title: The formation of organic molecules in astronomical ices.
abstract: An absorption feature at 3.4 micrometers has been observed in various lines-of-sight through the diffuse interstellar medium. Its position and width lead to an identification with the C-H stretching mode of solid organic material. A possible mechanism for the production of organic solids in the interstellar medium is UV photoprocessing of icy mantles which accrete on dust grains in dense clouds. Furthermore, thermally induced reactions involving formaldehyde molecules in the mantles could be an important source of organics. Laboratory simulation of these processes shows that a large variety of oxygen- and nitrogen-rich species may be produced. It is shown that the occurrence of periodic transient heating events plays an important role in the production of organic material in the ice mantles. Finally, it is pointed out how future missions like the Infrared Space Observatory (ISO) as well as analysis of comet material by Rosetta may be able to clarify the nature and evolution of interstellar organics.
authors.affiliation: Leiden Observatory Laboratory, The Netherlands.
authors.forename: W A
authors.initials: WA
authors.lastname: Schutte
mesh_terms: D002248:Carbon Monoxide / Q000032:analysis / Q000737:chemistry; D019418:Evolution, Chemical; D018559:Exobiology; D005118:Extraterrestrial Environment; D005557:Formaldehyde / Q000737:chemistry; D007053:Ice / Q000032:analysis*; D019110:Meteoroids; D008956:Models, Chemical; D009930:Organic Chemicals / Q000138:chemical synthesis*; D010782:Photolysis; D013696:Temperature; D014466:Ultraviolet Rays
chemical_list: D007053:Ice; D009930:Organic Chemicals; D005557:Formaldehyde; D002248:Carbon Monoxide