title: Hydrogen cyanide polymerization:  a preferred cosmochemical pathway.
abstract: Current research in cosmochemistry shows that crude organic solids of high molecular weight are readily formed in planetary, interplanetary and interstellar environments. Underlying much of this ubiquitous chemistry is a low energy route leading directly to the synthesis of hydrogen cyanide and its polymers. Evidence from laboratory and extraterrestrial investigations suggests that these polymers plus water yield heteropolypeptides, a truly universal process that accounts not only for the past synthesis of protein ancestors on Earth but also for reactions proceeding elsewhere today within our solar system, on planetary bodies and satellites around other stars and in the dusty molecular clouds of spiral galaxies. The existence of this preferred pathway - hydrogen cyanide polymerization - surely increases greatly the probability that carbon-based life is widespread in the universe.
authors.affiliation: Department of Chemistry, University of Illinois at Chicago 60680, USA.
authors.forename: C N
authors.initials: CN
authors.lastname: Matthews
mesh_terms: D000596:Amino Acids / Q000138:chemical synthesis; D000641:Ammonia / Q000737:chemistry; D019443:Cosmic Dust; D019418:Evolution, Chemical; D018559:Exobiology; D006856:Hydrogen Cyanide / Q000138:chemical synthesis / Q000737:chemistry*; D006868:Hydrolysis; D019110:Meteoroids; D008697:Methane / Q000737:chemistry; D000069497:Origin of Life; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D016082:Solar System
chemical_list: D000596:Amino Acids; D019443:Cosmic Dust; D011108:Polymers; D006856:Hydrogen Cyanide; D000641:Ammonia; D008697:Methane