Ab initio study on far-infrared spectra of dihalodiammine complexes of palladium(II) and platinum(II).
The far-infrared spectra of dihalodiammine complexes of Pd(II) and Pt(II) are calculated using ab initio method at RHF/LANL2DZ level. The calculated vibrational frequencies are in good agreement with the experimental ones except for M-N stretching frequencies in cis-M(NH3)2X2 complexes, and the reason for the deviation is discussed.
Zhang
Lin
L
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Jiangsu, People's Republic of China.
Wei
Hua
H
Zhang
Yu
Y
Guo
Zijian
Z
Zhu
Longgen
L
D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D014732:Vibration
D009942:Organometallic Compounds; D010984:Platinum; D010165:Palladium