Hydrogen-bonding in ethanol adducts to bis(3-R-penta-2,4-dionato)nickel(II) species.
Ethanol adducts of bis(3-R-penta-2,4-dionato) nickel(II) have been prepared by recrystallization of the corresponding nickel bisacetylacetonate species from ethanol, and their crystal structures have been determined by X-ray diffraction: R = methyl, C16H30NiO6, a = 5.177(1), b = 9.326(1), c = 9.649(1), a = 95.39(1), beta = 100.04(1), gamma = 97.16(1), space group Ponebar, Z = 1; R = hex-5-enyl, C26H46NiO6, a = 5.176(1), b = 9.677(1), c = 14.458(1), a = 92.333(3), beta = 93.945(4), gamma = 96.011(6), space group Ponebar, Z = 1; R = phenyl, C26H34NiO6, a = 27.399(1), b = 5.349(1), c = 19.827(2), beta = 117.410(7), space group C2/c, Z = 4. The compounds show remarkable differences in their ability to form hydrogen bonds in the solid phase and in solution, depending upon the nature of the substituent in the 3-position of the acetylacetone fragment. Analysis of the strength of hydrogen bonds within the limits of supermolecular approximation based on the results of calculations by DFT method has been carried out and were found to correlate with experimental observations.
Polyakov
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VR
Max-Planck-Institut für Kohlenforschung, Mülheim an der Ruhr, Germany. valery.polyakov@writeme.com
Czerwinski
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