title: Triradical thermochemistry from collision-induced dissociation threshold energy measurements. The heat of formation of 1,3,5-trimethylenebenzene.
abstract: A method for measuring the heats of formation of triradicals using energy-resolved collision-induced dissociation (CID) of chloro-substituted biradical negative ions is described. This method is applied to the determination of the heat of formation of 1,3,5-trimethylenebenzene, which was generated by CID of the 5-chloromethyl-m-xylylene ion. The measured CID threshold energy for chloride loss (0.83 +/- 0.07 eV) is combined with the electron affinity of the 5-chloromethyl-m-xylylene biradical (1.120 +/- 0.059 eV) to give a heat of formation of the triradical of 111.0 +/- 4.1 kcal/mol that agrees with the bond additivity value of 109.3 +/- 2.1 kcal/mol. The measured heat of formation indicates a third C-H bond dissociation energy (BDE) in 1,3,5-trimethylbenzene of 88.2 +/- 5.0 kcal/mol, indistinguishable from the C-H BDE in toluene or the first or second C-H BDEs in m-xylene. The results are in agreement with the predictions made on the basis of simple qualitative and high-level molecular orbital theories that predict negligible interaction between the unpaired electrons in the high-spin triradical.
authors.affiliation: The Department of Chemistry, Purdue University, West Lafayette, IN 47907-1393, USA.
authors.forename: L A
authors.initials: LA
authors.lastname: Hammad
authors.forename: P G
authors.initials: PG
authors.lastname: Wenthold