title: Mobility and leachability of zinc in two soils treated with six organic zinc complexes.
abstract: A study of soil columns was conducted to evaluate Zn movement potential in two reconstructed soil profiles. Zn-phenolate, Zn-EDDHA, Zn-EDTA, Zn-lignosulfonate, Zn-polyflavonoid, and Zn-heptagluconate were applied in the upper zone of the column. The different physicochemical properties of the two soils and the micronutrient source may influence Zn leaching, the distribution of Zn among soil fractions, and the Zn available to the plant in the depth of the layers. In Aquic Haploxeralf soil, the application of six fertilizers produced little migration and very small leaching of Zn in the soil profiles. In Calcic Haploxeralf soil, Zn-EDTA migrated and was distributed throughout the soil columns. This Zn chelate produces a loss of Zn by leaching, which was 36% of the added Zn. In the latter soil, Zn leached very little with the other five fertilizer treatments. The same as for these organic Zn complexes, the retention of added Zn indicated the potential of metal accumulation in the A(p) horizons of the two soil profiles. A large portion of applied Zn was available to plants [diethylenetriaminepentaacetic acid (DTPA) and Mehlich-3 extractable Zn] in the depths reached by the different commercial formulations. The relationship between the two methods was highly significant (Mehlich-3-Zn = 1.25 + 1.13 DTPA-Zn, R(2) = 99.19%). When Zn was added as Zn-EDTA, the amounts of the most labile fractions (water-soluble plus exchangeable and organically complexed Zn) increased throughout the entire profile column in comparison with the control columns, although in the B(t) horizon of the Aquic Haploxeralf soil they increased only slightly.
authors.affiliation: Departamento de Química y Análisis Agrícola, Escuela Técnica Superior de Ingenieros Agrónomos, Universidad Politécnica de Madrid, Ciudad Universitaria, s/n, 28040 Madrid, Spain.
authors.forename: J M
authors.initials: JM
authors.lastname: Alvarez
authors.forename: J
authors.initials: J
authors.lastname: Novillo
authors.forename: A
authors.initials: A
authors.lastname: Obrador
authors.forename: L M
authors.initials: LM
authors.lastname: López-Valdivia
mesh_terms: D000327:Adsorption; D002614:Chelating Agents / Q000737:chemistry*; D004784:Environmental Monitoring; D012987:Soil / Q000032:analysis*; D012989:Soil Pollutants; D012995:Solubility; D015032:Zinc / Q000737:chemistry*
chemical_list: D002614:Chelating Agents; D012987:Soil; D012989:Soil Pollutants; D015032:Zinc