title: Isolation and HPLC quantitative analysis of flavonoid glycosides from Brazilian beverages (Maytenus ilicifolia and M. aquifolium).
abstract: Aqueous infusions of Brazilian Maytenus leaves are used as beverages, foodstuffs, and phytomedicines. Previously, we isolated two new flavonoid tetrasaccharides from the infusion of Maytenus aquifolium leaves that showed antiulcer activity. In this investigation a new flavonoid tetrasaccharide, kaempferol-3-O-alpha-L-rhamnopyranosyl (1-->6)-O-[alpha-L-arabinopyranosyl (1-->3)-O-alpha-L-rhamnopyranosyl (1-->2)]-O-beta-D-galactopyranoside (3), was isolated, together with kaempferol tri- and disaccharides and quercetin trisaccharides from the aqueous infusion of Maytenus ilicifolia leaves. All structures were elucidated by ES-MS and NMR spectroscopic methods. The quantitative analysis of the flavonoid glycosides from Maytenus ilicifolia and M. aquifolium has been performed by HPLC.
authors.affiliation: Departamento de Quimica, Universidade Federal de Minas Gerais, Belo Horizonte, Brazil.
authors.forename: J P
authors.initials: JP
authors.lastname: Leite
authors.forename: L
authors.initials: L
authors.lastname: Rastrelli
authors.forename: G
authors.initials: G
authors.lastname: Romussi
authors.forename: A B
authors.initials: AB
authors.lastname: Oliveira
authors.forename: J H
authors.initials: JH
authors.lastname: Vilegas
authors.forename: W
authors.initials: W
authors.lastname: Vilegas
authors.forename: C
authors.initials: C
authors.lastname: Pizza
mesh_terms: D001628:Beverages / Q000032:analysis*; D001938:Brazil; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D005419:Flavonoids / Q000737:chemistry* / Q000302:isolation & purification*; D008401:Gas Chromatography-Mass Spectrometry; D006027:Glycosides / Q000737:chemistry* / Q000302:isolation & purification*; D018515:Plant Leaves / Q000737:chemistry
chemical_list: D005419:Flavonoids; D006027:Glycosides