title: Valence selective DAFS measurements of Mn in La1/3Ca2/3MnO3.
abstract: The manganese perovskite system La(1-x)Ca(x)MnO3 displays a complex phase diagram of structural, magnetic, and transport properties with varying Ca concentration. At x = 2/3 and at low temperature, the system is antiferromagnetic with Mn4+ and Mn3+ ions occupying special positions in a charge-ordered supperlattice. The charge ordering transition at about 260 K is characterized by the appearance of satellite peaks around certain strong normal lattice reflections. The normal lattice reflections are due to scattering from planes containing Mn4+ and Mn3+ ions in nearly stoichiometric proportion, however the superlattice reflections are due to scattering from planes containing only Mn4+ ions. By measuring Diffraction Anomalous Fine-Structure spectral on a superlattice reflection and its associated normal lattice reflection, it is possible to isolate absorption-like spectra for the two Mn sites. Due to the weak intensity of these superlattice reflections, we were unable to obtain high quality near-edge spectra for the superlattice reflection measured. However, the data offer useful information about the local electronic structures of the two Mn ions.
authors.affiliation: Laboratoire de Cristallographie, CNRS, Grenoble, France. ravel@phys.washington.edu
authors.forename: B
authors.initials: B
authors.lastname: Ravel
authors.forename: S
authors.initials: S
authors.lastname: Grenier
authors.forename: H
authors.initials: H
authors.lastname: Renevier
authors.forename: C B
authors.initials: CB
authors.lastname: Eom