title: Efficient enantioselective hydrosilylation of ketones catalyzed by air stable copper fluoride-phosphine complexes.
abstract: [reaction: see text] Copper(II) fluoride-chiral diphosphine systems catalyze the hydrosilylation of several ketones with moderate to excellent enantioselectivities. An oxygen acceleration effect was observed and led to a practical protocol with low catalyst loading.
authors.affiliation: Laboratoire de Chimie Organique et Médicinale, Place Louis Pasteur, 1, Université catholique de Louvain, B-1348 Louvain-La-Neuve, Belgium.
authors.forename: S
authors.initials: S
authors.lastname: Sirol
authors.forename: J
authors.initials: J
authors.lastname: Courmarcel
authors.forename: N
authors.initials: N
authors.lastname: Mostefai
authors.forename: O
authors.initials: O
authors.lastname: Riant