Playing the Keyboard of Fluorine Chemistry(,).
Organometallic fluorides of main group and transition elements are described starting with monocyclopentadienyl derivatives of the group 4 metals and their adducts with AlMe(3). Host-guest type compounds such as [(eta(5)-C(5)Me(4)Et)TiF(3)](4)CaF(2) and supramolecular assemblies such as Ag(S(4)(CN)(2))(2)AsF(6) are also observed. Finally some aluminum-fluorine compounds including derivatives of aluminum(I) are described.
Roesky
Herbert W.
HW
Institut für Anorganische Chemie der Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.