Two photon absorption properties of 1,3,5-tricyano-2,4,6-tris(styryl)benzene derivatives.
Two-photon absorption (TPA) properties of 1,3,5-tricyano-2,4,6-tris(styryl)benzene derivatives have been investigated. Comparison of the absorption and fluorescence spectra reveals that these compounds show large Stokes shifts, which increase gradually as the conjugation length increases. One-photon absorption and excitation spectra are similar except that the latter exhibit several peaks near lambda(max). It is also found that the one- and two-photon-induced fluorescence excitation spectra are quite similar, which indicates that the one- and two-photon allowed-excited states are the same. The peak TPA cross section values (delta(max)) measured with nanosecond pulses by the two-photon-induced fluorescence method are in the range (50-2620) x 10(-50) cm4 s/photon. The delta(max) value increases as the donor strength and conjugation length increase. A linear relationship is observed between delta(max) and beta, and this delta-beta relationship is found to serve as a useful synthetic strategy for the design of novel TPA dyes with the octupolar structure.
Cho
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BR
Molecular Opto-Electronics Laboratory, Department of Chemistry and Center for Electro- & Photo-Responsive Molecules, Korea University, 1-Anamdong, Seoul 136-701, Korea.
Son
K H
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Lee
S H
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Song
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Lee
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Jeon
S J
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Choi
J H
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Lee
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Cho
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