Synthesis of polyoxygenated bicyclic systems containing medium-sized rings from carbohydrates via tandem metathesis of dienynes.
[reaction: see text] Highly functionalized (5-7), (5-8), and (6-8) ring systems have been prepared from carbohydrates via tandem ring-closing metathesis of dienynes.
Boyer
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Unité de Phytopharmacie et Médiateurs Chimiques, I.N.R.A., Route de Saint-Cyr, F-78026 Versailles, France.
Hanna
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Ricard
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D001643:Bridged Bicyclo Compounds / Q000138:chemical synthesis*; D002241:Carbohydrates / Q000737:chemistry*; D018360:Crystallography, X-Ray; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*
D001643:Bridged Bicyclo Compounds; D002241:Carbohydrates; D010100:Oxygen