Lowering inversion barriers of buckybowls by benzannelation of the rim: synthesis and crystal and molecular structure of 1,2-dihydrocyclopenta[b,c]dibenzo[g,m]corannulene.
[structure: see text]. The title compound (3) has been synthesized by a non-pyrolytic route providing a 36% isolated yield in the final step. X-ray crystal structure determination shows that 3 crystallizes with one solvating molecule of toluene and exhibits slightly lower curvature than the parent cyclopentacorannulene. DFT calculations predict a substantially lower bowl-to-bowl inversion barrier for 3 than for dihydro-cyclopentacorannulene, and this is confirmed by dynamic 1H NMR experiments.
Marcinow
Z
Z
Department of Chemistry and Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA.
Sygula
A
A
Ellern
A
A
Rabideau
P W
PW