Regioselective oxidative liberation of aryl-substituted tripyrrinone metal complexes from N-confused porphyrin.
[reaction: see text] A Cu(II) complex of the first aryl-substituted tripyrrinone derivative, 14-benzoyl-5,10-diphenyl-1-oxo-tripyrrinato copper(II) (3-Cu) was obtained in the reaction of N-confused tetraphenylporphyrin (NCTPP) and Cu(OAc)(2) in refluxing toluene, and subsequent treatment with acid afforded a free tripyrrolic ligand that could bind a variety of transition metals.
Furuta
Hiroyuki
H
PRESTO, Japan Science and Technology Corporation (JST). hfuruta@kuchem.kyoto-u.ac.jp
Maeda
Hiromitsu
H
Osuka
Atsuhiro
A
D001654:Bile Pigments / Q000737:chemistry / Q000378:metabolism; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D009942:Organometallic Compounds / Q000737:chemistry; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000737:chemistry; D011758:Pyrroles / Q000737:chemistry*; D013057:Spectrum Analysis
D001654:Bile Pigments; D009942:Organometallic Compounds; D011166:Porphyrins; D011758:Pyrroles; C409084:tetraphenylporphyrin; D003300:Copper