Waste form corrosion modeling: comparison with experimental results.
Results of leaching experiments using active and inactively simulated HLW glass in concentrated NaCl solution are described. Measured solution concentrations of glass components, fission products and actinides are compared with computed data. The computed pH value corresponds with the findings from experiments with inactively simulated glass samples. Moreover, the concentrations of silica and strontium can be described adequately by reaction path modelling. The computed U concentration is explained by the precipitation of schoepite or Na2U2O7. The computed Am concentration significantly exceeds the measured data. This may be attributed to sorption processes on corrosion products of the glass, which are relevant also for lanthanide elements under the conditions of the experiments. This hypothesis is tested by solid solution approaches and by computing sorption of Am onto SiO2 precipitates.
Kienzler
B
B
Forschungszentrum Karlsruhe, Institut für Nukleare Entsorgung, INE, Germany. kienzler@ine.fzk.de
Luckscheiter
B
B
Wilhelm
S
S
D008671:Actinoid Series Elements / Q000737:chemistry; D000327:Adsorption; D005898:Glass / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D008962:Models, Theoretical; D010100:Oxygen; D011850:Radioactive Waste; D012822:Silicon Dioxide / Q000737:chemistry; D012965:Sodium Chloride / Q000737:chemistry*; D012995:Solubility; D014501:Uranium / Q000737:chemistry*
D008671:Actinoid Series Elements; D011850:Radioactive Waste; D012965:Sodium Chloride; D014501:Uranium; D012822:Silicon Dioxide; D010100:Oxygen