title: Susceptibility of the early Earth to irreversible glaciation caused by carbon dioxide clouds.
abstract: Simple energy-balance climate models of the Budyko/Sellers type predict that a small (2-5%) decrease in solar output could result in runaway glaciation on the Earth.  But solar fluxes 25-30% lower early in the Earth's history apparently did not lead to this result.  One currently favoured explanation is that high partial pressures of carbon dioxide, caused by higher volcanic outgassing rates and/or slower rates of silicate weathering, created a large enough greenhouse effect to keep the planet warm.  This does not resolve the problem of climate stability, however, because as we argue here, the oceans can freeze much more quickly than CO2 can accumulate in the atmosphere.  Had such a transient global glaciation occurred in the distant past when solar luminosity was low, it might have been irreversible because of the formation of highly reflective CO2 clouds, similar to those encountered in climate simulations of early Mars.  Our simulations of the early Earth, incorporating the possible formation of such clouds, suggest that the Earth might not be habitable today had it not been warm during the first part of its history.
authors.affiliation: Department of Geosciences, The Pennsylvania State University, University Park 16802, USA.
authors.forename: K
authors.initials: K
authors.lastname: Caldeira
authors.forename: J F
authors.initials: JF
authors.lastname: Kasting
mesh_terms: D000641:Ammonia; D001272:Atmosphere; D002245:Carbon Dioxide; D002980:Climate; D018534:Earth, Planet; D019419:Evolution, Planetary; D055593:Geological Phenomena; D005844:Geology; D017752:Greenhouse Effect; D007053:Ice; D008433:Mathematics; D008962:Models, Theoretical; D016082:Solar System; D013696:Temperature; D018707:Volcanic Eruptions
chemical_list: D007053:Ice; D002245:Carbon Dioxide; D000641:Ammonia