Stabilization of an elevated heavy metal contaminated site.
Heavy metal contamination is a common problem that is encountered at many uncontrolled sites. Immobilization is seen as a promising technology for heavy metal remediation. Here, we report a remediation case study of an elevated and multi-metal contaminated site containing Cd, Cu, Ni, Pb, and Zn. In a laboratory test, when the soil was stabilized with reagent grade stabilizers (CaHPO(4) and CaCO(3)), the toxicity characteristic leaching procedure (TCLP) extractable concentrations of Cd, Cu, Pb, and Zn were reduced by more than 87%. The greatest reduction was shown with Pb (99.8%). In the field, Ca(H(2)PO(4))(2) due to lower cost and higher solubility replaced CaHPO(4). The TCLP results of the field treatment showed that the extractable concentrations of Cd, Cu, Pb, and Zn were significantly reduced after 30 days of stabilization. The reduction ratios were 98% (Cd), 97% (Cu), 99% (Pb), and 96% (Zn). Although, the reduction ratio of Ni was only 65%, the average extractable concentration was still less than 4.0mg/l. The percent reduction can, therefore, be considered reasonable. The significant reduction of extractable metal concentrations showed that the stabilizers, a combination of Ca(H(2)PO(4))(2) and CaCO(3), successfully immobilized heavy metals on the site.
Wang
Y M
YM
Department of Civil Engineering, National Pingtung University of Science and Technology, Pingtung 912, Taiwan, ROC. wangym@mail.npust.edu.tw
Chen
T C
TC
Yeh
K J
KJ
Shue
M F
MF
D002254:Carbonates / Q000737:chemistry*; D004787:Environmental Pollution / Q000517:prevention & control; D019216:Metals, Heavy / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis*; D012995:Solubility
D002254:Carbonates; D019216:Metals, Heavy; D010710:Phosphates; D012989:Soil Pollutants