[Polymerization of 4-nitrophenylacrylate under microwave heating conditions].
The 2,2'-azodiisobutyronitrile-induced radical polymerization in solution of 4-nitrophenyl acrylate was performed under microwave heating at a frequency of 2.45 GHz. This approach allows the control of the molecular mass of poly(4-nitrophenyl acrylate) used in the synthesis of multivalent glycoconjugates. It was found that the polymerization of 4-nitrophenyl acrylate under microwave irradiation results in products with a narrower molecular mass distribution than at conventional heating.
Dikusar
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MA
Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, ul. Miklukho-Maklaya 16/10, GSP Moscow, 117997 Russia.
Kubrakova
I V
IV
Chinarev
A A
AA
Bovin
N V
NV
D000180:Acrylic Resins / Q000138:chemical synthesis* / Q000737:chemistry; D006361:Heating; D008872:Microwaves; D008970:Molecular Weight
D000180:Acrylic Resins; C107926:poly(4-nitrophenylacrylate)