title: Variations in the HCN/HNC abundance ratio in the Orion molecular cloud.
abstract: We have used observations of the rare isotopes of HCN and HNC to determine the relative abundance of these two chemical isomers along the central ridge of the Orion molecular cloud.  The abundance ratio [HCN]/[HNC] decreases by more than an order of magnitude from the relatively warm plateau and hot core sources toward the KL nebula to the colder, more quiescent clouds to the north and south.  Even in the cooler regions, however, the ratio is an order of magnitude larger than that found in previous investigations of cold dark clouds.  We determine the kinetic temperature in the regions we have studied from new observations of methylacetylene (CH3CCH), together with other recent estimates of the gas temperature near KL.  The results suggest that the warmer portions of the cloud are dominated by different chemical pathways than those in the general interstellar cloud material.
authors.affiliation: Five College Radio Astronomy Observatory, University of Massachusetts, USA.
authors.forename: P F
authors.initials: PF
authors.lastname: Goldsmith
authors.forename: W M
authors.initials: WM
authors.lastname: Irvine
authors.forename: A
authors.initials: A
authors.lastname: Hjalmarson
authors.forename: J
authors.initials: J
authors.lastname: Elldér
mesh_terms: D000480:Alkynes / Q000737:chemistry; D055580:Astronomical Phenomena; D001256:Astronomy; D002250:Carbon Radioisotopes; D005118:Extraterrestrial Environment; D005740:Gases / Q000032:analysis*; D006859:Hydrogen; D006856:Hydrogen Cyanide / Q000032:analysis / Q000737:chemistry*; D007536:Isomerism; D009590:Nitrogen Radioisotopes; D013057:Spectrum Analysis; D013696:Temperature
chemical_list: D000480:Alkynes; D002250:Carbon Radioisotopes; D005740:Gases; D009590:Nitrogen Radioisotopes; C022030:methylacetylene; D006856:Hydrogen Cyanide; D006859:Hydrogen