title: Induced thermolysis of tert-butyl phenylperacetates by thiophenol: simultaneous occurrence of homolysis and single electron transfer.
abstract: Thermolysis of tert-butyl phenylperacetates in the presence of thiophenol takes place via dual mechanism. The two-bond homolysis indicates rho(+)(4)= -1.16, testifying to polar transition states. The single electron transfer yields a radical anion intermediate which undergoes fragmentation with rho(ET) = 1.01.
authors.affiliation: Department of Chemistry and Center for Chemical Dynamics, Inha University, Inchon 402-751, South Korea. sungsoo@inha.ac.kr
authors.forename: S S
authors.initials: SS
authors.lastname: Kim
authors.forename: A
authors.initials: A
authors.lastname: Tuchkin
authors.forename: C S
authors.initials: CS
authors.lastname: Kim