A new function of the (mu(3)-S) ligand in an Fe(4)S(4) cluster: synthesis and structure of the high-nuclearity Mo/Fe/S cluster, Fe(DMF)Cl(Cl(4)-cat)(2)-Mo(2)Fe(2)S(4)(PEt(3))(2)ClFe(4)S(4)(PEt(3))(3)(CO)(6)Cl.
Han
J
J
Department of Chemistry, The University of Michigan, Ann Arbor, Michigan 48109-1055, USA.
Coucouvanis
D
D
D004798:Enzymes / Q000737:chemistry; D058085:Iron Compounds / Q000737:chemistry*; D008024:Ligands; D008667:Metalloproteins / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D018716:Molecular Mimicry; D008982:Molybdenum / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*
D004798:Enzymes; D058085:Iron Compounds; D008024:Ligands; D008667:Metalloproteins; D013455:Sulfur; D008982:Molybdenum