Use of porous glass and silica gel as support media of a surface compound for generation of analytes in gaseous standard mixtures. New method for the determination of the amount of analyte generated.
The paper presents a new method for the determination of a volatile component of a gaseous standard mixture obtained by thermal decomposition of a suitable surface compound. The amount of the analyte generated (under given conditions of thermal decomposition) per unit of mass of the chemically modified material has been determined exclusively on the basis of measuring generation time. Therefore, the total error of the determination of the amount of a standard compound depends solely on the respective errors of weighing the material and measuring its decomposition time (both being direct measurements). This new method permits obtaining a few measuring points on the basis of a single sample of the material with chemically modified surface.
Przyk
E
E
Chemical Faculty, Technical University of Gdańsk, Poland.
Konieczka
P
P
Szczygelska-Tao
J
J
Teschner
R
R
Biernat
J F
JF
Namieśnik
J
J
D002849:Chromatography, Gas; D005740:Gases / Q000737:chemistry*; D005898:Glass; D015203:Reproducibility of Results; D058428:Silica Gel; D012822:Silicon Dioxide; D014835:Volatilization
D005740:Gases; D058428:Silica Gel; D012822:Silicon Dioxide