Use of the Gaussian Distribution Function as a Tool to Estimate Continuous Heterogeneity in Adsorbing Systems.
In environmental engineering, adsorption and desorption are phenomena commonly referred to as responsible for pollution dispersion, retention, or retardation in soils, aquifers, and hydrologic systems. They are also used to remove organic pollutants from water or odorous compounds in gas deodorization. Most often, the characterization of the aqueous adsorption systems that are of engineering interest involves a narrow adsorbate concentration range and low values of the adsorbate concentration. The practice is to use the Freundlich equation that best fits most data and is considered sufficient to design adsorption contactors. However, no physical or chemical meaning can be associated with the values taken by the parameters. The present paper gives a new way of analyzing adsorption data, using an extension of the Freundlich equation and the Gaussian distribution function that makes it possible to associate parameter values of this extension with the adsorbate-adsorbent normal interaction energy, its heterogeneity, and to some extent the adsorbate-adsorbate lateral interaction energy. Copyright 2001 Academic Press.
Bersillon
Jean-Luc
JL
Laboratoire Environnement et Minéralurgie, Groupe de Recherche sur l'Eau et les Solides Divisés, CNRS URA 7569-ENSG-INPL, 15 avenue du Charmois, Vandoeuvre Cedex, F-54501, France
Villieras
Frederic
F
Bardot
Frederique
F
Gorner
Tatiana
T
Cases
Jean-Maurice
JM