Speciation and mobility of cadmium in straw and wood combustion fly ash.
Two fly ashes from biomass combustion have been analysed regarding cadmium speciation and mobility. A fly ash from straw combustion contained 10 mg Cd/kg dry matter, and around 50% of the cadmium was leachable in water. The possible main speciation of cadmium in this fly ash was CdCl2. When adding this fly ash to agricultural soil a threat for groundwater contamination and plant uptake is existing. A fly ash from wood chip combustion had 28.6 mg Cd/kg dry matter. In this fly ash, the cadmium was bound more heavily, with only small amounts of cadmium leached in mild extractants. A possible speciation of cadmium in this fly ash was as oxide or as CdSiO3. Long-term effects and accumulation of cadmium could be a problem when adding this fly ash to agricultural or forest soils.
Hansen
H K
HK
Department of Geology and Geotechnical Engineering, The Technical University of Denmark, Lyngby. iggheha@pop.dtu.dk
Pedersen
A J
AJ
Ottosen
L M
LM
Villumsen
A
A
D000383:Agriculture; D018533:Biomass; D002104:Cadmium / Q000032:analysis*; D004784:Environmental Monitoring; D017745:Incineration; D012037:Refuse Disposal; D012989:Soil Pollutants / Q000032:analysis; D014197:Trees; D014873:Water Pollutants / Q000032:analysis; D014934:Wood
D012989:Soil Pollutants; D014873:Water Pollutants; D002104:Cadmium