title: Preparation and Structures of Crystalline Aromatic Cation-Radical Salts. Triethyloxonium Hexachloroantimonate as a Novel (One-Electron) Oxidant.
abstract: Triethyloxonium hexachloroantimonate [Et(3)O(+)SbCl(6)(-)] is a selective oxidant of aromatic donors (ArH), and it allows the facile preparation and isolation of crystalline paramagnetic salts [ArH(+)(*), SbCl(6)(-)] for the X-ray structure determination of various aromatic cation radicals. The mechanistic relationship between the Meerwein salt [Et(3)O(+)SbCl(6)(-)] and the pure Lewis acid oxidant SbCl(5) is based on a prior ethyl transfer from oxygen to chlorine within the ion pair.
authors.affiliation: Department of Chemistry, University of Houston, Houston, Texas 77204-5641.
authors.forename: R.
authors.initials: R
authors.lastname: Rathore
authors.forename: A. S.
authors.initials: AS
authors.lastname: Kumar
authors.forename: S. V.
authors.initials: SV
authors.lastname: Lindeman
authors.forename: J. K.
authors.initials: JK
authors.lastname: Kochi