Hydrosilylation of carbonyl compounds using a PhSeSiMe(3)/Bu(3)SnH/AIBN system.
[reaction: see text] When carbonyl compounds were allowed to react with phenyl trimethylsilyl selenide and tributylstannyl hydride in the presence of a catalytic amount of AIBN as a radical initiator, the hydrosilylation of the carbonyl compounds efficiently proceeded to give the corresponding silyl ethers in moderate to good yields.
Nishiyama
Y
Y
Department of Applied Chemistry, Faculty of Engineering, Kansai University, Suita, Osaka 564-8680, Japan. nishiya@ipcku.kansai-u.ac.jp
Kajimoto
H
H
Kotani
K
K
Sonoda
N
N