title: Phosphorus export from an agricultural watershed: linking source and transport mechanisms.
abstract: Many source and transport factors control P loss from agricultural landscapes; however, little information is available on how these factors are linked at a watershed scale. Thus, we investigated mechanisms controlling P release from soil and stream sediments in relation to storm and baseflow P concentrations at four flumes and in the channel of an agricultural watershed. Baseflow dissolved reactive phosphorus (DRP) concentrations were greater at the watershed outflow (Flume 1; 0.042 mg L(-1)) than uppermost flume (Flume 4; 0.028 mg L(-1)). Conversely, DRP concentrations were greater at Flume 4 (0.304 mg L(-1)) than Flume 1 (0.128 mg L(-1)) during stormflow. Similar trends in total phosphorus (TP) concentration were also observed. During stormflow, stream P concentrations are controlled by overland flow-generated erosion from areas of the watershed coincident with high soil P. In-channel decreases in P concentration during stormflow were attributed to sediment deposition, resorption of P, and dilution. The increase in baseflow P concentrations downstream was controlled by channel sediments. Phosphorus sorption maximum of Flume 4 sediment (532 mg kg(-1)) was greater than at the outlet Flume 1 (227 mg kg(-1)). Indeed, the decrease in P desorption between Flumes 1 and 4 sediment (0.046 to 0.025 mg L(-1)) was similar to the difference in baseflow DRP between Flumes 1 and 4 (0.042 to 0.028 mg L(-1)). This study shows that erosion, soil P concentration, and channel sediment P sorption properties influence streamflow DRP and TP. A better understanding of the spatial and temporal distribution of these processes and their connectivity over the landscape will aid targeting remedial practices.
authors.affiliation: USDA-ARS, Pasture Systems and Watershed Management Research Unit, University Park, PA 16802-3702, USA.
authors.forename: R
authors.initials: R
authors.lastname: McDowell
authors.forename: A
authors.initials: A
authors.lastname: Sharpley
authors.forename: G
authors.initials: G
authors.lastname: Folmar
mesh_terms: D000383:Agriculture; D004784:Environmental Monitoring; D019015:Geologic Sediments; D008962:Models, Theoretical; D010758:Phosphorus / Q000032:analysis* / Q000737:chemistry; D011891:Rain; D012995:Solubility; D014872:Water Movements
chemical_list: D010758:Phosphorus