Reactions of Elemental Indium and Indium(I) Bromide with Nickel-Bromine Bonds: Structure of (eta(5)-C(5)H(5))(Ph(3)P)Ni-InBr(2)(O=PPh(3)).
The reactions of elemental indium and In(I)Br with the carbonyl-free organonickel complexes (eta(5)-C(5)H(5))(PR(3))Ni-Br (R = CH(3), C(6)H(5)) have been studied in some detail. Either redox reactions to yield the ionic products [(eta(5)-C(5)H(5))(PR(3))(2)Ni][InBr(4)] (2a,b) occurred or the Ni-In bound systems (eta(5)-C(5)H(5))(PPh(3))Ni-InBr(2)(OPPh(3)) (3a) and [(eta(5)-C(5)H(5))(PPh(3))Ni](2)InBr (4) were obtained in good yields. The new compounds were characterized by elemental analysis, NMR, and mass spectrometry. A short Ni-In bond of 244.65(9) pm was found for 3a. Single crystal data for (eta(5)-C(5)H(5))(PPh(3))Ni-InBr(2)(OPPh(3)).THF (3a): triclinic, P1 with a = 1124.9(3), b = 1353.2(4), c = 1476.4(4) pm, alpha = 94.74(2) degrees, beta = 101.78(2) degrees, gamma = 109.64(1) degrees, V = 2044(1) x 10(6) pm(3), Z = 2, R = 0.053 (R(w) = 0.063).
Weiss
Jurij
J
Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstrasse 4, D-85747 Garching, Germany.
Priermeier
Thomas
T
Fischer
Roland A.
RA