Synthesis of disaccharides related to the mycobacterial arabinogalactan.
Several novel glycofuranoses disaccharides related to mycobacterial cell wall polysaccharides were synthesized regio- and stereoselectively using 2,3,5-tri-O-benzoyl-alpha-D-arabinofuranosyl trichloroacetimidate as a glycosyl donor.
Pathak
A K
AK
Organic Chemistry Department, Southern Research Institute, Birmingham, AL 35255-5305, USA.
Pathak
V
V
Khare
N K
NK
Maddry
J A
JA
Reynolds
R C
RC
D000081:Acetamides; D002240:Carbohydrate Sequence; D062845:Chloroacetates; D004187:Disaccharides / Q000138:chemical synthesis* / Q000737:chemistry*; D005685:Galactans / Q000737:chemistry*; D006031:Glycosylation; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009161:Mycobacterium / Q000737:chemistry*; D011135:Polysaccharides, Bacterial / Q000737:chemistry
D000081:Acetamides; D062845:Chloroacetates; D004187:Disaccharides; D005685:Galactans; D011135:Polysaccharides, Bacterial; C009528:trichloroacetamide; C005653:arabinogalactan