catena-Poly[aquacopper(II)-mu-[N-(1-oxido-2-naphthylmethylene)-glycinato-O,N,O':O']].
In the title compound, [Cu(C(13)H(9)NO(3))(H(2)O)](n), the Cu(II) ion is in a slightly distorted square-pyramidal environment, with four short bonds in the basal plane formed by three donor atoms of the Schiff base and a water O atom. A symmetry-related neighbouring molecule provides an apical carboxylate O atom at a distance of 2.551 (3) A; this contact leads to the formation of zigzag polymeric chains. In addition, the chain fragments are connected to each other by hydrogen bonding.
Maniukiewicz
W
W
Institute of General and Ecological Chemistry, Technical University of Lódz, Zwirki 36, 90-924 Lódz, Poland. waldemar@ck-sg.p.lodz.pl
Bukowska-Strzyzewska
M
M
D002614:Chelating Agents / Q000737:chemistry; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D012545:Schiff Bases
D002614:Chelating Agents; D009942:Organometallic Compounds; D012545:Schiff Bases; C435283:poly(aquacopper(II)-(N-(1-oxido-2-naphthylmethylene)-glycinato-O,N,O'-O'))