Fullerenes in the 1.85-billion-year-old Sudbury impact structure.
Fullerenes (C60 and C70) have been identified by laser desorption, laser desorption post-ionization, and high-resolution electron-impact mass spectrometry in shock-produced breccias (Onaping Formation) of the Sudbury impact structure in Ontario, Canada. The C60 isotope is present at a level of a few parts per million. The fullerenes were likely synthesized within the impact plume from the carbon contained in the bolide. The oxidation of the fullerenes during the 1.85 billion years of exposure was apparently prevented by the presence of sulfur in the form of sulfide-silicate complexes associated with the fullerenes.
Becker
L
L
Scripps Institution of Oceanography, University of California at San Diego, La Jolla 92093-0212B, USA.
Bada
J L
JL
Winans
R E
RE
Hunt
J E
JE
Bunch
T E
TE
French
B M
BM
D002244:Carbon / Q000032:analysis*; D037741:Fullerenes; D019015:Geologic Sediments / Q000032:analysis* / Q000737:chemistry; D019110:Meteoroids; D009864:Ontario; D017640:Silicates / Q000032:analysis; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; D013440:Sulfides / Q000032:analysis
D037741:Fullerenes; D017640:Silicates; D013440:Sulfides; C069836:fullerene C70; D002244:Carbon; C069837:fullerene C60