title: Complexes of Strong Bidentate Lewis Acids Derived from 2,7-Bis(1,1-dimethylethyl)fluorene-1,8-diol.
abstract: Treatment of 2,7-bis(1,1-dimethylethyl)fluorene-1,8-diol (3) with 2 equiv of TiCl(4) converts the two OH groups into OTiCl(3) groups and thereby yields bis(trichlorotitanium phenoxide) 7, a structurally well-defined reagent that holds two sites of strong Lewis acidity in close proximity. Bidentate Lewis acid 7 forms a crystalline 1:2 complex with 4,4'-dimethylbenzophenone. An X-ray crystallographic study revealed that each atom of titanium binds only one molecule of ketone to form an unusual pentacoordinate adduct with an approximately trigonal bipyramidal geometry. Treatment of fluorenediol 3 with 2 equiv of Al(CH(2)CH(3))(3) does not yield the expected bis(diethylaluminum phenoxide) 8, but rather its dimer 9. Formation of diverse reagents 7 and 9 from the same precursor demonstrates that the strategy of converting organic compounds with suitably oriented hydroxyl groups into the corresponding metal alkoxides is a particularly versatile and effective way to make strong, structurally well-defined multidentate Lewis acids.
authors.affiliation: Département de Chimie, Université de Montréal, Montréal, Québec, H3C 3J7 Canada.
authors.forename: Okba
authors.initials: O
authors.lastname: Saied
authors.forename: Michel
authors.initials: M
authors.lastname: Simard
authors.forename: James D.
authors.initials: JD
authors.lastname: Wuest