An experimental and computational analysis of the formation of the terminal nitrido complex (eta3-Cp*)2Mo(N)(N3) by elimination of N2 from Cp*2Mo(N3)2: the barrier to elimination is strongly influenced by the exo versus endo configuration of the azide ligand.
Shin
J H
JH
Department of Chemistry, Columbia University, New York, New York 10027, USA.
Bridgewater
B M
BM
Churchill
D G
DG
Baik
M H
MH
Friesner
R A
RA
Parkin
G
G
D001386:Azides / Q000737:chemistry*; D008024:Ligands; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013329:Structure-Activity Relationship; D013816:Thermodynamics; D014961:X-Ray Diffraction
D001386:Azides; D008024:Ligands; D009942:Organometallic Compounds; D008982:Molybdenum; D009584:Nitrogen