Soft mode dynamics above and below the Burns temperature in the relaxor Pb(Mg1/3Nb2/3)O3.
We report neutron inelastic scattering measurements of the lowest-energy transverse optic (TO) phonon branch in the relaxor Pb(Mg1/3Nb2/3)O3 from 400 to 1100 K. Far above the Burns temperature T(d) approximately 620 K we observe well-defined propagating TO modes at all wave vectors q, and a zone center TO mode that softens in a manner consistent with that of a ferroelectric soft mode. Below T(d) the zone center TO mode is overdamped. This damping extends up to, but not above, the waterfall wave vector q(wf), which is a measure of the average size of the polar nanoregions.
Gehring
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NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA.
Wakimoto
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Ye
Z G
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Shirane
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