title: The monoterpenes of Artemisia tridentata ssp. vaseyana, Artemisia cana ssp. viscidula and Artemisia tridentata ssp. spiciformis.
abstract: Monoterpenes from three different members of the Anthemideae family, Artemisia tridentata ssp. vaseyana, Artemisia cana ssp. viscidula and Artemisia tridentata ssp. spiciformis were isolated and their structures determined using spectroscopic techniques. A total of 26 irregular and regular monoterpenes were identified. Among these, 20 had previously been identified in the Anthemideae family. Of the remaining six, four were known, but previously unidentified in this family. 2,2-Dimethyl-6-isopropenyl-2H-pyran, 2,3-dimethyl-6-isopropyl-4H-pyran and 2-isopropenyl-5-methylhexa-trans-3,5-diene-1-ol were isolated from both A. tridentata ssp. vaseyana and A. cana ssp. viscidula. The irregular monoterpene 2,2-dimethyl-6-isopropenyl-2H-pyran has a carbon skeleton analogous to the biologically important triterpene squalene. Two additional irregular monoterpenes, artemisia triene and trans-chrysanthemal were isolated from A. cana ssp. viscidula and lavandulol was isolated from A. tridentata ssp. spiciformis. This is the first time a compound possessing a lavandulyl-skeletal type has been found in the Anthemideae family.
authors.affiliation: Department of Chemistry, University of Utah, 314 South 1400 East, Salt Lake City, UT 84112, USA.
authors.forename: K
authors.initials: K
authors.lastname: Gunawardena
authors.forename: S B
authors.initials: SB
authors.lastname: Rivera
authors.forename: W W
authors.initials: WW
authors.lastname: Epstein
mesh_terms: D019306:Artemisia / Q000737:chemistry*; D039823:Iridoids; D011714:Pyrans / Q000737:chemistry / Q000302:isolation & purification*; D013729:Terpenes / Q000737:chemistry / Q000302:isolation & purification
chemical_list: C450204:2,2-dimethyl-6-isopropenyl-2H-pyran; C450205:2,3-dimethyl-6-isopropyl-4H-pyran; D039823:Iridoids; D011714:Pyrans; D013729:Terpenes