title: Fullerenes in an impact crater on the LDEF spacecraft.
abstract: The fullerenes C60 and C70 have been found to occur naturally on Earth and have also been invoked to explain features in the absorption spectra of interstellar clouds. But no definitive spectroscopic evidence exists for fullerenes in space and attempts to find fullerenes in carbonaceous chondrites have been unsuccessful. Here we report the observation of fullerenes associated with carbonaceous impact residue in a crater on the Long Duration Exposure Facility (LDEF) spacecraft. Laser ionization mass spectrometry and Raman spectroscopy indicate the presence of fullerenes in the crater and in adjacent ejecta. Man-made fullerenes survive experimental hypervelocity (approximately 6.1 km s-1) impacts into aluminium targets, suggesting that space fullerenes contained in a carbonaceous micrometeorite could have survived the LDEF impact at velocities towards the lower end of the natural particle encounter range (<13 km s-1). We also demonstrate that the fullerenes were unlikely to have formed as instrumental artefacts, nor are they present as contaminants. Although we cannot specify the origin of the fullerenes with certainty, the most plausible source is the chondritic impactor. If, alternatively, the impact produced the fullerenes in situ on LDEF, then this suggests a viable mechanism for fullerene production in space.
authors.affiliation: Charles Evans and Associates, Redwood City, California 94063, USA.
authors.forename: F
authors.initials: F
authors.lastname: Radicati di Brozolo
authors.forename: T E
authors.initials: TE
authors.lastname: Bunch
authors.forename: R H
authors.initials: RH
authors.lastname: Fleming
authors.forename: J
authors.initials: J
authors.lastname: Macklin
mesh_terms: D000535:Aluminum; D002244:Carbon; D019443:Cosmic Dust; D005118:Extraterrestrial Environment; D037741:Fullerenes; D013058:Mass Spectrometry; D019110:Meteoroids; D008855:Microscopy, Electron, Scanning; D013026:Space Flight; D018531:Spacecraft; D013059:Spectrum Analysis, Raman
chemical_list: D019443:Cosmic Dust; D037741:Fullerenes; C069836:fullerene C70; D002244:Carbon; D000535:Aluminum; C069837:fullerene C60