Synthesis of aziridine-2,2-dicarboxylates via 1,4-addition of N,O-(bistrimethylsilyl)hydroxylamine to alpha,beta-unsaturated malonates.
Cardillo
G
G
Dipartimento di Chimica "G. Ciamician" and C.S.F.M., Università di Bologna, Via Selmi 2, 40126 Bologna. cardillo@ciam.unibo.it
Gentilucci
L
L
Gianotti
M
M
Perciaccante
R
R
Tolomelli
A
A
D001388:Aziridines / Q000138:chemical synthesis*; D003500:Cyclization; D003998:Dicarboxylic Acids / Q000138:chemical synthesis*; D006868:Hydrolysis; D006898:Hydroxylamines / Q000737:chemistry*; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D008314:Malonates / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D014297:Trimethylsilyl Compounds / Q000737:chemistry*
D001388:Aziridines; D003998:Dicarboxylic Acids; D006898:Hydroxylamines; D007202:Indicators and Reagents; D008314:Malonates; D014297:Trimethylsilyl Compounds