Optically active molecule-based magnets: enantioselective self-assembling, optical, and magnetic properties.
In this short communication we describe the synthesis and the optical and magnetic properties of optically active three dimensional (3D) bimetallic [Cr-Mn] networks [[Delta Cr(III) Delta Mn(II)(ox)(3)][Delta Ru(II)(bpy)(3)]ClO(4)](n)1 - Delta, [[Lambda Cr(III)Lambda Mn(II)(ox)(3)][Lambda Ru(II) (bpy)(3)]ClO(4)](n) 1 - Lambda and [[Delta Cr(III)Delta Mn(II)(ox)(3)][Delta Ru(II)(bpy)(2)p p y]](n) 2 - Delta,[[Lambda Cr(III)Lambda Mn(II)(ox)(3)][Lambda Ru(II)(bpy)(2)ppy]](n) 2 - Lambda (ox = oxalate, bpy = bipyridine, ppy = phenyl-pyridine).
Gruselle
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Chimie Inorganique et Matériaux Moléculaires CIM2 Unité CNRS 7071, Université Pierre et Marie Curie, Paris, France. gruselle@ccr.jussieu.fr
Andres
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Malezieux
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Brissard
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Train
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C
Verdaguer
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