N,N'-Dimethylpiperazinium(2+) phosphonoacetate: hydrogen-bonded anion sheets containing cation-templated R(6)(6)(28) rings.
In the title compound, C(6)H(16)N(2)(2+).2C(2)H(4)O(5)P(-), the cations lie across centres of inversion; in the anions, two of the H-atom sites have 0.50 occupancy. The anions are linked by short O-H...O hydrogen bonds [O...O 2.465 (3)-2.612 (3) A and O-H...O 165-171 degrees ] into sheets of alternating R(2)(2)(12) and R(6)(6)(28) rings, both of which are centrosymmetric; the cations lie at the centres of the larger rings linked to the anion sheet by N-H...O hydrogen bonds [N...O 2.642 (2) A and N-H...O 176 degrees ].
Farrell
D M
DM
School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, Scotland.
Ferguson
G
G
Lough
A J
AJ
Glidewell
C
C