Electronic absorption spectroscopy of matrix-isolated polycyclic aromatic hydrocarbon cations.  II.  The phenanthrene cation (C14H10+) and its 1-methyl derivative.
The ultraviolet, visible, and near infrared absorption spectra of phenanthrene (C14H10), 1-methylphenanthrene [(CH3)C14H9], and their radical ions [C14H10+; (CH3)C14H9+], formed by vacuum-ultraviolet irradiation, were measured in neon matrices at 4.2 K. The associated vibronic band systems and their spectroscopic assignments are discussed. The oscillator strengths were calculated for the phenanthrene ion and found lower than the theoretical predictions. This study presents the first spectroscopic data for phenanthrene and its methyl derivative trapped in a neon matrix where the perturbation of the isolated species by its environment is minimum; a condition crucial to astrophysical applications.
Salama
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F
NASA-Ames Research Center, Space Science Division, Moffett Field, California 94035-1000, USA.
Joblin
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C
Allamandola
L J
LJ
D001128:Argon; D002412:Cations; D008956:Models, Chemical; D009356:Neon; D010616:Phenanthrenes / Q000737:chemistry*; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D019265:Spectroscopy, Near-Infrared
D002412:Cations; D010616:Phenanthrenes; D011084:Polycyclic Aromatic Hydrocarbons; C031181:phenanthrene; C041507:1-methylphenanthrene; D009356:Neon; D001128:Argon