New Metal-Intercalated Layered Vanadyl Phosphates, M(x)()VOPO(4).yH(2)O (M = Ag, Cu, Zn).
Three new, mixed-valent layered vanadyl phosphates, Ag(0.43)VOPO(4).2H(2)O (AgVPO), Cu(0.16)VOPO(4).2.5H(2)O (CuVPO), and Zn(0.11)VOPO(4).2.5H(2)O (ZnVPO), have been synthesized hydrothermally and their structures determined by single-crystal X-ray diffraction: AgVPO is triclinic, space group P&onemacr;, a = 6.287(1), b = 6.283(1), and c = 13.240(1) Å, alpha = 80.98(1), beta = 86.58(1) and gamma = 90.00(1) degrees, Z = 4; CuVPO is triclinic, space group P&onemacr;, a = 6.260(2), b = 6.249(3), and c = 7.257(1) Å, alpha = 83.62(3), beta = 73.99(2), and gamma = 90.13(4) degrees, Z = 2; ZnVPO is triclinic, space group P&onemacr;, a = 6.252(1), b = 6.248(2), and c = 7.339(3) Å, alpha = 83.24(4), beta = 73.93(2), and gamma = 90.00(2) degrees, Z = 2. The structures are related to that of VOPO(4).2H(2)O. Metal powders have been found to be effective both as reductants and as countercations.
Ayyappan
P.
P
Central Research and Development, DuPont Company, Experimental Station, Wilmington, Delaware 19880-0356.
Ramanan
A.
A
Torardi
C. C.
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