Corrosion of Cu-xZn alloys in slightly alkaline chloride solutions studied by stripping voltammetry and microanalysis.
The mechanism of corrosion of Cu-xZn alloys (x = 10-40 wt %) in slightly alkaline chloride solutions was investigated by analysing solid reaction products by energy dispersive X-ray analysis (EDS) and dissolved reaction products by differential anodic pulse stripping (DAPS) voltammetry. The corrosion process was studied under open circuit and under potentiostatic conditions at selected potentials. Pure metals were studied comparatively so that an interacting effect of particular metal components in the alloy could be determined. All four Cu-xZn alloys show an improved behaviour compared to pure metals. Under open-circuit condition both components dissolve simultaneously in the solution. With increasing immersion time the preferential, dissolution of zinc in the solution becomes pronounced. It is the highest for Cu-10Zn and the lowest for Cu-30Zn alloy. Under potentiostatic control the dissolution mechanism depends on the electrode potential and changes from exclusive dissolution of zinc to simultaneous dissolution of both components with preferential dissolution of zinc. The latter decreases, as the electrode potential becomes more positive.
Milosev
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J. Stefan Institute, Jamova 39, 1001 Ljubljana, Slovenia. ingrid.milosev@ijs.si
Minović
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D000497:Alloys / Q000737:chemistry; D002623:Chemistry Techniques, Analytical / Q000379:methods; D002712:Chlorides / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D004563:Electrochemistry; D004566:Electrodes; D006863:Hydrogen-Ion Concentration; D012995:Solubility; D017967:Zinc Compounds / Q000737:chemistry*
D000497:Alloys; D002712:Chlorides; D017967:Zinc Compounds; D003300:Copper