Correlation of polychlorinated naphthalenes with polychlorinated dibenzofurans formed from waste incineration.
Isomer composition of polychlorinated naphthalenes (PCNs) was measured for municipal waste incinerator fly ash samples and for emission samples produced from soot and copper-deposit experiments conducted at the United States Environmental Protection Agency (US-EPA). Two types of PCN isomer patterns were identified. One pattern contained specific PCN isomers in which chlorine atoms are substituted as if the peri(alpha-) position were dechlorinated from the higher chlorinated PCNs one by one. In another pattern, the isomers had a tendency for the chlorine atoms to assume successive positions on the naphthalene ring, which may be caused by specifically oriented chlorination. Some of these isomers increased, together with several polychlorinated dibenzofuran (PCDF) and a few polychlorinated dibenzo-p-dioxin (PCDD) isomers. The ratios between some specific PCN, PCDF, and PCDD isomers measured for the fly ash samples agree with those obtained from the soot and copper-deposit experiments. The observations suggest that these isomers were formed possibly from de novo synthesis utilizing the carbon structure contained in soot under the catalytic effect of a copper compound. Typical isomers for PCNs and PCDFs produced from incineration emissions were identified.
Imagawa
T
T
National Institute for Resources and Environment, Agency of Industrial Science and Technology, Tsukuba, Ibaraki, Japan. imagawa@nire.go.jp
Lee
C W
CW
D000393:Air Pollutants; D001572:Benzofurans / Q000737:chemistry*; D002713:Chlorine / Q000737:chemistry; D000072338:Dibenzofurans, Polychlorinated; D004784:Environmental Monitoring; D017745:Incineration; D007536:Isomerism; D009281:Naphthalenes / Q000737:chemistry*; D000072317:Polychlorinated Dibenzodioxins / Q000031:analogs & derivatives* / Q000737:chemistry*; D012037:Refuse Disposal; D012989:Soil Pollutants / Q000032:analysis
D000393:Air Pollutants; D001572:Benzofurans; D000072338:Dibenzofurans, Polychlorinated; D009281:Naphthalenes; D000072317:Polychlorinated Dibenzodioxins; D012989:Soil Pollutants; D002713:Chlorine