3-O-acetyl-4-deoxy-4-iodo-beta-D-fructofuranosyl 2,3,6-tri-o-acetyl-4-chloro-4-deoxy-alpha-D-glucopyranoside.
At 160 K, the glucopyranosyl ring of the title compound, C(20)H(28)ClIO(13), has a near-ideal (4)C(1) conformation and the fructofuranosyl ring has a twist (4)T(3) conformation. The two hydroxy groups are involved in intra- and intermolecular hydrogen bonds, with the latter interactions linking the molecules into infinite one-dimensional chains. The absolute configuration of the molecule has been determined.
Linden
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Institute of Organic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland. alinden@oci.unizh.ch
Lee
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CK
Sofian
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D002236:Carbohydrate Conformation; D004187:Disaccharides / Q000737:chemistry*; D005632:Fructose / Q000737:chemistry; D005960:Glucosides / Q000737:chemistry*; D006860:Hydrogen Bonding; D013329:Structure-Activity Relationship; D013395:Sucrose / Q000737:chemistry; D013549:Sweetening Agents / Q000737:chemistry
C438249:3-O-acetyl-4-deoxy-4-iodo-fructofuranosyl 2,3,6-tri-o-acetyl-4-chloro-4-deoxy-glucopyranoside; D004187:Disaccharides; D005960:Glucosides; D013549:Sweetening Agents; D005632:Fructose; D013395:Sucrose