title: Carboracycles: Macrocyclic Compounds Composed of Carborane Icosahedra Linked by Organic Bridging Groups.
abstract: A family of macrocyclic compounds are described, together with their precursors. These cycles are composed of icosahedral carboranes linked via their carbon vertices through 1,3-trimethylene, alpha,alpha'-1,3-xylylene, or alpha,alpha'-2,6-lutidylene groups. The compounds cyclo-(1,3-trimethylene-1',2'-closo-1',2'-C(2)B(10)H(10))(4) (6a), cyclo-(1,3-trimethylene-1',2'-closo-9',12'-dimethyl-1',2'-C(2)B(10)H(8))(4) (6b), cyclo-(1,3-trimethylene-1',2'-closo-1',2'-C(2)B(10)H(10))(3) (9), cyclo-(alpha,alpha'-1,3-xylylene-1',2'-closo-1',2'-C(2)B(10)H(10))(2) (11a), cyclo-(alpha,alpha'-1,3-xylylene-1',7'-closo-1',7'-C(2)B(10)H(10))(2) (11b), cyclo-(alpha,alpha'-1,3-xylylene-1',7'-closo-9',10'-dimethyl-1,7-C(2)B(10)H(8))(2) (11c), cyclo-(alpha,alpha'-1,3-xylylene-1',2'-closo-1',2'-C(2)B(10)H(10))(4) (12), cyclo-(alpha,alpha'-1,3-xylylene-1',7'-closo-1',7'-C(2)B(10)H(10))(3) (13), cyclo-(alpha,alpha'-2,6-lutidylene-1',7'-closo-1',7'-C(2)B(10)H(10))(2) (19), and cyclo-(alpha,alpha'-2,6-lutidylene N-oxide-1',7'-closo-1',7'-C(2)B(10)H(10))(2) (20) have been synthesized. The structures of 6a, 6b, 9, 11a, 11b, 11c, 12, and 19 have been determined by X-ray crystallography. Crystal data: for 6a, triclinic, space group P&onemacr;, a = 11.131(2) Å, b = 12.642(2) Å, c = 12.996(2) Å, alpha = 84.383(6) degrees, beta = 65.884(6) degrees, gamma = 97.292(5) degrees, Z = 1, R = 0.079; for 6b, monoclinic, space group P2(1)/a, a = 13.500(2) Å, b = 31.141(3) Å, c = 13.831(2) Å, beta = 99.90(1) degrees, Z = 2, R = 0.097; for 11a, monoclinic, space group C2/c, a = 14.5682(8) Å, b = 14.5046(8) Å, c = 16.1998(8) Å, beta = 95.631(2) degrees, Z = 4, R = 0.081; for 11b, monoclinic, space group P2(1)/n, a = 11.650(2) Å, b = 10.606(2) Å, c = 11.730(2) Å, beta = 104.951(6) degrees, Z = 2, R = 0.069; for 11c, orthorhombic, space group Pbca, a = 12.532(2) Å, b = 14.271(2) Å, c = 18.143(3) Å, Z = 4, R = 0.076; for 19, orthorhombic, space group Pcab (No. 61, standard setting Pbca), a = 11.0428(6) Å, b = 11.3785(6) Å, c = 22.533(1) Å, Z = 4, R = 0.074.
authors.affiliation: Department of Chemistry and Biochemistry, 405 Hilgard Avenue, University of California, Los Angeles, California 90095.
authors.forename: Wei
authors.initials: W
authors.lastname: Jiang
authors.forename: Igor T.
authors.initials: IT
authors.lastname: Chizhevsky
authors.forename: Mark D.
authors.initials: MD
authors.lastname: Mortimer
authors.forename: Weilin
authors.initials: W
authors.lastname: Chen
authors.forename: Carolyn B.
authors.initials: CB
authors.lastname: Knobler
authors.forename: S. E.
authors.initials: SE
authors.lastname: Johnson
authors.forename: F. A.
authors.initials: FA
authors.lastname: Gomez
authors.forename: M. Frederick
authors.initials: MF
authors.lastname: Hawthorne