title: Confined-pyrolysis as an experimental method for hydrothermal organic synthesis.
abstract: A closed pyrolysis system has been developed as a tool for studying the reactions of organic compounds under extreme hydrothermal conditions.  Small high pressure stainless steel vessels in which the ratio of sediment or sample to water has been adjusted to eliminate the headspace at peak experimental conditions confines the organic components to the bulk solid matrix and eliminates the partitioning of the organic compounds away from the inorganic components during the experiment.  Confined pyrolysis experiments were performed to simulate thermally driven catagenetic changes in sedimentary organic matter using a solids to water ratio of 3.4 to 1.  The extent of alteration was measured by monitoring the steroid and triterpenoid biomarkers and polycyclic aromatic hydrocarbon distributions.  These pyrolysis experiments duplicated the hydrothermal transformations observed in nature.  Molecular probe experiments using alkadienes, alkenes and alkanes in H2O and D2O elucidated the isomerization and hydrogenation reactions of aliphatic compounds and competing oxidative reactions occurring under hydrothermal conditions.  This confined pyrolysis technique is being applied to test experiments on organic synthesis of relevance to chemical evolution for the origin of life.
authors.affiliation: College of Oceanic and Atmospheric Sciences, Oregon State University, Corvallis 97331, USA.
authors.forename: R N
authors.initials: RN
authors.lastname: Leif
authors.forename: B R
authors.initials: BR
authors.lastname: Simoneit
mesh_terms: D000473:Alkanes / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry; D002849:Chromatography, Gas; D008401:Gas Chromatography-Mass Spectrometry; D019015:Geologic Sediments / Q000032:analysis* / Q000737:chemistry; D006358:Hot Temperature; D006838:Hydrocarbons / Q000737:chemistry*; D000069497:Origin of Life; D010578:Petroleum / Q000032:analysis; D013816:Thermodynamics; D014867:Water
chemical_list: D000473:Alkanes; D000475:Alkenes; D006838:Hydrocarbons; D010578:Petroleum; D014867:Water