Poly[cadmium(II)-mu-4,4'-oxydianiline-N:N'-di-mu-thiocyanato-N:S].
The title polymeric complex, [Cd(SCN)(2)(C(12)H(12)N(2)O)], exhibits a three-dimensional framework in which each Cd(II) atom is bridged by two eta-1,3-(SCN)(-) groups, forming a double-stranded chain. The unique Cd(II) atom lies on an inversion centre and the coordination sphere is completed by two terminal N atoms from two different 4,4'-oxydianiline (4,4'-Oda) ligands, furnishing a CdS(2)N(4) octahedral geometry. Adjacent polymeric double-stranded chains are linked via the 4,4'-Oda ligands, which lie across twofold rotation axes.
Chen
H J
HJ
Department of Chemistry, Jinan University, Guangzhou 510632, People's Republic of China. hjchen@public.guangzhou.gd.cn
Yu
W J
WJ
Chen
X M
XM
Zheng
W J
WJ