title: Characterization of complex organic compounds formed in simulated planetary atmospheres by the action of high energy particles.
abstract: A wide variety of organic compounds, which are not simple organics but also complex organics, have been found in planets and comets. We reported that complex organics was formed in simulated planetary atmospheres by the action of high energy particles. Here we characterized the experimental products by using chromatographic and mass spectrometric techniques. A gaseous mixture of CO, N2 and H2O was irradiated with high energy protons (major components of cosmic rays). Water-soluble non-volatile substances, which gave amino acids after acid-hydrolysis, were characterized by HPLC and mass spectrometry. Major part of the products were complex compounds with molecular weight of several hundreds. Amino acid precursors were produced even when no water was incorporated with the starting materials. It was suggested that complex molecules including amino acid precursors were formed not in solution from simple molecules like HCN, but directly in gaseous phase.
authors.affiliation: Department of Chemistry and Biotechnology, Yokohama National University, Hodogaya-ku, Japan.
authors.forename: K
authors.initials: K
authors.lastname: Kobayashi
authors.forename: T
authors.initials: T
authors.lastname: Kaneko
authors.forename: T
authors.initials: T
authors.lastname: Saito
mesh_terms: D000596:Amino Acids / Q000032:analysis / Q000138:chemical synthesis*; D001272:Atmosphere / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry / Q000528:radiation effects; D002248:Carbon Monoxide / Q000737:chemistry* / Q000528:radiation effects; D008401:Gas Chromatography-Mass Spectrometry; D005740:Gases / Q000032:analysis; D006838:Hydrocarbons / Q000032:analysis / Q000138:chemical synthesis; D006868:Hydrolysis; D009584:Nitrogen / Q000737:chemistry* / Q000528:radiation effects; D016083:Planets; D011522:Protons; D014867:Water / Q000737:chemistry*
chemical_list: D000596:Amino Acids; D005740:Gases; D006838:Hydrocarbons; D011522:Protons; D014867:Water; D002245:Carbon Dioxide; D002248:Carbon Monoxide; D009584:Nitrogen