Synthesis and Characterization of New Binuclear Co(0) Complexes with Diphosphinoamine Ligands. A Potential Approach for Asymmetric Pauson-Khand Reactions.
The synthesis of P-N-P bidentate ligands and the evaluation, based on IR and X-ray data, of their pi-acceptor properties in the complexes derived from phenylacetylene-dicobalt hexacarbonyl have been carried out. In addition, the reactivity of these complexes in the Pauson-Khand reaction has been examined.
Gimbert
Yves
Y
Université Joseph Fourier de Grenoble, Chimie Recherche et Service de Cristallographie (LEDSS), 38041 Grenoble Cedex, France.
Robert
Frédéric
F
Durif
André
A
Averbuch
Marie-Thérèse
MT
Kann
Nina
N
Greene
Andrew E.
AE