ArtTAX--a new mobile spectrometer for energy-dispersive micro X-ray fluorescence spectrometry on art and archaeological objects.
A newly developed spectrometer for energy-dispersive micro X-ray fluorescence spectrometry has been designed for the demands of archaeometry. ArtTAX combines the advantages of non-destructive and sensitive multi-elemental analysis at sub-mm resolution with the possibility of working outside the laboratory. The spectrometer consists of an air-cooled, low-power molybdenum tube, new generation polycapillary X-ray optics, a silicon drift detector without the need for liquid-nitrogen cooling, a CCD camera, and three light diodes for sample positioning. The motor-driven measurement head is fixed on a x,y,z-flexible tripod support which can be assembled and dismantled within minutes. The spot size of the primary X-ray beam was determined to be 94 microm for the Cu(Kalpha) energy, the detection limits are in a range of a few tens of microg g(-1) for the medium energy-range in glass. Additional open helium purging in the excitation and detection paths enables the determination of elements down to sodium, thus avoiding vacuum conditions or a size-limiting sample chamber. A selection of qualitative and quantitative results on pigment, metal, glass, and enamel analyses are presented to show the potential of ArtTAX in the field of art and archaeology.
Bronk
H
H
Technische Universität Berlin, Institut für Anorganische und Analytische Chemie, Germany. bronoecc@mailszrz.zrz.tu-berlin.de
Röhrs
S
S
Bjeoumikhov
A
A
Langhoff
N
N
Schmalz
J
J
Wedell
R
R
Gorny
H E
HE
Herold
A
A
Waldschläger
U
U