Synthesis of peracetylated chacotriose.
Steroidal glycoalkaloids of many Solanum species have recognized biological activities, especially those containing the glycosyl moiety alpha-L-rhamnopyranosyl-(1-->2)-[alpha-L-rhamnopyranosyl-(1-->4)]-D-glucopyranose (chacotriose) whose peracetate is here synthesized and characterized by complete 1H and 13C NMR assignment.
Morillo
M
M
Instituto de Investigaciones, Facultad de Farmacia, Universidad de Los Andes, 5101, Mérida, Venezuela.
Lequart
V
V
Grand
E
E
Goethals
G
G
Usubillaga
A
A
Villa
P
P
Martin
P
P
D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D008969:Molecular Sequence Data; D010463:Peracetic Acid / Q000138:chemical synthesis*; D010936:Plant Extracts / Q000138:chemical synthesis; D012991:Solanaceous Alkaloids / Q000737:chemistry; D012992:Solanine / Q000031:analogs & derivatives* / Q000737:chemistry; D011198:Solanum tuberosum / Q000737:chemistry; D014326:Tropanes / Q000138:chemical synthesis*
D010936:Plant Extracts; D012991:Solanaceous Alkaloids; D014326:Tropanes; C433845:chacotriose; D012992:Solanine; C011860:alpha-chaconine; C026608:alpha-solamargine; D010463:Peracetic Acid