Hexa-mu-chloro-mu4-oxo-tetrakis[(4,5-dihydro-2-methyl-1,2-thiazole-kappaN)copper(II)].
The title compound, [Cu4Cl6O(C4H7NS)4], was obtained by the reaction of CuCl2*2H2O with 2-methyl-2-thiazoline in methanol. The complex has twofold crystallographic symmetry and contains a tetrahedron of four Cu(II) atoms coordinating a central mu4-O atom, with the six edges of the tetrahedron bridged by Cl atoms. Distance ranges are Cu-O 1.917 (4)-1.920 (4) and Cu-Cl 2.370 (2)-2.445 (2) A.
Bolos
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CA
Laboratory of Inorganic Chemistry, Department of Chemistry, Aristotle University of Thessaloniki, GR54006 Thessaloniki, Greece.
Christidis
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PC