors.forename: S
authors.initials: S
authors.lastname: Degni
authors.forename: C E
authors.initials: CE
authors.lastname: Wilén
authors.forename: R
authors.initials: R
authors.lastname: Leino