Dissipation of epoxiconazole in the paddy field under subtropical conditions of Taiwan.
The environmental fate and distribution of fungicide epoxiconazole were studied by a rice paddy field model ecosystem. One week before the head-sprouting stage, rice plant was treated separately once with OPUS (tradename of epoxiconazole) 12% SC 2.1 kg ha(-1) and 1.4 kg ha(-1), respectively. Soil, water and rice plant were sampled seven days intervals nine times after application. The bioconcentration factor of epoxiconazole on mosquito fish in the ecosystem was also determined, based on the amounts of epoxiconazole content both in fish and water. This was initiated one day after the fungicide treatment, and continued for four days. In addition, the residue of epoxiconazole in rice grains was analyzed after harvest. After harvest, both planted water spinach (Ipomoea aquatica Forsk) and edible amaranth (Amaranthus mangostanüs L.) were analyzed. The results showed that epoxiconazole degraded in the local environment under the experimental conditions described. The degradation equations were in accordance with the first order kinetics. The DT50 of soil, field water and rice plant were 20-69 days, 11-20 days and 14-39 days, respectively. The bioconcentration factors of epoxiconazole on mosquito fish were 12.9 and 10.6 from 2.1 kg ha(-1) and 1.4 kg ha(-1) treatment, respectively. Residues of epoxiconazole in both rice and harvest vegetables were non-detectable. This indicates that epoxiconazole applied to rice at the recommended rates and application frequencies will not accumulate on rice grain and successive cropping vegetables.
Lin
H T
HT
Residue Control Department, Taiwan Agricultural Chemicals and Toxic Substances Research Institute, Wufeng, ROC. htlin@hp847.tactri.gov.tw
Wong
S S
SS
Li
G C
GC
D027721:Amaranthus / Q000378:metabolism; D000818:Animals; D018556:Crops, Agricultural / Q000378:metabolism; D003532:Cyprinodontiformes / Q000378:metabolism; D003710:Demography; D004463:Ecology; D017753:Ecosystem; D004852:Epoxy Compounds / Q000032:analysis* / Q000378:metabolism; D005659:Fungicides, Industrial / Q000032:analysis* / Q000378:metabolism; D027741:Ipomoea / Q000378:metabolism; D012275:Oryza / Q000378:metabolism; D010573:Pesticide Residues / Q000032:analysis; D012621:Seasons; D012989:Soil Pollutants / Q000032:analysis* / Q000378:metabolism; D013624:Taiwan; D014230:Triazoles / Q000032:analysis* / Q000378:metabolism; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000378:metabolism
D004852:Epoxy Compounds; D005659:Fungicides, Industrial; D010573:Pesticide Residues; D012989:Soil Pollutants; D014230:Triazoles; D014874:Water Pollutants, Chemical; C109476:epoxiconazole