Novel reversion reaction of D-arabino-hexose phenylosotriazole. A useful model in natural glycoside and polysaccharide analysis.
Treatment of D-arabino-hexose phenylosotriazole with conc. hydrochloric acid afforded a new type of alpha- and beta-glycosides of D-erythrose formed by reaction of the 3,6-anhydro derivative with the in situ formed 2-phenyl-4-(formylmethyl)- 1,2,3-triazole.
Hassan
H H
HH
Chemistry Department, Faculty of Science, Alexandria University, Egypt.
El-Husseiny
A H
AH
D002511:Cephalosporins / Q000138:chemical synthesis / Q000737:chemistry; D006027:Glycosides / Q000737:chemistry*; D006851:Hydrochloric Acid / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D008956:Models, Chemical; D011134:Polysaccharides / Q000737:chemistry*; D014230:Triazoles / Q000138:chemical synthesis* / Q000737:chemistry*
D002511:Cephalosporins; D006027:Glycosides; D011134:Polysaccharides; D014230:Triazoles; D006851:Hydrochloric Acid