A three-dimensional inorganic/organic hybrid vanadium oxide complex with pentacoordinate CoII, [CoV2O6(4,4'-bipy)].
The title compound, poly[[cobalt(II)-mu-(hexaoxodivanadium-O:O')]-mu-bipyridine-N:N'], [CoV2O6(C10H8N2)], has been prepared hydrothermally and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The structure consists of bimetallic oxide layers, [Co2V4O12], linked through 4,4'-bipyridine ligands into a three-dimensional network.
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Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.
Naruke
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Yamase
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