Total synthesis of (2S,3S,5S,10S)-6,9-epoxynonadec-18-ene-7,10-diol and formal total synthesis of (+)-trans-kumausyne from D-arabinose.
Gadikota
R R
RR
Department of Chemistry, The Ohio State University, Columbus, OH 43210, USA.
Callam
C S
CS
Lowary
T L
TL
D000475:Alkenes / Q000138:chemical synthesis*; D001089:Arabinose / Q000737:chemistry*; D002855:Chromatography, Thin Layer; D004852:Epoxy Compounds / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism
C445820:(2,3,5,10)-6,9-epoxynonadec-18-ene-7,10-diol; D000475:Alkenes; D004852:Epoxy Compounds; D007202:Indicators and Reagents; D001089:Arabinose