title: Solvation of Copper(II) Ions in Liquid Ammonia.
abstract: X-ray absorption fine structure (XAFS) measurements have been performed at -50 degrees C on a 0.4 mol dm(-)(3) copper(II) nitrate solution in liquid ammonia. Extended X-ray absorption fine structure (EXAFS) spectroscopy was used to determine the coordination number and bond distances for the solvated copper(II) ion in solution. The equatorial ammonia nitrogens are located 2.00 Å from the copper and the axial nitrogen 2.19 Å from the copper. However, it was not possible from the EXAFS analysis alone to conclude whether there was one or two axial nitrogens. Therefore, X-ray absorption near-edge structure (XANES) spectroscopy was combined with discrete variational Xalpha (DV-Xalpha) molecular orbital calculations for a series of five- and six-coordinated models to determine the coordination number and the geometry. The experimental XANES spectrum was best reproduced by a model where the copper(II) ion is pentacoordinated in liquid ammonia in a square pyramidal geometry with the copper(II) ion lifted above the average nitrogen plane.
authors.affiliation: Department of Chemistry, Fukuoka University, Fukuoka 814-80, Japan.
authors.forename: M.
authors.initials: M
authors.lastname: Valli
authors.forename: S.
authors.initials: S
authors.lastname: Matsuo
authors.forename: H.
authors.initials: H
authors.lastname: Wakita
authors.forename: T.
authors.initials: T
authors.lastname: Yamaguchi
authors.forename: M.
authors.initials: M
authors.lastname: Nomura