title: The early atmosphere:  a new picture.
abstract: Over the last several years, many of the fundamental ideas concerning the composition and chemical evolution of the Earth's early atmosphere have changed.  While many aspects of this subject are clouded--either uncertain or unknown, a new picture is emerging.  We are just beginning to understand how astronomical, geochemical, and atmospheric processes each contributed to the development of the gaseous envelope around the third planet from the sun some 4.6 billion years ago and how that envelope chemically evolved over the history of our planet.  Simple compounds in that gaseous envelope, energized by atmospheric lightning and/or solar ultraviolet radiation, formed molecules of increasing complexity that eventually evolved into the first living systems on our planet.  This process is called "chemical evolution" and immediately preceded biological evolution; once life developed and evolved, it began to alter the chemical composition of the atmosphere that provided the very essence of its creation.  Photosynthetic organisms which have the ability to biochemically transform carbon dioxide and water to carbohydrates, which they use for food, produce large amounts of molecular oxygen (O2) as a by-product of the reaction.  Atmospheric oxygen photochemically formed ozone, which absorbs ultraviolet radiation from the sun and shields the Earth's surface from this biologically lethal radiation.  Once atmospheric ozone levels increased sufficiently, life could leave the safety of the oceans and go ashore for the first time.  Throughout the history of our planet, there has been strong interaction between life and the atmosphere.  Understanding our cosmic roots is particularly relevant as we embark on a search for life outside the Earth.  At this very moment, several radio telescopes around the world are searching for extraterrestrial intelligence (SETI).
authors.affiliation: Atmospheric Sciences Division, NASA Langley Research Center, Hampton,Virginia, USA.
authors.forename: J S
authors.initials: JS
authors.lastname: Levine
mesh_terms: D001272:Atmosphere / Q000737:chemistry*; D018534:Earth, Planet; D019418:Evolution, Chemical; D019419:Evolution, Planetary; D017752:Greenhouse Effect; D018535:Mars; D010100:Oxygen / Q000737:chemistry*; D010777:Photochemistry; D016082:Solar System; D018536:Venus
chemical_list: D010100:Oxygen