title: Hydrogenated polycyclic aromatic hydrocarbons and the 2940 and 2850 wavenumber (3.40 and 3.51 micron) infrared emission features.
abstract: The 3150-2700 cm-1 (3.17-3.70 microns) range of the spectra of a number of Ar-matrix-isolated PAHs containing excess H atoms (Hn-PAHs) are presented. This region covers features produced by aromatic and aliphatic C-H stretching vibrations as well as overtone and combination bands involving lower lying fundamentals. The aliphatic C-H stretches in molecules of this type having low to modest excess H coverage provide excellent fits to a number of the weak emission features superposed on the plateau between 3080 and 2700 cm-1 (3.25 and 3.7 microns) in the spectra of many planetary nebulae, reflection nebulae, and H II regions. Higher H coverage is implied for a few objects. We compare these results in context with the other suggested identifications of the emission features in the 2950-2700 cm-1 (3.39-3.70 microns) region and briefly discuss their astrophysical implications.
authors.affiliation: Astrophysics Branch, NASA Ames Research Center, Moffett Field, CA 94035-1000, USA.
authors.forename: M P
authors.initials: MP
authors.lastname: Bernstein
authors.forename: S A
authors.initials: SA
authors.lastname: Sandford
authors.forename: L J
authors.initials: LJ
authors.lastname: Allamandola
mesh_terms: D001256:Astronomy / Q000379:methods; D005118:Extraterrestrial Environment; D006840:Hydrocarbons, Alicyclic / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis / Q000737:chemistry*; D013055:Spectrophotometry, Infrared
chemical_list: D006840:Hydrocarbons, Alicyclic; D011084:Polycyclic Aromatic Hydrocarbons; D006859:Hydrogen