title: Electrolytic Partial Fluorination of Organic Compounds. 30.(1) Drastic Improvement of Anodic Monofluorination of 2-Substituted 1,3-Oxathiolan-5-ones Using the Novel Fluorine Source Et(4)NF.4HF.
abstract: The highly regioselective anodic monofluorination of 2-substituted 1,3-oxathiolan-5-ones was successfully carried out using a novel supporting electrolyte, Et(4)NF.4HF, while use of a conventional supporting electrolyte, Et(3)N.3HF, resulted in no formation or extremely low yields of the fluorinated products.
authors.affiliation: Department of Electronic Chemistry, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan, and Department of Research and Development, Morita Chemical Industries Co., Ltd., Higashi-mikuni, Yodogawa-ku, Osaka 532-0002, Japan.
authors.forename: Seiichiro
authors.initials: S
authors.lastname: Higashiya
authors.forename: Satoru
authors.initials: S
authors.lastname: Narizuka
authors.forename: Akinori
authors.initials: A
authors.lastname: Konno
authors.forename: Tomoko
authors.initials: T
authors.lastname: Maeda
authors.forename: Kunitaka
authors.initials: K
authors.lastname: Momota
authors.forename: Toshio
authors.initials: T
authors.lastname: Fuchigami