title: Synthesis of Functionalized Deuterioallylic Compounds.
abstract: Functionalized deuterioallylic compounds were efficiently prepared by reaction of the corresponding propargylic derivative with the Schwartz reagent followed by hydrolysis of the adduct with D(2)O. The Z-3-deuterio-2-propenylstannane, prepared in pure form for the first time, is a useful reagent for the preparation of deuterioallylic compounds which cannot be synthesized by hydrozirconation of the corresponding derivatives.
authors.affiliation: Laboratoire de Synthèses et Activations de Biomolécules, ESA 6052, ENSCR, Avenue du Général Leclerc, 35700 Rennes, France.
authors.forename: David
authors.initials: D
authors.lastname: Orain
authors.forename: Jean-Claude
authors.initials: JC
authors.lastname: Guillemin