title: Dynamics of spin I=3/2 under spin-locking conditions in an ordered environment.
abstract: We have derived approximate analytic solutions to the master equation describing the evolution of the spin I=3/2 density operator in the presence of a radio-frequency (RF) field and both static and fluctuating quadrupolar interactions. Spectra resulting from Fourier transformation of the evolutions of the on-resonance spin-locked magnetization into the various coherences display two satellite pairs and, in some cases, a central line. The central line is generally trimodal, consisting of a narrow component related to a slowly relaxing mode and two broad components pertaining to two faster relaxing modes. The rates of the fast modes are sensitive to slow molecular motion. Neither the amplitude nor the width of the narrow component is affected by the magnitude of the static coupling, whereas the corresponding features of the broad components depend in a rather complicated manner on the spin-lock field strength and static quadrupolar interaction. Under certain experimental conditions, the dependencies of the amplitudes on the dynamics are seen to vanish and the relaxation rates reduce to relatively simple expressions. One of the promising emerging features is the fact that the evolutions into the selectively detected quadrupolar spin polarization order and the rank-two double-quantum coherence do not exhibit a slowly relaxing mode and are particularly sensitive to slow molecular motion. Furthermore, these coherences can only be excited in the presence of a static coupling and this makes it possible to discern nuclei in anisotropic from those in isotropic environment. The feasibility of the spin-lock pulse sequences with limited RF power and a nonvanishing average electric field gradient has been demonstrated through experiments on sodium in a dense lyotropic DNA liquid crystal.
authors.affiliation: Soft Condensed Matter Group, Leiden Institute of Chemistry, Leiden University, 2300 RA Leiden, The Netherlands.
authors.forename: J R
authors.initials: JR
authors.lastname: van der Maarel
authors.forename: W
authors.initials: W
authors.lastname: Jesse
authors.forename: I
authors.initials: I
authors.lastname: Hancu
authors.forename: D E
authors.initials: DE
authors.lastname: Woessner
mesh_terms: D003460:Crystallization; D004247:DNA / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008433:Mathematics; D012815:Signal Processing, Computer-Assisted
chemical_list: D004247:DNA