Determination of bentazone, dichlorprop, and MCPA in different soils by sodium hydroxide extraction in combination with solid-phase preconcentration.
A method for the extraction of bentazone, dichlorprop, and MCPA in three selected Norwegian soils of different textures is described. Initially three different extraction methods were tested on one soil type. All methods gave recoveries >80% for the pesticide mixture, but extraction with sodium hydroxide in combination with solid-phase preconcentration was used for further recovery tests with soils of different properties spiked at four herbicide concentration levels (0.001-10 microg/g of wet soil). The method was rapid and easy and required a minimum of organic solvents. The recoveries were in the range of 82-109, 80-123, and 45-91% for the soils containing 1.4 (Hole), 2.5 (Kroer), and 37.8% (Froland) organic carbon, respectively. Limits of quantification using GC-MS were 0.0003 microg/g of wet soil for bentazone and 0.0001 microg/g of wet soil for both dichlorprop and MCPA.
Thorstensen
C W
CW
The Norwegian Crop Research Institute, Plant Protection, Høgskoleveien 7, N-1432 As, Norway. christian.thorstensen@planteforsk.no
Christiansen
A
A
D015084:2,4-Dichlorophenoxyacetic Acid / Q000031:analogs & derivatives* / Q000302:isolation & purification; D008456:2-Methyl-4-chlorophenoxyacetic Acid / Q000302:isolation & purification; D001581:Benzothiadiazines / Q000302:isolation & purification; D008401:Gas Chromatography-Mass Spectrometry; D006540:Herbicides / Q000302:isolation & purification*; D012680:Sensitivity and Specificity; D012972:Sodium Hydroxide / Q000494:pharmacology*; D012989:Soil Pollutants / Q000032:analysis / Q000302:isolation & purification*; D013997:Time Factors
D001581:Benzothiadiazines; D006540:Herbicides; D012989:Soil Pollutants; D015084:2,4-Dichlorophenoxyacetic Acid; D012972:Sodium Hydroxide; D008456:2-Methyl-4-chlorophenoxyacetic Acid; C010571:dichlorprop; C002003:bentazone