title: Interstellar cyanomethane.
abstract: We have made an observational study of the newly identified cyanomethane radical CH2CN and the possibly related species CH3CN with the goals of (1) elucidating the possible role of reactions of the type CnHm(+) + N in astrochemistry, and (2) providing a possible test of Bates's models of dissociative electron recombination.  We find a remarkably different abundance ratio CH2CN/CH3CN in TMC-1 and Sgr B2, which we deduce is a result of the large difference in temperature of these objects.  Studies of CH2CN and CH3CN in other sources, including two new detections of CH2CN, support this conclusion and are consistent with a monotonic increase in the CH2CN/CH3CN ratio with decreasing temperature over the range 10-120 K.  This behavior may be explained by the destruction of CH2CN by reaction with O.  If this reaction does not proceed, then CH2CN and CH3CN are concluded to form via different chemical pathways.  Thus, they do not provide a test of Bates's conjectures (they do not both form from CH3CNH+).  CH2CN is then likely to form via C2H4(+) + N --> CH2CNH+, thus demonstrating the viability of this important reaction in astrochemistry.  The T dependence of the CH2CN/CH3CN ratio would then reflect the increasing rate of the C2H4(+) + N reaction with decreasing temperature.
authors.affiliation: National Radio Astronomy Observatory, USA.
authors.forename: B E
authors.initials: BE
authors.lastname: Turner
authors.forename: P
authors.initials: P
authors.lastname: Friberg
authors.forename: W M
authors.initials: WM
authors.lastname: Irvine
authors.forename: S
authors.initials: S
authors.lastname: Saito
authors.forename: S
authors.initials: S
authors.lastname: Yamamoto
mesh_terms: D000097:Acetonitriles / Q000032:analysis*; D055580:Astronomical Phenomena; D001256:Astronomy; D055598:Chemical Phenomena; D002621:Chemistry; D005118:Extraterrestrial Environment; D013057:Spectrum Analysis; D013696:Temperature
chemical_list: D000097:Acetonitriles