title: Detection of martian amino acids by chemical derivatization coupled to gas chromatography: in situ and laboratory analysis.
abstract: If there is, or ever was, life in our solar system beyond the Earth, Mars is the most likely place to search for. Future space missions will have then to take into account the detection of prebiotic molecules or molecules of biological significance such as amino acids. Techniques of analysis used for returned samples have to be very sensitive and avoid any chemical or biological contamination whereas in situ techniques have to be automated, fast and low energy consuming. Several possible methods could be used for in situ amino acid analyses on Mars, but gas chromatography would likely be the most suitable. Returned samples could be analyzed by any method in routine laboratory use such as gas chromatography, already successfully performed for analyses of organic matter including amino acids from martian meteorites. The derivatization step, which volatilizes amino acids to perform both in situ and laboratory analysis by gas chromatography, is discussed here.
authors.affiliation: LISA, Universites Paris 7 et 12, CNRS UMR 7583, F 94010 Creteil, France.
authors.forename: C
authors.initials: C
authors.lastname: Rodier
authors.forename: O
authors.initials: O
authors.lastname: Vandenabeele-Trambouze
authors.forename: R
authors.initials: R
authors.lastname: Sternberg
authors.forename: D
authors.initials: D
authors.lastname: Coscia
authors.forename: P
authors.initials: P
authors.lastname: Coll
authors.forename: C
authors.initials: C
authors.lastname: Szopa
authors.forename: F
authors.initials: F
authors.lastname: Raulin
authors.forename: C
authors.initials: C
authors.lastname: Vidal-Madjar
authors.forename: M
authors.initials: M
authors.lastname: Cabane
authors.forename: G
authors.initials: G
authors.lastname: Israel
authors.forename: M F
authors.initials: MF
authors.lastname: Grenier-Loustalot
authors.forename: M
authors.initials: M
authors.lastname: Dobrijevic
authors.forename: D
authors.initials: D
authors.lastname: Despois
mesh_terms: D000596:Amino Acids / Q000032:analysis*; D002849:Chromatography, Gas; D018559:Exobiology / Q000295:instrumentation*; D005118:Extraterrestrial Environment; D018535:Mars; D012987:Soil / Q000032:analysis; D013026:Space Flight / Q000295:instrumentation
chemical_list: D000596:Amino Acids; D012987:Soil