title: Electrolytic removal of nitrate from crop residues.
abstract: The Controlled Ecological Life Support System (CELSS) resource recovery system, which is a waste-processing system,uses aerobic and anaerobic bioreactors to recover plants nutrients and secondary foods from the inedible biomass. Crop residues contain a significant amount of nitrate. There are actually two major problems concerning nitrate: 1) both CELSS biomass production and resource recovery consume large quantities of nitric acid, and 2) nitrate causes a variety of problems in both aerobic and anaerobic bioreactors. The nitrate anion causes several problems in the resource recovery system in such a way that removal prior to the process is highly desirable. The technique proposed to remove nitrate from potato inedible biomass leachate and to satisfy the nitric acid demand was a four-compartment electrolytic cell. In order to establish the electrolytic cell performance variables, experiments were carried out using potato crop residue aqueous leachate as the diluate solution. The variables studied were the potato biomass leachate composition and electrical properties, preparation of compartment solutions to be compatible with the electrolytic system, limiting current density, nutrients removal rates as a function of current density, fluid hydrodynamic conditions, applied voltage, and process operating time during batch recirculation operation. Results indicated that the limiting current density (maximum operating current density) was directly proportional to the solution electrical conductivity an a power function of the linear fluid velocity in the range between 0.083 and 0.403 m/s. During the electrolytic cell once-through operation, the nitrate, potassium, and other nutrient removal rates were proportional to the current density and were inversely proportional to fluid velocity. The removal of monovalent ions was found to be higher than divalent ones. Under batch recirculation operation at constant applied voltage of 4.5 and 8.5 V, it was found that the nutrient removal rates were independent of applied voltage, but were proportional to the ions concentration and operating time.
authors.affiliation: University of Puerto Rico, Mayaguez Campus, Chemical Engineering Department, Mayaguez, PR 00681. gu_colon@rumac.uprm.edu
authors.forename: G
authors.initials: G
authors.lastname: Colon
authors.forename: J C
authors.initials: JC
authors.lastname: Sager
mesh_terms: D000838:Anions; D018533:Biomass; D019149:Bioreactors; D003956:Dialysis / Q000379:methods*; D018504:Ecological Systems, Closed; D004553:Electric Conductivity; D004572:Electrolysis / Q000379:methods*; D008021:Life Support Systems; D008567:Membranes, Artificial; D009566:Nitrates / Q000032:analysis / Q000737:chemistry*; D017942:Nitric Acid / Q000032:analysis / Q000737:chemistry; D011188:Potassium / Q000032:analysis / Q000737:chemistry; D011198:Solanum tuberosum; D018505:Waste Management / Q000379:methods*
chemical_list: D000838:Anions; D008567:Membranes, Artificial; D009566:Nitrates; D017942:Nitric Acid; D011188:Potassium