Electron paramagnetic resonance parameters of V2+ ions in both Cd2+ sites of CsCdCl3 crystal.
From the perturbation formulas based on a two-spin-orbit-parameter model, the electron paramagnetic resonance (EPR) zero-field splitting (D), g-factors (g //, g perpendicular) and hyperfine structure constants (A //, A perpendicular) for V2+ in Cd2+ (I) and Cd2+ (II) sites of CsCdCl3 crystal at room and liquid nitrogen temperatures are calculated. From the calculations, the signs of zero-field splittings and hyperfine structure constants are determined and so all of the EPR parameters are explained reasonably on the basis of the structure data of lattice.
Wen-Chen
Zheng
Z
Department of Material Science, Sichuan University, Chengdu, People's Republic of China. zhengwenchen@netease.com
Shao-Yi
Wu
W
D002104:Cadmium / Q000737:chemistry*; D002586:Cesium / Q000737:chemistry*; D002713:Chlorine / Q000737:chemistry*; D003460:Crystallization; D004578:Electron Spin Resonance Spectroscopy; D015233:Models, Statistical; D014639:Vanadium / Q000737:chemistry*
D002104:Cadmium; D014639:Vanadium; D002586:Cesium; D002713:Chlorine