title: Abundances of ethylene oxide and acetaldehyde in hot molecular cloud cores.
abstract: We have searched for millimetre-wave line emission from ethylene oxide (c-C2H4O) and its structural isomer acetaldehyde (CH3CHO) in 11 molecular clouds using SEST. Ethylene oxide and acetaldehyde were detected through multiple lines in the hot cores NGC 6334F, G327.3-0.6, G31.41+0.31, and G34.3+0.2. Acetaldehyde was also detected towards G10.47+0.03, G322.2+0.6, and Orion 3'N, and one ethylene oxide line was tentatively detected in G10.47+0.03. Column densities and rotational excitation temperatures were derived using a procedure which fits the observed line intensifies by finding the minimum chi 2-value. The resulting rotational excitation temperatures of ethylene oxide and acetaldehyde are in the range 16-38 K, indicating that these species are excited in the outer, cooler parts of the hot cores or that the excitation is significantly subthermal. For an assumed source size of 20", the deduced column densities are (0.6-1)x10(14) cm-2 for ethylene oxide and (2-5)x10(14) cm-2 for acetaldehyde. The fractional abundances with respect to H2 are X[c-C2H4O]=(2-6)xl0(-10), and X[CH3CHO]=(0.8-3)x10(-9). The ratio X[CH3CHO]/X[c-C2H4O] varies between 2.6 (NGC 6334F) and 8.5 (G327.3-0.6). We also detected and analysed multiple transitions of CH3OH, CH3OCH3, C2H5OH, and HCOOH. The chemical, and possibly evolutionary, states of NGC 6334F, G327.3-0.6, G31.41+0.31, and G34.3+0.2 seem to be very similar.
authors.affiliation: Onsala Space Observatory, Sweden.
authors.forename: A
authors.initials: A
authors.lastname: Nummelin
authors.forename: J E
authors.initials: JE
authors.lastname: Dickens
authors.forename: P
authors.initials: P
authors.lastname: Bergman
authors.forename: A
authors.initials: A
authors.lastname: Hjalmarson
authors.forename: W M
authors.initials: WM
authors.lastname: Irvine
authors.forename: M
authors.initials: M
authors.lastname: Ikeda
authors.forename: M
authors.initials: M
authors.lastname: Ohishi
mesh_terms: D000079:Acetaldehyde / Q000032:analysis* / Q000737:chemistry; D001256:Astronomy / Q000295:instrumentation; D000431:Ethanol / Q000032:analysis; D005027:Ethylene Oxide / Q000032:analysis* / Q000737:chemistry; D005118:Extraterrestrial Environment; D005561:Formates / Q000032:analysis; D000432:Methanol / Q000032:analysis; D008738:Methyl Ethers / Q000032:analysis; D008956:Models, Chemical; D015394:Molecular Structure; D013057:Spectrum Analysis; D013696:Temperature
chemical_list: D005561:Formates; D008738:Methyl Ethers; C030544:formic acid; D000431:Ethanol; C033413:dimethyl ether; D000079:Acetaldehyde; D005027:Ethylene Oxide; D000432:Methanol