Synthesis of photo- and electroactive stilbenoid dendrimers carrying dibutylamino peripheral groups.
[structure: see text]. A novel convergent synthetic route for the preparation of functionalized and fluorescent stilbenoid dendrons built on the 1,3,5-benzene core and endowed with a periphery of dibutylamino groups has been developed. Long alkyl chains have been incorporated on the peripheral amino moieties to increase the solubility of the final products. Good donor ability of the new dendrimers has been observed by cyclic voltammetry measurements as a result of the presence of the peripheral dibutylaniline moieties.
Segura
J L
JL
Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, E-28040 Madrid, Spain.
Gómez
R
R
Martín
N
N
Guldi
D M
DM