Detections of 13C-substituted C3H2 in astronomical sources.
We report observations of the 2(12)-1(01) rotational transition of the 13C isotopic species of cyclopropenylidene (C3H2) toward TMC-1, Sgr B2, and IRC +10216 using the laboratory rest frequencies which have recently become available.  Our detections allow estimates to be made of the fractional abundance of the unsubstituted similar species in these sources.  The fractional abundance relative to H2, f(C3H2), is 1-2 x 10(-8) in TMC-1, and this is similar to the abundance of HCN, one of the more abundant organic molecules in the interstellar medium.  In IRC +10216 f(C3H2) is one order of magnitude greater than in TMC-1.  The 12C species in Sgr B2 shows a self-absorbed profile and the relative abundance of C3H2 estimated to be about an order of magnitude less than in TMC-1.
Madden
S C
SC
Department of Physics and Astronomy, University of Massachusetts, USA.
Irvine
W M
WM
Matthews
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HE
D055580:Astronomical Phenomena; D001256:Astronomy; D002244:Carbon / Q000737:chemistry*; D002247:Carbon Isotopes; D005118:Extraterrestrial Environment; D006844:Hydrocarbons, Cyclic / Q000032:analysis* / Q000737:chemistry; D013057:Spectrum Analysis; D013696:Temperature
D002247:Carbon Isotopes; D006844:Hydrocarbons, Cyclic; D002244:Carbon