Pretransitional behavior of dielectric permittivity on approaching a clearing point in a mixture of nematogens with antagonistic configurations of dipoles.
The results of studies of static dielectric permittivity epsilon(T) in the isotropic phase of 4-cyano-4-pentylalkylbiphenyl and n-p-methoxybenzylidene-p'-butylaniline (5CB-MBBA) mixtures are presented. 5CB and MBBA are nematogens with antagonistic permanent dipole moments configurations. An increase in MBBA concentration strongly decreases the pretransitional effect. However, a derivative analysis detected the existence of a pretransitional anomaly even if its weakness made a straightforward epsilon(T) fit impossible. The obtained anomalies can be well portrayed by fluidlike equations, isomorphic to that applied in critical binary mixtures. Every time the same value of the specific heat critical exponent alpha approximately 0.5 was obtained. A preliminary discussion of the influence of the permanent dipole configuration on the pretransitional behavior of dielectric permittivity was also possible.
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A. Chelkowski Institute of Physics, Silesian University, ulnica Uniwersytecka 4, 40-007 Katowice, Poland.
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