title: The spin temperature of NH3 in Comet C/1999S4 (LINEAR).
abstract: A high-dispersion spectrum of Comet C/1999S4 (LINEAR) was obtained in the optical region with the high-dispersion spectrograph on the Subaru telescope when the comet was 0.863 astronomical units from the Sun before its disintegration. We obtained high signal-to-noise ratio emission lines of the cometary NH2 bands from which an ortho-to-para ratio (OPR) of 3.33 +/- 0.07 was derived on the basis of a fluorescence excitation model. Assuming that cometary NH2 mainly originates from ammonia through photodissociation, the derived OPR of NH2 molecules should reflect that of ammonia, which provides information on the environment of molecular formation or condensation and of the thermal history of cometary ices. Assuming that the OPR of ammonia in comets was unchanged in the nucleus, the derived spin temperature of ammonia (28 +/- 2 kelvin) suggests that a formation region of the cometary ammonia ice was between the orbit of Saturn and that of Uranus in the solar nebula.
authors.affiliation: Gunma Astronomical Observatory, 6860-86 Nakayama, Takayama, Agatsuma, Gunma 377-0702, Japan. kawakita@astron.pref.gunma.jp
authors.forename: H
authors.initials: H
authors.lastname: Kawakita
authors.forename: J
authors.initials: J
authors.lastname: Watanabe
authors.forename: H
authors.initials: H
authors.lastname: Ando
authors.forename: W
authors.initials: W
authors.lastname: Aoki
authors.forename: T
authors.initials: T
authors.lastname: Fuse
authors.forename: S
authors.initials: S
authors.lastname: Honda
authors.forename: H
authors.initials: H
authors.lastname: Izumiura
authors.forename: T
authors.initials: T
authors.lastname: Kajino
authors.forename: E
authors.initials: E
authors.lastname: Kambe
authors.forename: S
authors.initials: S
authors.lastname: Kawanomoto
authors.forename: K
authors.initials: K
authors.lastname: Noguchi
authors.forename: K
authors.initials: K
authors.lastname: Okita
authors.forename: K
authors.initials: K
authors.lastname: Sadakane
authors.forename: B
authors.initials: B
authors.lastname: Sato
authors.forename: M
authors.initials: M
authors.lastname: Takada-Hidai
authors.forename: Y
authors.initials: Y
authors.lastname: Takeda
authors.forename: T
authors.initials: T
authors.lastname: Usuda
authors.forename: E
authors.initials: E
authors.lastname: Watanabe
authors.forename: M
authors.initials: M
authors.lastname: Yoshida
mesh_terms: D000641:Ammonia; D007053:Ice; D019110:Meteoroids; D013057:Spectrum Analysis; D013696:Temperature
chemical_list: D007053:Ice; D000641:Ammonia