Syntheses of anolignans A and B using ruthenium-catalyzed cross-enyne metathesis.
Anolignans A and B were synthesized using ruthenium-catalyzed cross-enyne metathesis as the key steps. The 1,3-diene moieties of these natural products were constructed by the introduction of the methylene parts of ethylene into alkyne using Grubbs' catalyst.
Mori
Miwako
M
Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan.
Tonogaki
Keisuke
K
Nishiguchi
Nao
N
D000480:Alkynes / Q000737:chemistry; D002384:Catalysis; D017705:Lignans / Q000138:chemical synthesis*; D018894:Reverse Transcriptase Inhibitors / Q000138:chemical synthesis*; D012428:Ruthenium / Q000737:chemistry
D000480:Alkynes; D017705:Lignans; D018894:Reverse Transcriptase Inhibitors; C090325:anolignan A; C090326:anolignan B; D012428:Ruthenium