Synthesis and Photophysical Properties of Porphyrin-Functionalized Molecular Clips.
Different clip-shaped receptor molecules functionalized at one side-wall with a porphyrin unit have been synthesized by a condensation involving a diamino glucoluril derivative and a porphyrin dione. A similar condensation reaction with a porphyrin tetraone resulted in porphyrin molecule with two receptor sites. The binding and photophysical properties of some of these porphyrin-receptor molecules are described.
Reek
Joost N. H.
JN
Department of Organic Chemistry, NSR Center, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands, and School of Chemistry, The University of Sydney, NSW 2006, Australia.
Rowan
Alan E.
AE
Crossley
Maxwell J.
MJ
Nolte
Roeland J. M.
RJ