title: A new approach to sampling for particle size and chemical species "fingerprinting" of workplace aerosols.
abstract: A commercially-available, high-volume (28.3 Lpm) Andersen-type cascade impactor was modified in order to extend its operational range further into the range of large inhalable particles for purposes of use in an exposure assessment study in the primary nickel production industry. The modification involved incorporating a 10-ppi (pores per inch) porous plastic foam top stage that has a wide penetration curve with a (50)d(ae)-value of approximately 27 microm. This enabled the upper end of the range of the instrument to be extended from about 10 to greater than 70 microm. The inlet of the original instrument was also modified to incorporate the new top stage and provide "representative" aspiration of total airborne particulate with an efficiency of close to 100% over the range of aerodynamic particle sizes of interest. A mathematical inversion algorithm developed in earlier research was modified so that it could be applied to this new instrument. This enabled raw data on particulate material recovered from all stages of the instrument (including the new porous foam top stage) to be used for the determination of continuous particle size distributions, as well as chemical speciation, over the inhalable range. The new instrument was deployed in a pilot field study in the nickel primary production industry by which to demonstrate the potential of the new instrument for generating useful information pertaining to health-relevant aerosol size tractions (e.g., inhalable, thoracic, and respirable), and for soluble, sulphidic, metallic, oxidic and total nickel chemical species groups.
authors.affiliation: Division of Environmental and Occupational Health, School of Public Health, University of Minnesota, Minneapolis, MN 55455, USA.
authors.forename: S M
authors.initials: SM
authors.lastname: Kerr
authors.forename: J H
authors.initials: JH
authors.lastname: Vincent
authors.forename: G
authors.initials: G
authors.lastname: Ramachandran
mesh_terms: D000336:Aerosols; D000395:Air Pollutants, Occupational / Q000032:analysis*; D004784:Environmental Monitoring / Q000295:instrumentation*; D006801:Humans; D016015:Logistic Models; D008669:Metallurgy; D009532:Nickel / Q000032:analysis*; D016273:Occupational Exposure / Q000032:analysis*; D010316:Particle Size
chemical_list: D000336:Aerosols; D000395:Air Pollutants, Occupational; D009532:Nickel