Secoiridoid glycosides from Gentiana scabra.
Two new secoiridoid glycosides, 4'-O-beta-D-glucopyranosylgentiopicroside (1) and 6'-O-beta-D-glucopyranosylgentiopicroside (2), have been isolated from the rhizomes and roots of Gentiana scabra together with three known compounds, olivieroside, 1-O-beta-D-glucopyranosylamplexine, and benzyl alcohol O-alpha-L-arabinopyranosyl (1 --> 6)-beta-D-glucopyranoside. The structures of 1 and 2 were elucidated using chemical and physicochemical (MS and NMR) studies.
Kakuda
R
R
Department of 2nd Analytical Chemistry, Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai, Miyagi 981-8558, Japan.
Iijima
T
T
Yaoita
Y
Y
Machida
K
K
Kikuchi
M
M
D002681:China; D002849:Chromatography, Gas; D002851:Chromatography, High Pressure Liquid; D029965:Gentianaceae / Q000737:chemistry*; D006027:Glycosides / Q000737:chemistry / Q000302:isolation & purification*; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D010946:Plants, Medicinal / Q000737:chemistry*; D011714:Pyrans / Q000737:chemistry / Q000302:isolation & purification*; D027343:Rhizome / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet
C446140:4'-O-beta-D-glucopyranosylgentiopicroside; C446141:6'-O-beta-D-glucopyranosylgentiopicroside; D006027:Glycosides; D011714:Pyrans