title: Synthesis and Characterization of New Binuclear Co(0) Complexes with Diphosphinoamine Ligands. A Potential Approach for Asymmetric Pauson-Khand Reactions.
abstract: The synthesis of P-N-P bidentate ligands and the evaluation, based on IR and X-ray data, of their pi-acceptor properties in the complexes derived from phenylacetylene-dicobalt hexacarbonyl have been carried out. In addition, the reactivity of these complexes in the Pauson-Khand reaction has been examined.
authors.affiliation: Université Joseph Fourier de Grenoble, Chimie Recherche et Service de Cristallographie (LEDSS), 38041 Grenoble Cedex, France.
authors.forename: Yves
authors.initials: Y
authors.lastname: Gimbert
authors.forename: Frédéric
authors.initials: F
authors.lastname: Robert
authors.forename: André
authors.initials: A
authors.lastname: Durif
authors.forename: Marie-Thérèse
authors.initials: MT
authors.lastname: Averbuch
authors.forename: Nina
authors.initials: N
authors.lastname: Kann
authors.forename: Andrew E.
authors.initials: AE
authors.lastname: Greene