Diastereoselective kinetic protonation of exocyclic enolates derived from bicyclic ketones: control of stereochemistry mediated by bridging heteroatoms.
Davies
H M
HM
Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, NY 14260, USA. hdavies@acsu.buffalo.edu
Hodges
L M
LM
Gregg
T M
TM
D001952:Bridged-Ring Compounds / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry; D006572:Heterocyclic Compounds, Bridged-Ring / Q000737:chemistry; D006844:Hydrocarbons, Cyclic / Q000737:chemistry; D007659:Ketones / Q000737:chemistry*; D007700:Kinetics; D011522:Protons; D013237:Stereoisomerism
D001952:Bridged-Ring Compounds; D002264:Carboxylic Acids; D006572:Heterocyclic Compounds, Bridged-Ring; D006844:Hydrocarbons, Cyclic; D007659:Ketones; D011522:Protons