Screening for sarin in air and water by solid-phase microextraction-gas chromatography-mass spectrometry.
A method of screening air and water samples for the chemical-warfare agent Sarin is developed using solid-phase microextraction (SPME)-gas chromatography (GC)-mass spectrometry (MS). The SPME field kit sampler is ideal for collecting air and water samples in the field and transporting samples safely to the laboratory. The sampler also allows the sample to be introduced into the GC-MS system without further sample preparation. Results of the tests with Sarin using the SPME technique indicate that a sample collection time of 5 min is sufficient to detect 100 ng/L of Sarin in air. For water samples, Sarin is detected at a concentration of 12 microg/mL or higher. This method is ideal for screening samples for quick response situations.
Schneider
J F
JF
Argonne National Laboratory, Energy Systems Division, IL 60439, USA.
Boparai
A S
AS
Reed
L L
LL
D000388:Air / Q000032:analysis*; D002619:Chemical Warfare Agents / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D012524:Sarin / Q000032:analysis*; D014867:Water / Q000737:chemistry*
D002619:Chemical Warfare Agents; D014867:Water; D012524:Sarin