Uoamines A and B, piperidine alkaloids from the ascidian Aplidium uouo.
A specimen of the ascidian Aplidium uouo from Maui contained two piperidine alkaloids, uoamines A and B, that differed only in the geometry of a 3-thiomethylacrylate ester group. The alkaloids exhibit conformational mobility in the NMR time frame, which complicated the elucidation of their structures by interpretation of spectroscopic data.
McCoy
M C
MC
Scripps Institution of Oceanography, University of California at San Diego, La Jolla, California 92093-0212, USA.
Faulkner
D J
DJ
D000470:Alkaloids / Q000737:chemistry / Q000302:isolation & purification*; D000818:Animals; D006254:Hawaii; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D010880:Piperidines / Q000737:chemistry / Q000302:isolation & purification*; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism; D014561:Urochordata / Q000737:chemistry*
D000470:Alkaloids; D010880:Piperidines; C436545:uoamine A; C436546:uoamine B