title: Influence of variable rates of neritic carbonate deposition on atmospheric carbon dioxide and pelagic sediments.
abstract: Short-term imbalances in the global cycle of shallow water calcium carbonate deposition and dissolution may be responsible for much of the observed Pleistocene change in atmospheric carbon dioxide content. However, any proposed changes in the alkalinity balance of the ocean must be reconciled with the sedimentary record of deep-sea carbonates. The possible magnitude of the effect of shallow water carbonate deposition on the dissolution of pelagic carbonate can be tested using numerical simulations of the global carbon cycle. Boundary conditions can be defined by using extant shallow water carbonate accumulation data and pelagic carbonate deposition/dissolution data. On timescales of thousands of years carbonate deposition versus dissolution is rarely out of equilibrium by more than 1.5 x 10(13) mole yr-1. Results indicate that the carbonate chemistry of the ocean is rarely at equilibrium on timescales less than 10 ka. This disequilibrium is probably due to sea level-induced changes in shallow water calcium carbonate deposition/dissolution, an interpretation that does not conflict with pelagic sedimentary data from the central Pacific.
authors.affiliation: Department of Atmospheric, Oceanic and Space Sciences, University of Michigan, Ann Arbor, USA. james_c_g_walker@um.cc.umich.edu
authors.forename: J C
authors.initials: JC
authors.lastname: Walker
authors.forename: B C
authors.initials: BC
authors.lastname: Opdyke
mesh_terms: D001272:Atmosphere / Q000737:chemistry*; D001274:Atmospheric Pressure; D002119:Calcium Carbonate / Q000032:analysis / Q000737:chemistry*; D002244:Carbon / Q000032:analysis / Q000737:chemistry*; D002245:Carbon Dioxide / Q000032:analysis / Q000737:chemistry*; D003198:Computer Simulation; D018534:Earth, Planet; D019419:Evolution, Planetary; D019015:Geologic Sediments / Q000032:analysis / Q000737:chemistry*; D008956:Models, Chemical; D010140:Pacific Ocean; D010163:Paleontology; D012623:Seawater / Q000032:analysis / Q000737:chemistry
chemical_list: D002245:Carbon Dioxide; D002244:Carbon; D002119:Calcium Carbonate