title: Enantioselective adsorption of phenylalanine onto self-assembled monolayers of 1,1'binaphthalene-2,2'-dithiol on gold.
abstract: Self-assembled monolayer of atropisomeric compound, 1,1'-binaphthalene-2,2'-dithiol (BNSH), provides a field for chiral discrimination. The two-dimensional chiral arrangement with screw-like units, each of which is composed of three BNSH molecules, plays an important role in the enantioselectivity of adsorption of phenylalanine, as revealed by a quartz crystal microbalance technique.
authors.affiliation: Department of Applied Chemistry, School of Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555, Japan.
authors.forename: Takuya
authors.initials: T
authors.lastname: Nakanishi
authors.forename: Naoko
authors.initials: N
authors.lastname: Yamakawa
authors.forename: Toru
authors.initials: T
authors.lastname: Asahi
authors.forename: Tetsuya
authors.initials: T
authors.lastname: Osaka
authors.forename: Bunsho
authors.initials: B
authors.lastname: Ohtani
authors.forename: Kohei
authors.initials: K
authors.lastname: Uosaki
mesh_terms: D000327:Adsorption; D006046:Gold / Q000737:chemistry*; D009281:Naphthalenes / Q000737:chemistry*; D010649:Phenylalanine / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity; D013499:Surface Properties
chemical_list: C451166:1,1'-bianphthalene-2,2'-dithiol; D009281:Naphthalenes; D010649:Phenylalanine; D006046:Gold