Synthesis of (Z)-2-acyl-2-enals via retrocycloadditions of 5-acyl-4-alkyl-4H-1,3-dioxins: application in the total synthesis of the cytotoxin (+/-)-euplotin A.
Aungst
R A
RA
Department of Chemistry, Pennsylvania State University, University Park, Pennsylvania 16802, USA.
Funk
R L
RL
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D003603:Cytotoxins / Q000138:chemical synthesis*; D004147:Dioxins / Q000737:chemistry*; D005663:Furans / Q000138:chemical synthesis*; D006575:Heterocyclic Compounds, 3-Ring / Q000138:chemical synthesis*
D000475:Alkenes; D003603:Cytotoxins; D004147:Dioxins; D005663:Furans; D006575:Heterocyclic Compounds, 3-Ring; C437183:euplotin A