New chlorinated diphenyl ethers from an Aspergillus species.
Two new chlorinated diphenyl ethers (5, 6) have been isolated from the culture broth of an Aspergillus species obtained from leaf litter, together with the known benzophenone sulochrin (1), the grisandiene geodin (2), and the diphenyl ether asterric acid (3). The structure of another metabolite, methyl asterrate (4), was confirmed by single-crystal X-ray structure analysis.
Hargreaves
Jaih
J
Department of Chemistry and Soil Science and Plant Nutrition Group, Faculty of Agriculture, University of Western Australia, 35 Stirling Highway, Crawley, Western Australia, 6009, Australia.
Park
Ja-on
JO
Ghisalberti
Emilio L
EL
Sivasithamparam
Krishnapillai
K
Skelton
Brian W
BW
White
Allan H
AH
D000935:Antifungal Agents / Q000737:chemistry / Q000302:isolation & purification* / Q000494:pharmacology; D000969:Antinematodal Agents / Q000737:chemistry / Q000302:isolation & purification* / Q000494:pharmacology; D001230:Aspergillus / Q000737:chemistry* / Q000201:enzymology; D001315:Australia; D001565:Benzoates / Q000737:chemistry / Q000302:isolation & purification / Q000494:pharmacology; D001572:Benzofurans / Q000737:chemistry / Q000302:isolation & purification / Q000494:pharmacology; D002845:Chromatography; D018360:Crystallography, X-Ray; D019906:Nuclear Magnetic Resonance, Biomolecular; D010105:Oxygenases / Q000032:analysis / Q000378:metabolism; D010636:Phenols / Q000737:chemistry / Q000302:isolation & purification / Q000494:pharmacology; D010647:Phenyl Ethers / Q000737:chemistry / Q000302:isolation & purification* / Q000494:pharmacology
D000935:Antifungal Agents; D000969:Antinematodal Agents; D001565:Benzoates; D001572:Benzofurans; D010636:Phenols; D010647:Phenyl Ethers; C449744:methyl asterrate; C449746:methyl chloroasterrate; C449745:methyl dichloroasterrate; C052047:geodin; C078941:asterric acid; C111298:sulochrin; D010105:Oxygenases; C044391:ligninase