title: Development and evaluation of a continuous coarse (PM10-PM2.5) particle monitor.
abstract: In this paper, we describe the development and laboratory and field evaluation of a continuous coarse (2.5-10 microm) particle mass (PM) monitor that can provide reliable measurements of the coarse mass (CM) concentrations in time intervals as short as 5-10 min. The operating principle of the monitor is based on enriching CM concentrations by a factor of approximately 25 by means of a 2.5-microm cut point round nozzle virtual impactor while maintaining fine mass (FM)--that is, the mass of PM2.5 at ambient concentrations. The aerosol mixture is subsequently drawn through a standard tapered element oscillating microbalance (TEOM), the response of which is dominated by the contributions of the CM, due to concentration enrichment. Findings from the field study ascertain that a TEOM coupled with a PM10 inlet followed by a 2.5-microm cut point round nozzle virtual impactor can be used successfully for continuous CM concentration measurements. The average concentration-enriched CM concentrations measured by the TEOM were 26-27 times higher than those measured by the time-integrated PM10 samplers [the micro-orifice uniform deposit impactor (MOUDI) and the Partisol] and were highly correlated. CM concentrations measured by the concentration-enriched TEOM were independent of the ambient FM-to-CM concentration ratio, due to the decrease in ambient coarse particle mass median diameter with an increasing FM-to-CM concentration ratio. Finally, our results illustrate one of the main problems associated with the use of real impactors to sample particles at relative humidity (RH) values less than 40%. While PM10 concentrations obtained by means of the MOUDI and Partisol were in excellent agreement, CM concentrations measured by the MOUDI were low by 20%, and FM concentrations were high by a factor of 5, together suggesting particle bounce at low RH.
authors.affiliation: Civil and Environmental Engineering, University of Southern California, Los Angeles 90089, USA.
authors.forename: C
authors.initials: C
authors.lastname: Misra
authors.forename: M D
authors.initials: MD
authors.lastname: Geller
authors.forename: P
authors.initials: P
authors.lastname: Shah
authors.forename: C
authors.initials: C
authors.lastname: Sioutas
authors.forename: P A
authors.initials: PA
authors.lastname: Solomon
mesh_terms: D000397:Air Pollution / Q000032:analysis*; D002947:Cities; D004784:Environmental Monitoring / Q000295:instrumentation*; D004867:Equipment Design; D010316:Particle Size; D012680:Sensitivity and Specificity; D013997:Time Factors