Organic compounds in the Forest Vale, H4 ordinary chondrite.
We have analyzed the H4 ordinary chondrite Forest Vale for polycyclic aromatic hydrocarbons (PAHs) using two-step laser mass spectrometry (L2MS) and for amino acids using a standard chromatographic method. Indigenous PAHs were identified in the matrices of freshly cleaved interior faces but could not be detected in pulverized silicates and chondrules. No depth dependence of the PAHs was found in a chipped interior piece. Amino acids, taken from the entire sample, consisted of protein amino acids that were nonracemic, indicating that they are terrestrial contaminants. The presence of indigenous PAHs and absence of indigenous amino acids provides support for the contention that different processes and environments contributed to the synthesis of the organic matter in the solar system.
Zenobi
R
R
Department of Chemistry, Stanford University, CA 94305, USA.
Philippoz
J M
JM
Zare
R N
RN
Wing
M R
MR
Bada
J L
JL
Marti
K
K
D000596:Amino Acids / Q000032:analysis*; D000621:Aminoisobutyric Acids / Q000032:analysis; D019418:Evolution, Chemical; D018559:Exobiology; D007834:Lasers; D013058:Mass Spectrometry; D019110:Meteoroids; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis*; D016082:Solar System; D014633:Valine / Q000032:analysis
D000596:Amino Acids; D000621:Aminoisobutyric Acids; D011084:Polycyclic Aromatic Hydrocarbons; C100049:2-aminoisobutyric acid; C032737:isovaline; D014633:Valine