title: Ab initio study on far-infrared spectra of dihalodiammine complexes of palladium(II) and platinum(II).
abstract: The far-infrared spectra of dihalodiammine complexes of Pd(II) and Pt(II) are calculated using ab initio method at RHF/LANL2DZ level. The calculated vibrational frequencies are in good agreement with the experimental ones except for M-N stretching frequencies in cis-M(NH3)2X2 complexes, and the reason for the deviation is discussed.
authors.affiliation: State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Jiangsu, People's Republic of China.
authors.forename: Lin
authors.initials: L
authors.lastname: Zhang
authors.forename: Hua
authors.initials: H
authors.lastname: Wei
authors.forename: Yu
authors.initials: Y
authors.lastname: Zhang
authors.forename: Zijian
authors.initials: Z
authors.lastname: Guo
authors.forename: Longgen
authors.initials: L
authors.lastname: Zhu
mesh_terms: D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D014732:Vibration
chemical_list: D009942:Organometallic Compounds; D010984:Platinum; D010165:Palladium