Some furfural derivatives as nitrification inhibitors.
Three series of furfural derivatives, namely N-O-furfural oxime ethers, furfural Schiff bases (furfurylidene anilines), and furfural chalcones, have been synthesized and evaluated for nitrification inhibition activity in laboratory incubation studies in typic Ustocrept soil. Furfural oxime ethers and furfural Schiff bases showed potential activity, but furfural chalcones were only mildly active. N-O-ethyl furfural oxime among the oxime ethers, and furfurylidine-4-chloroaniline among the furfural Schiff bases, performed the best. These two compounds showed more than 50% nitrification inhibition on the 45th day at 5% dose as compared to 73% inhibition by nitrapyrin. Activity of furfural oxime ethers decreased with an increase in carbon atoms in the N-O-alkyl side chain. Introduction of a chlorine atom in the phenyl ring of furfurylidene anilines increased the persistence of their activity. N-O-Ethyl furfural oxime and furfurylidine-4-chloroaniline coated urea performed at par with their application in solution form. Ethyl and N-O-isopropyl oxime, as well as chloro- and nitro- substituted Schiff bases, did not reveal any phytotoxicity (adverse effect on germination) on chickpea seeds (Cicer arietinum) even at the highest dose (40 ppm, soil basis).
Datta
A
A
Division of Agricultural Chemicals, Indian Agricultural Research Institute, New Delhi, 110012, India.
Walia
S
S
Parmar
B S
BS
D002599:Chalcone / Q000737:chemistry / Q000494:pharmacology; D007887:Fabaceae / Q000196:embryology; D005662:Furaldehyde / Q000031:analogs & derivatives* / Q000494:pharmacology; D018525:Germination / Q000187:drug effects; D009584:Nitrogen / Q000037:antagonists & inhibitors* / Q000378:metabolism*; D012545:Schiff Bases / Q000737:chemistry / Q000494:pharmacology
D012545:Schiff Bases; D002599:Chalcone; D005662:Furaldehyde; D009584:Nitrogen