title: Short Enantioselective Total Syntheses of the Piperidine Alkaloids (S)-Coniine and (2R,6R)-trans-Solenopsin A via Catalytic Asymmetric Imine Hydrosilylation.
abstract: The enantioselective syntheses of (S)-coniine and (2R,6R)-trans-solenopsin A are reported. The key step in both syntheses is the catalytic asymmetric hydrosilylation of a cyclic imine.
authors.affiliation: Massachusetts Institute of Technology, Cambridge, Massachusetts 02139.
authors.forename: Matthew T.
authors.initials: MT
authors.lastname: Reding
authors.forename: Stephen L.
authors.initials: SL
authors.lastname: Buchwald