title: Nickel- and Zinc-Promoted [2 + 2 + 2] Cycloaddition of Diynes and alpha,beta-Enones.
abstract: The [2 + 2 + 2] cycloaddition of diynes and enones occurred in the presence of both nickel and zinc together. This binary metal-mediated reaction had two interesting features: (1) a terminally unsubstituted diyne reacted with an enone to give an aromatic compound with the concomitant incorporation of two hydrogen atoms abstracted from an expected 1,3-diene product into another molecule of the starting enone and (2) a trimethylsilyl-substituted diyne reacted with an equimolar amount of enone to regioselectively afford a 1,3-diene, in which the trimethylsilyl group is adjacent to the carbonyl group.
authors.affiliation: Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya 467-8603, Japan.
authors.forename: Shin-ichi
authors.lastname: Ikeda Si
authors.forename: Hitomi
authors.initials: H
authors.lastname: Watanabe
authors.forename: Yoshiro
authors.initials: Y
authors.lastname: Sato