title: Switching enantiofacial selectivities using one chiral source: catalytic enantioselective synthesis of the key intermediate for (20S)-camptothecin family by (S)-selective cyanosilylation of ketones.
authors.affiliation: Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
authors.forename: K
authors.initials: K
authors.lastname: Yabu
authors.forename: S
authors.initials: S
authors.lastname: Masumoto
authors.forename: S
authors.initials: S
authors.lastname: Yamasaki
authors.forename: Y
authors.initials: Y
authors.lastname: Hamashima
authors.forename: M
authors.initials: M
authors.lastname: Kanai
authors.forename: W
authors.initials: W
authors.lastname: Du
authors.forename: D P
authors.initials: DP
authors.lastname: Curran
authors.forename: M
authors.initials: M
authors.lastname: Shibasaki
mesh_terms: D002166:Camptothecin / Q000138:chemical synthesis*; D003486:Cyanides / Q000737:chemistry*; D005947:Glucose / Q000737:chemistry; D013237:Stereoisomerism; D014297:Trimethylsilyl Compounds / Q000737:chemistry*
chemical_list: D003486:Cyanides; D014297:Trimethylsilyl Compounds; C058010:trimethylsilyl cyanide; D005947:Glucose; D002166:Camptothecin