title: Modeling nickel hydrogenases: synthesis and structure of a distorted octahedral complex with an unprecedented [NiS(4)H(2)] core.
authors.affiliation: Department of Chemistry, The University of North Carolina at Charlotte, 9201 University City Boulevard, Charlotte, North Carolina 28223, USA.
authors.forename: H M
authors.initials: HM
authors.lastname: Alvarez
authors.forename: M
authors.initials: M
authors.lastname: Krawiec
authors.forename: B T
authors.initials: BT
authors.lastname: Donovan-Merkert
authors.forename: M
authors.initials: M
authors.lastname: Fouzi
authors.forename: D
authors.initials: D
authors.lastname: Rabinovich
mesh_terms: D001665:Binding Sites; D001881:Borates / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D003901:Desulfovibrio / Q000201:enzymology; D004563:Electrochemistry / Q000295:instrumentation; D006864:Hydrogenase / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D019906:Nuclear Magnetic Resonance, Biomolecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D013055:Spectrophotometry, Infrared
chemical_list: D001881:Borates; D009942:Organometallic Compounds; C444159:nickel bis(2-mercapto-1-methylimidazolyl)borate; D009532:Nickel; C043296:nickel-iron hydrogenase; D006864:Hydrogenase