Fractal analysis of STM images of photochemical polymer of coniferyl alcohol.
Fractal analysis was applied to images of photochemical lignin polymer obtained using scanning tunneling microscope. We studied the polymer obtained in vitro by ionic mechanism through UV radiation--induced polymerization. The analysis showed the regularity of the lignin-like polymer at different levels of organization. At the 95% confidence level, there was no significant difference in the fractal dimension between images representing different organizational levels of photochemical lignin. That means that lignin produced in in vitro conditions by photochemical mechanism of synthesis, has a fractal structural organization. The obtained values of the fractal dimension are in good agreement with the theoretically predicted value for the polyaddition and polycondensation mechanism of polymerization, known as the bulk model.
Radotić
K
K
Centre for Multidisciplinary Studies, University of Belgrade, Yugoslavia. xenia@ibiss.bg.ac.yu
Tasić
M
M
Jeremić
M
M
Budimlija
Z
Z
Simić-Krstić
J
J
Polzović
A
A
Bozović
Z
Z
D017709:Fractals; D007477:Ions; D008031:Lignin / Q000096:biosynthesis / Q000737:chemistry; D016252:Microscopy, Scanning Tunneling / Q000379:methods*; D010636:Phenols / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry; D011487:Protein Conformation; D014466:Ultraviolet Rays
D007477:Ions; D010636:Phenols; D011108:Polymers; D008031:Lignin; C010559:coniferyl alcohol