title: An experimental and computational analysis of the formation of the terminal nitrido complex (eta3-Cp*)2Mo(N)(N3) by elimination of N2 from Cp*2Mo(N3)2: the barrier to elimination is strongly influenced by the exo versus endo configuration of the azide ligand.
authors.affiliation: Department of Chemistry, Columbia University, New York, New York 10027, USA.
authors.forename: J H
authors.initials: JH
authors.lastname: Shin
authors.forename: B M
authors.initials: BM
authors.lastname: Bridgewater
authors.forename: D G
authors.initials: DG
authors.lastname: Churchill
authors.forename: M H
authors.initials: MH
authors.lastname: Baik
authors.forename: R A
authors.initials: RA
authors.lastname: Friesner
authors.forename: G
authors.initials: G
authors.lastname: Parkin
mesh_terms: D001386:Azides / Q000737:chemistry*; D008024:Ligands; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013329:Structure-Activity Relationship; D013816:Thermodynamics; D014961:X-Ray Diffraction
chemical_list: D001386:Azides; D008024:Ligands; D009942:Organometallic Compounds; D008982:Molybdenum; D009584:Nitrogen