A comparison of tailpipe, dilution tunnel, and wind tunnel data in measuring motor vehicle PM.
Comparison between particle size distributions recorded directly at the tailpipes of both diesel and gasoline vehicles and measurements made using a conventional dilution tunnel reveals two problems incurred when using the latter method for studying particle number emissions. One is the potential for particulate matter (PM) artifacts originating from hydrocarbon material stored in the transfer hose connecting the tailpipe to the dilution tunnel, and the other is the particle coagulation (as well as condensation and chemical changes) that occurs during the transport. Both are potentially generic to current PM emissions measurement practices. The artifacts typically occur as a nanoparticle mode (10-30 nm) that is 2-4 orders of magnitude larger than what is present in the vehicle exhaust and can easily be mistaken for a similar mode that can arise from the nucleation of hydrocarbon or SO4(2-) components in the exhaust under appropriate dilution rates. Wind tunnel measurements are in good agreement with those made directly from the tailpipe and substantiate the potential for artifacts. They reveal PM levels for the recent model port fuel injection (PFI) gasoline vehicles tested that are small compared with the ambient background particle level during steady-state driving. The PM emissions recorded for drive cycles such as the Federal Test Procedure (FTP) and US06 occur primarily during acceleration, as has been previously noted. Light-duty diesel vehicle emissions normally exhibit a single lognormal mode centered between 55 and 80 nm, although a nonartifact nanoparticle mode in some cases appears at a 70-mph cruise up a grade.
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Research Laboratory, Ford Motor Company, Dearborn, Michigan 48121, USA.
Chase
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D000392:Air Movements; D000393:Air Pollutants / Q000032:analysis*; D016477:Artifacts; D006838:Hydrocarbons / Q000032:analysis; D010316:Particle Size; D012016:Reference Values; D015203:Reproducibility of Results; D013464:Sulfuric Acids / Q000032:analysis; D001335:Vehicle Emissions / Q000032:analysis*
D000393:Air Pollutants; D006838:Hydrocarbons; D013464:Sulfuric Acids; D001335:Vehicle Emissions; C033158:sulfuric acid