Aliphatic hydrocarbons of the Murchison meteorite.
The indigenous organic compounds of carbonaceous chondrites have been difficult to characterize because of problems arising from terrestrial contamination.  The fall of the Murchison meteorite (CM2) provided pristine samples which allowed the resolution of some prior ambiguities as, for example, in the case of the amino acids.  However, the nature of the aliphatic hydrocarbons has remained unclear.  Shortly after the Murchison fall, one laboratory found them to be mainly cycloalkanes; another found, in order of abundance, branched alkanes, olefins, and cycloalkanes; while a third reported predominantly n-alkanes followed by methyl alkanes and olefins.  We have reinvestigated this question using benzene-methanol as the extraction solvent, silica-gel chromatography for fractionation of the extract, and GC-MS, and IR and NMR spectroscopic techniques for the analyses.  When interior samples were obtained and the analyses carried out under conditions that minimized environmental contaminants, we have found the principal aliphatic components of the Murchison meteorite to be a structurally diverse suite of C15 to C30 branched alkyl-substituted mono-, di-, and tricyclic alkanes.  Comparative analyses were carried out on the Murray (CM2), Allende (CV3), and New Concord (L6) chondrites that illustrate the nature of the contamination problem encountered with carbonaceous chondrites.
Cronin
J R
JR
Department of Chemistry and Center for Meteorite Studies, Arizona State University, Tempe 85287-1604.
Pizzarello
S
S
D000473:Alkanes / Q000032:analysis; D001554:Benzene; D005591:Chemical Fractionation / Q000379:methods; D002625:Chemistry, Organic; D005118:Extraterrestrial Environment; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D006838:Hydrocarbons / Q000032:analysis*; D008279:Magnetic Resonance Imaging; D000432:Methanol; D055601:Organic Chemistry Phenomena; D016082:Solar System; D012997:Solvents; D013055:Spectrophotometry, Infrared
D000473:Alkanes; D006838:Hydrocarbons; D012997:Solvents; D001554:Benzene; D000432:Methanol