Twinned dichlorobis(2,6-dichloropyrazine-N(4))zinc(II).
For crystals of the title compound, [ZnCl(2)(C(4)H(2)Cl(2)N(2))(2)], metric considerations suggest a monoclinic unit cell. However, the symmetry of the diffraction pattern shows the crystals to be triclinic, with very similar lattice constants a and b, and alpha and beta. All crystals examined were twinned. The discrepancy between the reliability indices for merging in the monoclinic lattice metric symmetry and the triclinic crystal symmetry constitutes an indicator for the volume ratio between the components. The asymmetric unit contains three independent molecules. At the molecular level, the compound shows a distorted tetrahedral coordination around one Zn atom.
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Institut für Anorganische Chemie, RWTH Aachen, Prof.-Pirlet-Strasse 1, 52074 Aachen, Germany.
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D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*
D009942:Organometallic Compounds; C443735:dichlorobis(2,6-dichloropyrazine-N(4))zinc(II)