Modeling nickel hydrogenases: synthesis and structure of a distorted octahedral complex with an unprecedented [NiS(4)H(2)] core.
Alvarez
H M
HM
Department of Chemistry, The University of North Carolina at Charlotte, 9201 University City Boulevard, Charlotte, North Carolina 28223, USA.
Krawiec
M
M
Donovan-Merkert
B T
BT
Fouzi
M
M
Rabinovich
D
D
D001665:Binding Sites; D001881:Borates / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D003901:Desulfovibrio / Q000201:enzymology; D004563:Electrochemistry / Q000295:instrumentation; D006864:Hydrogenase / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D019906:Nuclear Magnetic Resonance, Biomolecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D013055:Spectrophotometry, Infrared
D001881:Borates; D009942:Organometallic Compounds; C444159:nickel bis(2-mercapto-1-methylimidazolyl)borate; D009532:Nickel; C043296:nickel-iron hydrogenase; D006864:Hydrogenase