title: Use of iron monocarboxylates in the two-step preparation of poly(ester-urethane)s.
abstract: Five different iron monocarboxylates were used as catalysts in the two-step preparation route of lactic acid based poly(ester-urethane)s (PEU). In the first step, a hydroxyl-terminated poly(lactic acid) prepolymer was prepared, which in the second step was linked with 1,6-hexamethylene diisocyanate. The resulting polymers were characterized by titration, size exclusion chromatography, differential scanning calorimetry, and nuclear magnetic resonance spectroscopy, and the mechanical properties were tested as well. Iron monocarboxylates proved to be efficient catalysts in the preparation of a hydroxyl-terminated prepolymer (lowest acid number obtained: 0.08). The same catalyst systems proved also to be highly efficient in the linking step yielding a high molar mass PEU. Semicrystalline PEUs could be prepared at 160 and 180 degrees C by using the iron acetate of different oxidation state. PEU prepared at 200 degrees C was amorphous, which could be related to racemization during the polycondensation. By using the fluorinated iron acetate amorphous PEUs was prepared at all reaction temperatures. The molar mass of the prepolymers and the PEUs increased as a function of the polycondensation temperature for all catalysts used. The highest weight-average molar masses (M(w)) were obtained by using the fluorinated iron acetate.
authors.affiliation: Laboratory of Polymer Technology, Abo Akademi University, Biskopsgatan 8, 20500 Abo, Finland.
authors.forename: M
authors.initials: M
authors.lastname: Stolt
authors.forename: K
authors.initials: K
authors.lastname: Hiltunen
authors.forename: A
authors.initials: A
authors.lastname: Södergård
mesh_terms: D002152:Calorimetry, Differential Scanning; D002264:Carboxylic Acids / Q000737:chemistry; D002384:Catalysis; D003460:Crystallization; D007501:Iron / Q000737:chemistry; D019344:Lactic Acid / Q000737:chemistry; D008970:Molecular Weight; D011091:Polyesters / Q000138:chemical synthesis* / Q000737:chemistry; D011108:Polymers / Q000737:chemistry; D011140:Polyurethanes / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D002264:Carboxylic Acids; D011091:Polyesters; D011108:Polymers; D011140:Polyurethanes; D019344:Lactic Acid; C033616:poly(lactide); D007501:Iron