A highly substituted germacranolide from Leontodon cichoraceus.
A re-investigation of subaerial parts of Leontodon cichoraceus (Ten.) Sanguin. yielded the new germacrane-type sesquiterpenoid 15-beta-D-glucopyranosyl-8-[p-(beta-D-glucopyranosyloxy)phenylacetyl]-salonitenolide. The structure was established by APCI mass spectrometry and 1D- and 2D-NMR spectroscopy. A survey by HPLC-DAD and HPLC-MS gave no signs of this compound in 23 other taxa of Leontodon.
Zidorn
C
C
Institut für Pharmazie, Abteilung für Pharmakognosie, Universität Innsbruck, Austria. Christian.H.Zidorn@uibk.ac.at
Ellmerer-Müller
E P
EP
Dobner
M J
MJ
Stuppner
H
H
D000890:Anti-Infective Agents / Q000737:chemistry / Q000302:isolation & purification*; D019659:Asteraceae / Q000737:chemistry*; D002851:Chromatography, High Pressure Liquid; D006027:Glycosides / Q000737:chemistry / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D008958:Models, Molecular; D008968:Molecular Conformation; D012717:Sesquiterpenes / Q000737:chemistry / Q000302:isolation & purification*; D045788:Sesquiterpenes, Germacrane
D000890:Anti-Infective Agents; D006027:Glycosides; D012717:Sesquiterpenes; D045788:Sesquiterpenes, Germacrane; C432449:germacranolide