title: 1,4- and 1,3-dipolar reactivity of alpha-alkoxycarbonylcycloimmonium N-aminides with dipolarophiles: synthesis of new imidazo[2,1-f][1,2,4]triazinium inner salts.
abstract: 2-Alkoxycarbonylazolium N-aminides are interesting species, as they have the potential to act as efficient 1,4-dipole equivalents when they react with heterocumulenes, such as iso(thio)cyanates and carbodiimides. These reactions give heterobetaines containing the imidazo[2,1-f][1,2,4]triazinium system, in a formal [4 + 2] cyclocondensation process. These N-aminides, however, can also behave as 1,3-dipoles when they react with isocyanates to afford a cycloadduct that, depending on the position of alkoxycarbonyl group, can undergo a reversion process or a ring expansion to the more stable heterobetaine system.
authors.affiliation: Departamento de Química Orgánica, Universidad de Alcalá,28871-Alcalá de Henares, Madrid, Spain.
authors.forename: J
authors.initials: J
authors.lastname: Valenciano
authors.forename: E
authors.initials: E
authors.lastname: Sánchez-Pavón
authors.forename: A M
authors.initials: AM
authors.lastname: Cuadro
authors.forename: J J
authors.initials: JJ
authors.lastname: Vaquero
authors.forename: J
authors.initials: J
authors.lastname: Alvarez-Builla