Highly diastereoselective reformatsky-type reaction promoted by tin iodide ate complex.
[reaction: see text] An ate type of tin complex, Li(+)[n-Bu(2)SnI(3)](-)/HMPA, works as a novel type of reagent to accomplish the highly diastereoselective Reformatsky-type reaction by the halogen-metal exchange method.
Shibata
Ikuya
I
Department of Molecular Chemistry & Frontier Research Center, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan. shibata@ap.chem.eng.osaka-u.ac.jp
Suwa
Toshihiro
T
Sakakibara
Hideaki
H
Baba
Akio
A