title: [Synthesis of N-acetylglucosamine beta-aryl glycosides catalyzed by crown ethers].
abstract: Glycosylation of phenols of various structure with alpha-D-glucosaminyl chloride peracetate in a solid phase-liquid system catalyzed by crown compounds was studied. The highest yields of aryl beta-glycosides were observed at room temperature in acetonitrile using anhydrous potassium carbonate as a base. The optimum phenol-glycosyl donor-base-crown ether ratio was 1:1:1:0.2.
authors.affiliation: Vernadsky Taurida National University, ul. Yaltinskaya 4, Simferopol, 95007 Ukraine.
authors.forename: V O
authors.initials: VO
authors.lastname: Kur'ianov
authors.forename: T A
authors.initials: TA
authors.lastname: Chupakhina
authors.forename: A E
authors.initials: AE
authors.lastname: Zemliakov
authors.forename: S A
authors.initials: SA
authors.lastname: Kotliar
authors.forename: G L
authors.initials: GL
authors.lastname: Kamalov
authors.forename: V Ia
authors.initials: VIa
authors.lastname: Chirva
mesh_terms: D000117:Acetylglucosamine / Q000737:chemistry*; D002384:Catalysis; D004988:Ethers, Cyclic / Q000737:chemistry*; D006027:Glycosides / Q000138:chemical synthesis*
chemical_list: D004988:Ethers, Cyclic; D006027:Glycosides; D000117:Acetylglucosamine