title: Titan's surface and troposphere, investigated with ground-based, near-infrared observations.
abstract: New observations of Titan's near-infrared spectrum (4000-5000 cm-1) combined with points taken from Fink and Larson's (1979) spectrum (4000-12500 cm-1) provide information on Titan's haze, possible clouds, surface albedo, and atmospheric abundance of H2.  In the near-infrared, the main features in Titan's spectrum result from absorption of solar radiation by CH4.  The strength of this absorption varies considerably with wavelength, allowing us to probe various atmospheric levels down to the surface itself by choosing specific wavelengths for analysis.  At 4715 cm-1, the pressure-induced S(1) fundamental band of H2 lies in the wings of CH4 bands.  Based on current values for the CH4 line parameters, Titan's spectrum can be best interpreted with a volume mixing ratio of H2 between 0.5 and  1.0%.  Our observations suggest the existence of an optically thin CH4 cloud layer.  The optical depths that we derive for Titan's haze and clouds are small enough to allow us to sense the surface of Titan at 4900, 6250, and 7700 cm-1.  The most plausible interpretation of the albedos determined at these wavenumbers suggests a surface dominated by "dirty" water ice.  A global ethane ocean is not compatible with these albedos.
authors.affiliation: Physics Department, State University of New York, Stony Brook 11794, USA.
authors.forename: C A
authors.initials: CA
authors.lastname: Griffith
authors.forename: T
authors.initials: T
authors.lastname: Owen
authors.forename: R
authors.initials: R
authors.lastname: Wagener
mesh_terms: D001272:Atmosphere; D005118:Extraterrestrial Environment; D006859:Hydrogen / Q000032:analysis*; D007053:Ice / Q000032:analysis; D008697:Methane / Q000032:analysis*; D008962:Models, Theoretical; D055095:Optics and Photonics; D018539:Saturn; D012542:Scattering, Radiation; D016082:Solar System; D013055:Spectrophotometry, Infrared; D013057:Spectrum Analysis; D014466:Ultraviolet Rays
chemical_list: D007053:Ice; D006859:Hydrogen; D008697:Methane