Determination of As, Cd, Cr, and Hg in SRM 2584 (trace elements in indoor dust) by high-resolution inductively coupled plasma mass spectrometry.
Standard reference material (SRM) 2584 (Trace Elements in Indoor Dust) was developed as a reference standard for evaluating field methods and for validating laboratory and reference methods for the assessment of lead contamination and exposure. In addition to lead, the toxic trace elements As, Cd, Cr, and Hg, at approximately 17, 10, 140, and 5 microg g(-1), respectively, have been certified in the SRM. These four analytes were successfully determined by use of high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS). Isobaric interferences at masses of As and Cr were resolved by using the high resolution mode (nominal 8000) and the medium resolution mode (nominal 3000), respectively, of the instrument. The effects of a significant drift in analyte sensitivity in the course of measurement were rectified by use of internal standardization, single spike standard addition, and an optimized analysis sequence. The results were compared with those obtained by instrumental neutron activation analysis (INAA) and isotope dilution inductively coupled plasma mass spectrometry (ID-ICP-MS). The results for the quality control, SRM 2704 (Buffalo River Sediment), were in good agreement with the certified values, indicated by the uncertainty intervals of the measured values overlapping the certified intervals at 95% confidence level.
Yu
L L
LL
Analytical Chemistry Division, National Institute of Standards and Technology, Gaithersburg, MD 20899-8391, USA. lee.yu@nist.gov
Vocke
R D
RD
Murphy
K E
KE
Beck
C M
CM
D001151:Arsenic / Q000032:analysis; D002104:Cadmium / Q000032:analysis; D002857:Chromium / Q000032:analysis; D004391:Dust / Q000032:analysis*; D013058:Mass Spectrometry / Q000379:methods*; D008628:Mercury / Q000032:analysis; D012015:Reference Standards; D014131:Trace Elements / Q000032:analysis*
D004391:Dust; D014131:Trace Elements; D002104:Cadmium; D002857:Chromium; D008628:Mercury; D001151:Arsenic