(1-(Dimethylamino)-2-(diphenylphosphino)ethane)(eta(3)-1-arylallyl)palladium Tetrafluoroborates. Preparation, Isomeric Equilibria, and Correlations of NMR Chemical Shifts with Hammett Substituent Constants.
13C NMR differences of chemical shifts (delta(X) - delta(H)) of allyl carbon atoms in a series of trans-(1-(diphenylphosphino)-2-(dimethylamino)ethane)(eta(3)-1-arylallyl)palladium tetrafluoroborates, X ranging from NO(2) to OMe, correlate very well with sigma Hammett constants for C-1 and with sigma(+) for C-3, this carbon atom being in a trans relationship with the positively charged nitrogen atom.
Malet
Ramón
R
Department of Chemistry, Universitat Autònoma de Barcelona, Bellaterra, 08193 Barcelona, Spain.
Moreno-Mañas
Marcial
M
Parella
Teodor
T
Pleixats
Roser
R