Coordination chemistry umpolung: a gallane ligand on a phosphine lewis acceptor.
Pentaphenylphosphinophosphonium trifluoromethanesulfonate reacts with amino-iminogall(I)ane to effect quantitative substitution of Ph3P and formation of the first complex of a gallium Lewis base on a phosphine Lewis acid.
Burford
Neil
N
Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada.
Ragogna
Paul J
PJ
Robertson
Katherine N
KN
Cameron
T Stanley
TS
Hardman
Ned J
NJ
Power
Philip P
PP