Combustion of gasolines in premixed laminar flames European certified and California phase 2 reformulated gasoline.
Two gasoline qualities, European unleaded certified gasoline (EUCG) and California phase 2 reformulated gasoline (P2 RFG), were analysed. EUCG contained about twice the amount of alkyl benzenes compared to P2 RFG and a large amount of cyclohexane. As a balance, P2 RFG contained higher amounts of isooctane and MTBE. The gasolines were burned in a premixed laminar flame burner at 1 atm and at about stoichiometric fuel/air ratio. The species profiles were measured using on-line GC/MS. About 40 compounds were be detected in the gasoline flames. The EUCG resulted in formation of more reactive and toxic compounds. The combustion profiles of the fuel components showed a similar slope, which suggests that the fuel components burn quite independently of each other. Ethene and propene were the dominating species produced from the two gasolines. Commonly, substantial amounts of higher alkenes were found. Combustion of P2 RFG produced higher amounts of isobutene, propene, propyne, propadiene and methanol compared to combustion of EUCG. The high amount of isobutene is reasonably a result of high concentration of isooctane and MTBE in the fuel. The high amount of methanol formed is probably due to the MTBE present in the gasoline. EUCG produced significantly higher amounts of 1,3-butadiene, which quite likely is formed from the cyclohexane in the fuel. The benzene profiles from both gasolines shows an almost constant level up to 800 microm from the burner surface; this is probably due to formation of benzene from alkyl benzenes.
Håkansson
A
A
Department of Physical Chemistry, Chalmers University of Technology, Göteborg, Sweden.
Strömberg
K
K
Pedersen
J
J
Olsson
J O
JO
D000393:Air Pollutants / Q000032:analysis*; D001554:Benzene / Q000032:analysis; D002070:Butadienes / Q000032:analysis; D002140:California; D002273:Carcinogens / Q000032:analysis; D005060:Europe; D008401:Gas Chromatography-Mass Spectrometry; D005742:Gasoline / Q000032:analysis*; D017745:Incineration; D012016:Reference Values; D001335:Vehicle Emissions / Q000032:analysis*
D000393:Air Pollutants; D002070:Butadienes; D002273:Carcinogens; D005742:Gasoline; D001335:Vehicle Emissions; D001554:Benzene; C031763:1,3-butadiene