Electrolytic Partial Fluorination of Organic Compounds. 30.(1) Drastic Improvement of Anodic Monofluorination of 2-Substituted 1,3-Oxathiolan-5-ones Using the Novel Fluorine Source Et(4)NF.4HF.
The highly regioselective anodic monofluorination of 2-substituted 1,3-oxathiolan-5-ones was successfully carried out using a novel supporting electrolyte, Et(4)NF.4HF, while use of a conventional supporting electrolyte, Et(3)N.3HF, resulted in no formation or extremely low yields of the fluorinated products.
Higashiya
Seiichiro
S
Department of Electronic Chemistry, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan, and Department of Research and Development, Morita Chemical Industries Co., Ltd., Higashi-mikuni, Yodogawa-ku, Osaka 532-0002, Japan.
Narizuka
Satoru
S
Konno
Akinori
A
Maeda
Tomoko
T
Momota
Kunitaka
K
Fuchigami
Toshio
T