title: [Polymerization of 4-nitrophenylacrylate under microwave heating conditions].
abstract: The 2,2'-azodiisobutyronitrile-induced radical polymerization in solution of 4-nitrophenyl acrylate was performed under microwave heating at a frequency of 2.45 GHz. This approach allows the control of the molecular mass of poly(4-nitrophenyl acrylate) used in the synthesis of multivalent glycoconjugates. It was found that the polymerization of 4-nitrophenyl acrylate under microwave irradiation results in products with a narrower molecular mass distribution than at conventional heating.
authors.affiliation: Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, ul. Miklukho-Maklaya 16/10, GSP Moscow, 117997 Russia.
authors.forename: M A
authors.initials: MA
authors.lastname: Dikusar
authors.forename: I V
authors.initials: IV
authors.lastname: Kubrakova
authors.forename: A A
authors.initials: AA
authors.lastname: Chinarev
authors.forename: N V
authors.initials: NV
authors.lastname: Bovin
mesh_terms: D000180:Acrylic Resins / Q000138:chemical synthesis* / Q000737:chemistry; D006361:Heating; D008872:Microwaves; D008970:Molecular Weight
chemical_list: D000180:Acrylic Resins; C107926:poly(4-nitrophenylacrylate)