Insecticidal sesquiterpene polyol esters from Celastrus angulatus.
Three insecticidal sesquiterpene polyol esters were isolated from the root bark of Celastrus angulatus by bioassay-guided fractionation. Their chemical structures were elucidated as 1 alpha,2 alpha-diacetoxy-8 beta-isobutanoyloxy- 9 alpha-benzoyloxy-13-(alpha-methyl)butanoyloxy-4 beta, 6 beta-dihydroxy-beta-dihydroagarofuran (1), 1 alpha,2 alpha-diacetoxy-8 beta-(beta- furancarbonyloxy)-9 alpha-benzoyloxy-13-isobutanoyloxy-4 beta, 6 beta-dihydroxy-beta-dihydroagarofuran (2) and 1 alpha, 6 beta, 8 alpha,13-tetraacetoxy-9 alpha-benzoyloxy-2 alpha-hydroxy-beta-dihydroagarofuran (3) mainly by analyses NMR and MS spectral data.
Wenjun
W
W
Department of Plant Protection, Northwestern Agricultural University, Yangling, Shanxi 712100, People's Republic of China. wenjun_wu@263.net
Mingan
W
W
Wenming
Z
Z
Jinbo
Z
Z
Zhiqing
J
J
Zhaonong
H
H
D000818:Animals; D029753:Celastraceae / Q000737:chemistry*; D004952:Esters / Q000737:chemistry* / Q000302:isolation & purification / Q000494:pharmacology; D007313:Insecta / Q000187:drug effects; D007306:Insecticides / Q000737:chemistry* / Q000302:isolation & purification / Q000494:pharmacology; D010938:Plant Oils / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry; D012717:Sesquiterpenes / Q000737:chemistry* / Q000302:isolation & purification / Q000494:pharmacology
D004952:Esters; D007306:Insecticides; D010938:Plant Oils; D011108:Polymers; D012717:Sesquiterpenes; C024617:polyol; C097139:Celastrus oil