title: 2-Methyl-3-furanthiol and methional are possible off-flavors in stored orange juice: aroma-similarity, NIF/SNIF GC-O, and GC analyses.
abstract: The occurrence of methional in fresh orange juice, and possible occurrence of beta-damascenone in heated orange juice, has been previously suggested. Here we report on the occurrence of 2-methyl-3-furanthiol in the headspace, collected by solid-phase micro-extraction, of fresh, pasteurized, and stored orange juice. The contents of 2-methyl-3-furanthiol and methional were quantified, and the relative level of beta-damascenone was estimated, in the headspace of fresh, pasteurized, and stored orange juices using the nasal impact frequency (NIF) and surface of NIF (SNIF) GC-Olfactometry procedure. 2-Methyl-3-furanthiol concentrations were 2 ng/L in fresh and pasteurized Shamuti orange juice, and 270 ng/L in stored juice of the same variety. Methional concentrations were 550, 830, and 11,550 ng/L in fresh, pasteurized, and stored pasteurized juices, respectively. beta-Damascenone content appeared to have increased during pasteurization and storage. Aroma-similarity experiments strongly suggest that 2-methyl-3-furanthiol and methional, at the levels found in stored orange juice (21 days at 35 degrees C), contribute to stored orange juice off-flavor.
authors.affiliation: Institute of Biochemistry, Food Science and Nutrition, Faculty of Agricultural, Food and Environmental Quality Sciences, The Hebrew University of Jerusalem, P.O. Box 12, Rehovot 76-100, Israel.
authors.forename: Y
authors.initials: Y
authors.lastname: Bezman
authors.forename: R L
authors.initials: RL
authors.lastname: Rouseff
authors.forename: M
authors.initials: M
authors.lastname: Naim
mesh_terms: D000447:Aldehydes / Q000032:analysis*; D001628:Beverages / Q000032:analysis*; D002849:Chromatography, Gas; D002957:Citrus; D005663:Furans / Q000032:analysis*; D009812:Odorants; D013438:Sulfhydryl Compounds / Q000032:analysis*
chemical_list: D000447:Aldehydes; D005663:Furans; D013438:Sulfhydryl Compounds; C008390:methional; C443400:2-methyl-3-furanthiol